Sobute New Materials Co., Ltd

Nanjing Bote New Materials Co., Ltd.

Bote New Materials Taizhou Jiangyan Co., Ltd

Bote Building Materials (Tianjin) Co., Ltd

Bote New Materials Taizhou Co., Ltd.

Sobute Materials Co., Ltd

Panzhihua Bote Building Materials Co., Ltd.

Qianping Ran

Yong Yang

Jiaping Liu

Xin Shu

Jinzhi Liu

Shuai Qi

Jianfeng Ma

Dongliang Zhou

Shimin Fan

Tao Wang

Han Yan

Hongxia Zhao

Shentong Li

Jiangang Zhang

Bing Wang

Yanwei Wang

Xiumei Wang

Shuying Zhai

Changwen Miao

Zhen Huang

Min Qiao

Cheng Yu

Jianping Liu

Yonglin Mao

Zheng Han

The present invention discloses a polycarboxylic acid water-reducing agent with high adaptability to temperature and a method for preparing the same. The polycarboxylic acid water-reducing agent is prepared by introducing an unsaturated macromonomer D with a temperature-sensitive side chain which could be bonded to the backbone of the polycarboxylic acid through free radical polymerization. The polycarboxylic acid water-reducing agent prepared by the invention has an adsorption group density that can be automatically adjusted with the change of ambient temperature, and thereby shows similar dispersing capability and dispersion retention capability at different ambient temperatures, demonstrating high adaptability to different ambient temperatures. It can be used in a larger temperature range with a constant dosage, which is beneficial to further popularization and application of the polycarboxylic acid water-reducing agent in regions of different climates.

Polycarboxylic acid water-reducing agent with high adaptability to temperature and method for preparing the same

Disclosed are a highly adaptable viscosity-reducing polycarboxylate water reducer and its preparation method and application. The highly adaptable viscosity-reducing polycarboxylate water reducer is composed of a polymer and water, and the polymer accounts for 30-50 wt %; since the main chain of the polymer contains a hydrophobic benzene ring and hydrophilic amine, the polymer has strong rigidity and good solubility in an aqueous solution, and is rich in two adsorption groups of carboxyl group/phosphono group. The highly adaptable viscosity-reducing polycarboxylate water reducer of the present invention has excellent water-reducing and slump retention properties and is suitable for general construction projects and commercial concrete projects. Compared with the conventional polycarboxylate water reducer, the highly adaptable viscosity-reducing polycarboxylate water reducer of the present invention has strong adaptability to concrete materials and can effectively reduce the viscosity of high-strength concrete (C50-C100), thus having bright application prospects in the high-end water reducer market.

High-adaptability viscosity-reducing polycarboxylic acid water reducer, preparation method therefor and use thereof

Disclosed is an amphiphilic multifunctional hybrid nanoparticle. The nanoparticle of the present invention has a detachable hydrophilic organic polymer with both a water-soluble long chain and a hydrophobic long hydrocarbon functional group attached to the surface, wherein the body of the nanoparticle is a silica or an organofunctional group substituted silica or an organofunctional group substituted silicon-oxygen bond network, and the nanoparticle contains a free organosiloxane with hydrophobic long hydrocarbon functional groups and a fatty acid or fatty acid ester or aluminum complex of fatty acid with hydrophobic long hydrocarbon functional groups. The nanoparticle can reduce the water permeability of the cement-based material; the cement-based material has the internal hydration products and interfaces are hydrophobized, further reducing the possibility that the harmful particles erode the cement-based material through moisture penetration; furthermore, Si—Al oxides participate is beneficial to the improvement of its mechanical properties.

Amphipathic multifunctional hybrid nanoparticle, and preparation method therefor and application thereof

The present invention discloses a multitype-adsorptive-group polycarboxylic acid water-reducing agent, consisting of 30-60 wt % of a macromolecule with multitype-adsorptive groups and water, the macromolecule with multitype-adsorptive groups has a polyethylene glycol side chain, and adsorption groups of the polymer backbone include a carboxylic acid group, a sulfonic acid group and a phosphoric acid group, the phosphoric acid group being linked to the backbone of the macromolecule with multitype-adsorptive groups by nucleophilic addition. The water-reducing agent of the present invention has significantly improved adaptability to different cements and aggregates while maintaining a high water reduction efficiency, compared with the conventional polycarboxylic acid water-reducing agent agent. It has a good water reducing efficiency in many different grades of cement, as well as a better resistance to aggregates containing more impurities such as machine-made sand.

Multitype-adsorptive-group polycarboxylic acid water-reducing agent, method for preparing the same and use thereof

Disclosed is a preparation method of a polycarboxylate water reducer having a regular sequence structure. The preparation method of the present invention comprises: performing Michael addition on polyethylene glycol ether acrylate macromonomer A and amino-containing carboxylic acid B for 5-12 hours, then cooling to 0&#xb0; C., dropwise adding acryloyl chloride slowly and evenly, and further reacting for 12 hours at room temperature to obtain carboxyl-containing polyether macromonomer C; mixing the carboxyl-containing polyether macromonomer C, a small molecular RAFT reagent, an initiator, and water adequately; and holding the polymerization mass concentration at 30%-60% and heating to 60-80&#xb0; C. in the atmosphere of N2 to react for 2-5 hours to obtain the polycarboxylate water reducer having a regular sequence structure.

Preparation method for polycarboxylate water reducer having regular sequence structure

Embodiments of the invention relate to concrete admixtures, provide a phosphonato block polymer, a preparation method and an application. The method includes: the phosphonato block polymer prepared by copolycondensating an ether-type segment A, a phosphonato segment B, and a third part of aldehyde C. The ether-type segment A is obtained by polycondensating a polyether monomer and a first part of aldehyde C. The phosphonato segment B is obtained by polycondensating a monomer b containing phosphonato, a monomer c, and a second part of aldehyde C in an aprotic weak polar solvent E. By preparing a block polymer using arylalkane as a main chain and using a phosphonic acid or phosphinic acid functional group as an adsorption group, the invention improves the resistance of the block polymer to sulfate and clay interference, and can achieve initial high dispersion of concrete with a low water-cement ratio and decreasing of the system viscosity.

Phosphonato block polymer, preparation method therefor and application thereof

The present invention discloses a phosphorylated polycondensate high-performance water-reducing agent with a phosphorylated melamine derivative, instead of a conventional carboxyl group or sulfonic group, as a main adsorption group. The use of aryl alkoxypolyether as a side chain of the polymer provides a strong steric effect to improve the dispersibility and dispersion-retaining properties of the polymer. A polycondensate high-performance water-reducing agent and a method for preparing the same provided by the present invention have excellent overall performance, high adaptability for current low-grade raw materials of concrete, strong market demands, and vast application prospects. Additionally, the polycondensate has an advanced preparation process provided with the characteristics of industrially scalable production, which offers the prospect of a core technology in the field of water-reducing agent of concrete so as to promote development of the industry.

Phosphorylated polycondensate as high efficiency water reducing agent and preparation method thereof

The present invention discloses a method for preparing a concrete superplasticizer having a phosphorous acid group and a use of the concrete superplasticizer. The concrete superplasticizer having a phosphorous acid group according to the present invention is prepared by free radical copolymerization of a phosphorous-containing monomer A and a polyether macromonomer B. The concrete superplasticizer having a phosphorous acid group obtained in the present invention can effectively improve flowability of concrete and can retain good workability of concrete. The method is simple, economical and effective, and in particular, can be used for commercial mass production.

Method for preparing concrete superplasticizer having phosphorous acid group and use thereof

The present invention provides a method for preparing a polymer and a use of the polymer. The resulting polymer is used as a dispersant for an aqueous dispersion of a hydraulic binder and/or a latent hydraulic binder, such that water-reducing rate is improved, and suitable control of air content can be achieved, thereby improving the strength of concrete. The method for preparing a polymer includes polycondensation of a polyether macromonomer A of a specific structure, a monomer B and an aldehyde C to obtain the polymer. The monomer B is phenylsulfonic acid, p-/o-aminophenylsulfonic acid, p-/o-hydroxylbenzoic acid, p-/o-aminobenzoic acid, p-/o-hydroxylphenylsulfonic acid, or a phosphoric acid group or phosphorous acid group-containing monomer of a specific structure. A molar ratio of the polyether macromonomer A and the monomer B is 1:(0.5 to 12).

Preparation method for polymer and applications thereof

A slump retaining polycarboxylic acid superplasticizer. A weight average molecular weight of the superplasticizer is 20,000-80,000. The slump retaining polycarboxylic acid superplasticizer is prepared by performing polymerization reaction on a monomer A, a monomer B, a monomer C and a monomer D in an aqueous solution in the presence of a redox initiator, wherein a molar ratio of (the monomer A+the monomer B):the monomer C:the monomer D is 1:(3-8):(4-12), and a molar ratio of the monomer A to the monomer B is 1:(1-4).

Slump retaining polycarboxylic acid superplasticizer

The present invention provides a preparation method of hyperbranched polycarboxylic acid type copolymer cement dispersant, including: Monomer A, B and C undergo a free radical copolymerization in an aqueous medium. The molar ratio of Monomer A, Monomer B and Monomer C conforms to B/A&#x2212;A&#x2212;2&#x2212;10 and C/(A+B&#x2212;C)&#x2212;0.02&#x2212;0.08. Monomer A is expressed by General Formula (1), where, Ris H or a methyl; X&#x2550;O, CHO, CHCHO; m is an integer from 5 to 200. Monomer B is expressed by General Formula (2), where, Ris H or COOM; Ris H or CHand M is H, Na, K or NH; Monomer C is expressed by General Formula (3), where, Ris H or methyl; X&#x2550;O, CHO, CHCHO; Y&#x2550;CH, CHCH, CH(CH), CHCHCH, CH(CH)CH, C(CH)and n is an integer from 5 to 200.

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Nanjing, China

Qianping Ran