Air Products and Chemicals, Inc.

Puri, Pushpinder S.

Pushpinder S Puri

Guido Peter Pez

Bernard A Toseland

Madhu Anand

David Ross Graham

James G Hansel

Dilip G Kalthod

Stephen C Lynch

Christine A Costello

Myron J Coplan

Philip Bruce Henderson

Robert M Thorogood

Michael Langsam

Daniel Joseph Tempel

Jeffrey Richard Brzozowski

James Joseph Hart

Robin Joyce Maliszewskyj

Keith Douglas Campbell

James Michael Occhialini

Daniel V Laciak

John B Appleby

Albert A Brooks

James K Smith

John W McTopy, Ii

Daniel T Diggs

Jacob A Van't Hof

The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps:

Dehydrogenation of liquid fuel in microchannel catalytic reactor

The present invention is directed to improvements in storage and delivery systems that allow for rapid fill and delivery of gases reversibly stored in a nonvolatile liquid medium, improvements in delivery and purity of the delivered gas. The low pressure storage and delivery system for gas which comprises: a container having an interior portion containing a reactive Lewis basic or Lewis acidic reactive liquid medium that is reversibly reacted with a gas having opposing Lewis acidity or basicity;

Storage and delivery systems for gases held in liquid medium

An apparatus for detecting a leak of a fluid from a vessel having an inner wall and an outer wall includes: at least one odorant layer adjacent the inner wall or the outer wall; and at least one semi-permeable material layer adjacent the odorant layer.

Leak site odorization for gas leak detection

An apparatus for dispensing an odorant to a fluid in a vessel having an interior volume containing the fluid includes at least one odorant material and an odorant-permeable material. The at least one odorant material is disposed in the interior volume, the odorant material having at least one detectable odor. The odorant-permeable material encapsulates the odorant material.

Addition of odorants to gases for leak detection

An apparatus for dispensing an odorant to a hydrogen gas includes at least one container, each container having an interior volume. At least one odorant material is disposed in the interior volume of a first container, the odorant material having at least one detectable odor. At least one hydrogen storage material is disposed in the interior volume of the first container or the interior volume of a second container.

Addition of odorants to hydrogen by incorporating odorants with hydrogen storage materials

An apparatus for detecting a leak of a fluid from a system for storing and/or transporting a volume of the fluid includes an odorant material. The system includes at least one vessel and at least one sealant having an outer surface. The odorant material is encapsulated or sorbed on the sealant, at least a portion of the odorant material having at least one detectable odor.

Odorized seals for the detection of gas leak

Rapid cycle pressure swing adsorption processes, systems and apparatus for the separation of a multi-component feed gas mixture by selectively adsorbing at least one more readily adsorbable component in a bed of adsorbent material are provided.

Pressure swing adsorption system for gas separation

A process is provided for fabricating composite membranes by coating a porous substrate with a solution of selective polymer. A reserve of non-solvent medium is incorporated in the substrate pore network which allows the substrate to be successfully coated with a polymer solution formulated in a solvent medium which is also a solvent for the substrate material.

Process for producing composite membranes

Bundles of hollow filament membranes suitable for use in fluid separation, such as in the separation of air into gases more concentrated in oxygen and nitrogen are made in a cylindrical form and annular cross-section with multiple filaments of each layer lying in generally parallel helical paths at a common angle to the axis of symmetry of the bundle. Continuous lengths of filaments are laid down on the core while same is rotated first in a 'forward' sense and the filament lay-down point is traversed from a first end of the core to the second, and then in a 'reverse' sense while the filament lay-down point is traversed from the second end to the first. Reversing of the direction of core rotation and filament end-to-end traversal is repeated with said reversing controlled in such a manner that the path of the filament returning from either end to the other is displaced incrementally from that of the filament portion laid down in the immediately preceding traversal. Lay-down of filament is repeated until a plurality of segments of filament all sharing the same helix angle and direction have formed a thin annular layer. The instant method can be precisely controlled to obtain bundles of desired packing density with consequent improved flow of fluid within the shell side of the bundle.

Method of winding hollow fiber membranes

A hollow fiber separation module is provided having a single, elongated pressurizable shell and containing multiple separation stages by multiple sections of hollow fiber bundles contained within the shell, with the ends of each bundle section potted within a single tubesheet at each end of the elongated shell. The fibers within each section are aligned so that the permeate within the fiber bores passes along paths traveling generally from one tubesheet to the other and one or more impermeable barriers are provided within the shell to isolate each section and control the passage of feed gas along the shell side of each fiber bundle section in a flow path countercurrent to the passage of permeate in the bores of the fibers.

Multiple stage countercurrent hollow fiber membrane module

The present invention provides a surface modified polymeric gas separation membrane having improved selectivity, particularly for oxygen/nitrogen gas mixtures, prepared by forming a membrane of a polymer having the structural formula ##STR1## wherein R and R' can be the same or different linear, branched or cyclic alkyl group having one to twelve carbon atoms, or R can be H, with the proviso that both R and R' cannot be methyl, and n is at least 100, and treating the surface of the membrane with a fluoro-oxidizing agent at conditions sufficient to fluoro-oxidize the membrane surface.

Fluorooxidized polymeric membranes for gas separation and process for

Asymmetric polyacetylene polymer membranes having both improved selectivity and improved flux are provided by a process which comprises forming a solution containing from about 1 to about 5% by weight of a polyacetylene polymer in any suitable solvent therefor, forming the solution into a thin film and quenching the film in an aqueous bath in the presence of from about 0.002 to about 0.4% by weight of the quench bath of surfactant with an HLB value of 11 to 15. Additionally, the polyacetylene polymer solution contains a swelling agent at about 1% to about 10% by weight of polyacetylene polymer solution.

Asymmetric permselective polyacetylene membranes and process for the

The present invention is a process for applying a semi-permeable coating on a hollow fiber substrate. The hollow fiber substrate is continuously passed through a polymeric coating solution and withdrawn from the solution through a coating die to form a uniform polymeric solution coating on the outer surface of the hollow fiber. The coated hollow fiber is dried by passing it through a convective flow tunnel in which the rate of drying is controlled both by a pre-determined temperature profile in the tunnel and by a controlled air flow rate through the tunnel. The resultant material is a semi-permeable, coated composite hollow fiber membrane which can be used in gas and/or liquid separations.

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Macungie, PA, United States of America

Pushpinder S Puri