Research Institute of Petroleum Processing, Sinopec

China Petroleum Chemical Corporation

Other

China Petroleum & Chemical Corporation

Qinghe Yang

Hong Nie

Dadong Li

Lishun Dai

Dawei Hu

Chuanfeng Niu

Liang Ren

Yanzi Jia

Shuling Sun

Zhen Wang

Yahua Shi

Mingfeng Li

Xuefen Liu

Anpeng Hu

Xinqiang Zhao

Jia Liu

Tao Liu

Yu Wang

Li Zhu

Jie Gao

Zhihai Hu

Kui Wang

Yichao Mao

Runqiang Zhang

Guofu Xia

Yongcan Gao

Guangle Zhao

Zhicai Shao

Zhonghuo Deng

Honghui Li

Xiaohong Kang

Fucheng Zhuang

Shuangqin Zeng

Xinpeng Nie

Yunfei Bi

Weiguo Huang

Qingzhou Guo

Wenxiu Fang

Luqiang Wang

Hongbao Li

Weizheng Dong

A catalyst has a carrier and a hydrogenation active metal component supported on the carrier. The hydrogenation active metal component contains at least one Group VIB metal component and at least one Group VIII metal component, and the carrier is composed of phosphorus-containing alumina. When the hydrogenation catalyst is measured using a hydrogen temperature programmed reduction method (H-TPR), the ratio of the peak height of the low-temperature reduction peak, P, at a temperature of 300-500° C. to the peak height of the high-temperature reduction peak, P, at a temperature of 650-850° C., i.e. S=P/P, is 0.5-2.0; preferably 0.7-1.9, and more preferably 0.8-1.8. The hydrogenation catalyst shows excellent heteroatom removal effect and excellent stability when used in hydrotreatment.

Hydrogenation catalyst and preparation method therefor and use thereof

Described are a process and a system for hydrotreating a deoiled asphalt. The process includes: (2) introducing a deoiled asphalt and an aromatics-containing stream into a first reaction unit for hydrogenation reaction, wherein the first reaction unit comprises a mineral-rich precursor material and/or a hydrogenation catalyst, and the first reaction unit is a fixed bed hydrogenation unit; (21) fractionating the liquid-phase product from the first reaction unit to provide a first light component and a first heavy component; (31) introducing the first light component into a second reaction unit for reaction, to provide a gasoline component, a diesel component and/or a BTX feedstock component; and (32) introducing the first heavy component to a delayed coking unit for reaction; or using the first heavy component as a low sulfur ship fuel oil component.

Process and system for hydrotreating deoiled asphalt

Described are a process and a system for processing aromatics-rich fraction oil. The process includes: (1) introducing an aromatics-rich fraction oil into a fifth reaction unit for hydrosaturation, followed by fractionation, to provide a first light component and a first heavy component; (2) introducing a deoiled asphalt and an aromatics-comprising stream including the first heavy component into a hydrogen dissolving unit to be mixed with hydrogen, and introducing the mixed material into a first reaction unit for a hydrogenation reaction; (3) fractionating a liquid-phase product from the first reaction unit to provide a second light component and a second heavy component; (41) introducing the second light component into a second reaction unit for reaction; and (42) introducing the second heavy component into a delayed coking unit for reaction; or using the second heavy component as a component of low sulfur ship fuel oil.

Process and system for processing aromatics-rich fraction oil

A molecular sieve has a silica/alumina molar ratio of 100-300, and has a mesopore structure. One closed hysteresis loop appears in the range of P/P=0.4-0.99 in the low temperature nitrogen gas adsorption-desorption curve, and the starting location of the closed hysteresis loop is in the range of P/P=0.4-0.7. The catalyst formed from the molecular sieve as a solid acid not only has a good capacity of isomerization to reduce the freezing point, but also can produce a high yield of the product with a lower pour point. The process for preparing the catalyst involves steps including crystallization, filtration, calcination, and hydrothermal treatment.

Molecular sieve having mesopores, preparation method therefor, and application thereof

The present invention relates to a catalyst combination for hydrotreating raw oils and a process for hydrotreating raw oils with the catalyst combination. The catalyst combination comprises

Process for hydrotreating heavy raw oils

A hydrocracking catalyst comprises a support, at least one of VIII Group metal components, and at least one of VIB Group metal components. The support comprises an acidic silica-alumina component and alumina derived from a pseudo-boehmite component, wherein the content of the acidic silica-alumina component is 3-80 wt %, the content of alumina derived from the pseudo-boehmite component is 20-95 wt %, based on the support. The support is obtained by mixing, molding, drying and calcining the acidic silica-alumina component with the pseudo-boehmite component, wherein said pseudo-boehmite component comprises pseudo-boehmite PB1 and pseudo-boehmite PB2, wherein the content of PB1 is 10-90 wt % and the content of PB2 is 0-60 wt % on a dry basis and based on the support.

Hydrocracking catalyst and use of the same

Disclosed is a combined process for hydrotreating and catalytic cracking of residue, wherein the residue, catalytic cracking heavy cycle oil with acidic solid impurity being removed, optional distillate oil and adistillate of catalytic cracking slurry oil from which the acidic solid impurity is removed are fed into residue hydrotreating unit, the hydrogenated residue obtained and optional vacuum gas oil are fed into catalytic cracking unit to obtain various products; the catalytic cracking heavy cycle oil from which the acidic solid impurity is removed is circulated to the residue hydrotreating unit; the catalytic cracking slurry oil is separated by distilling, the distillate of the catalytic cracking slurry oil after removing off the acidic solid impurity is circulated to the residue hydrotreating unit. This process makes the residue hydrotreating and catalytic cracking being combined together more effectively such that it is not only able to improve product quality of the residue hydrotreating, elongate operation cycle of the residue hydrotreating unit, but also increases the yield of the hydrogenated diesel oil and catalytic cracking light oil, and decreases coking quantity of the catalytic cracking.

Combined process for hydrotreating and catalytic cracking of residue

A guard catalyst, comprising an alumina support and molybdenum and/or tungsten and nickel and/or cobalt supported on the alumina support, wherein the total ammonia integral adsorption heat of said alumina support does not exceed 25 J/g, the percentage taken up by the ammonia integral adsorption heat of the ammonia differential adsorption heat greater than 100 kJ/mol does not exceed 10% of the total ammonia integral adsorption heat. Compared to the catalysts of the prior art, the guard catalyst has higher catalytic activity, less coke deposit, lower reduction rate of pore volume, better stability of activity, and higher strength.

Guard catalyst and a process for its preparation

A catalyst for hydrofining fraction oils, comprises an alumina carrier and at least one metal and/or thereof oxide of Group VIB and at least one metal and/or thereof oxide of Group VIII supported on said alumina carrier. The pore volume of said alumina carrier is not less than 0.35 ml/g, in which the pore volume of the pores having a diameter of 40-100 angstrom accounts for more than 80% of the total pore volume, the alumina carrier is prepared by a special process. The catalyst possesses relatively high hydrogenation activity.

Catalyst for hydrorefining fraction oils, its carrier and preparation

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Beijing, China

Qinghe Yang