Zhejiang University

Qingfeng Sun

Chao Wang

Hanwei Wang

Chunde Jin

Baokang Dang

Caicai Li

Ye Xiong

Zhe Wang

Li Zheng

Yingying Li

Yipeng Chen

Xiaoping Shen

Kangchen Nie

The present invention provides a powder-assembled composite micro-nano fiber and a method for preparing the powder-assembled composite micro-nano fiber. The method includes the following steps: (1) preparing two-dimensional cellulose from a cellulose-raw-material; (2) dispersing the two-dimensional cellulose and a powder material in a solvent to form a mixed suspension; and (3) performing freeze drying on the mixed suspension to obtain the powder-assembled composite micro-nano fiber, wherein a temperature difference between two ends in a vertical direction of the mixed suspension is controlled to be 10-100° C. in a freezing process of the freeze drying. In the present invention, a new non-destructive processing path from primary particles to macro applications is constructed, and rich material platforms and infinite possibilities are provided for basic studies and technical applications. The technology will play a huge role in energy, medical material, environment, protection, catalysis, photoelectricity, food engineering, daily necessity and other vast fields.

Powder-assembled composite micro-nano fiber and preparation method thereof

The present disclosure provides a method for preparing a piezoresistive sensor material, including: preparing a wood fiber aerogel; conducting dopamine self-polymerization on the surface of the aerogel to obtain a wood fiber-based hydrogel; soaking the wood fiber-based hydrogel in a nano conductive phase suspension or a nano conductive phase precursor to form a conductive phase-loaded wood fiber-based hydrogel; subjecting the conductive phase-loaded wood fiber-based hydrogel to reaction with an aqueous solution including a polyelectrolyte monomer, a crosslinker, an initiator and a catalyst to form a conductive phase-wood fiber-based hydrogel composite; and complexing the composite with metal ions. The present disclosure further discloses a piezoresistive sensor including the sensor material, and a preparation method thereof. The sensor material prepared by the method of the present disclosure has excellent mechanical strength and ionic conductivity, and a sensor further prepared has extremely-high sensitivity.

Piezoresistive sensor material and preparation method and use thereof

The present invention provides a biomimetic composite material, a nacreous layer-mimetic material, a biomimetic nacre material and preparation methods thereof. The biomimetic composite material comprises multiple composite film formed from biomass fibers and an inorganic nanomaterial, wherein an organic polymer material is arranged between the multiple composite film layers or in the composite base body. The invention combines a high-mechanical-performance shellfish structure with a wood fiberboard to overcome the original defects of the fiberboard, improve the fiberboard performances and endow it with new special performances, so that the prepared material has dual functions of the fiberboard and the nanomaterial at the same time.

Biomimetic composite material and preparation method thereof

An artificial timber comprises the following components in parts by weight: 35-50 parts of cellulose, 20-35 parts of hemicellulose and 15-35 parts of lignin, wherein the artificial timber has a density of 0.01-0.05 g/cm. The preparing method comprises: (1) dissolving 15-35 parts by weight of lignin, 35-50 parts by weight of cellulose and 20-35 parts by weight of hemicellulose with an ionic liquid; (2) cleaning and replacing it with water to obtain a lignocellulose hydrogel; and (3) drying the lignocellulose hydrogel to obtain an artificial timber. The artificial timber prepared by the present invention is large in specific area, low in density, low in material energy consumption, moderate in condition and easy for operation. The artificial timber obtained by the present invention is regular in shape and is shaped like a sandy beige cylinder without obvious damage and deformation, which indicates that such artificial timber with high specific area has well molding capacity.

Artificial timber

A composite nanosheet for the cathode of a lithium-sulfur battery, a preparation method thereof, and an electrode and a battery having the same. The composite nanosheet includes carbon nanotubes which are closely accumulated in a two-dimensional plane and are combined together by carbon derived from nanocellulose. Transition metal compound nanoparticles which are uniformly distributed in the nanosheet composite and are fixed by the carbon derived from nanocellulose. Sulfur adsorbed on the surface of the transition metal compound nanoparticles. The composite organically combines and exerts the respective advantages of porous carbon, carbon nanotubes and nano metal oxides/sulfide by designing and constructing the structure of the cathode material.

Nanosheet composite for cathode of lithium-sulfur battery, preparation method thereof and electrode and battery comprising the same

The invention relates to a wood-based biomimetic artificial muscle and preparation method and application thereof. The biomimetic artificial muscle comprises a wood-based cellulose skeleton, and polyvinyl alcohol and at least one ionic polymer filled in the wood-based cellulose skeleton. The preparation method includes S1: slicing wood, and subjecting the obtained wood slices to ammonia treatment and delignification in sequence; S2: soaking in the solution of citric acid and/or citrate; S3: preparing water solution of an ionic polymer and DMSO water solution of polyvinyl alcohol separately, and mixing to obtain polymer solution; S4: subjecting the treated wood slices to vacuum treatment, filling the polymer solution into the container, releasing vacuum, and pressurizing to infiltrate the polymer into the wood slices until saturation; S5: freezing the wood slices in a refrigerator and thawing; and S6: repeating S5 for 5-10 times, washing the wood slices, and drying. The inventive biomimetic artificial muscle obtained by physical crosslinking not only has the same elasticity and electrostriction as the polymer, but also maintains the strength of the wood-based skeleton.

Wood-based biomimetic artificial muscle and preparation method and application thereof

A graphene material prepared using waste tires and a preparation method thereof. Waste tires are crushed to 30-200 meshes to obtain tire powders. The tire powders are mixed with KOH or an aqueous solution of KOH to obtain a homogeneous mixture. The mixture is dried at 50-90&#xb0; C. for 12-48 hours, heated and calcinated in a tube furnace under a protective gas for 1-48 hour to obtain a black lump. The black lump is washed with distilled water, dilute hydrochloric acid or dilute sulfuric acid for at least 3 times, and then washed with deionized water for at least 3 times to obtain a black powder. The black powder is dried to obtain the graphene material. The graphene material has a three-dimensional structure composed of oligolayer graphene intertwined and connected with each other, has a high crystallinity, is not easily agglomerated, and thus can maintain nano-effect of the graphene material.

Graphene material prepared from waste tire and preparation method thereof

An artificial timer and preparing method thereof. The artificial timber includes the following components in parts by weight: 35-50 parts of cellulose, 20-35 parts of hemicellulose and 15-35 parts of lignin, wherein the artificial timber has a density of 0.01-0.05 g/cm. The preparing method includes: (1) dissolving 15-35 parts by weight of lignin, 35-50 parts by weight of cellulose and 20-35 parts by weight of hemicellulose with an ionic liquid; (2) cleaning and replacing it with water to obtain a lignocellulose hydrogel; and (3) drying the lignocellulose hydrogel to obtain an artificial timber. The prepared artificial timber is large in specific area, low in density, low in material energy consumption, moderate in condition and easy for operation. The obtained artificial timber is regular in shape and shaped like a sandy beige cylinder without obvious damage and deformation, which indicates that such artificial timber with high specific area has well molding capacity.

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Hangzhou, China

Qingfeng Sun