General Electric Company

Sabic Innovative Plastics IP B.v.

General Electric Corporation Gmbh

Pramod Shankar Kumbhar

John William Fulmer

Jegadeesh Thampi

Bharat Singh

Prashant Anil Tatake

Sunil Ashtekar

Umesh Krishna Hasyagar

Rathinam Jothi Mahalingam

Arun Kumar

Ramesh Krishnamurti

Jan-Pleun Lens

Gurram Kishan

Edward Joseph Nesakumar

David Joseph Parrillo

Mukund Parthasarathy

Vinod Kumar Rai

Geuch Zijlma

Rupesh Bhikaji Pawar

Nileshkumar Prakash Kukalyekar

Ashok Shyadligeri

Ashok Menon

Jacob Lee Oberholtzer

Sabyasachi Mandal

Debjani Kapila

Anju S Shukla

R Jothi Mahalingam

Nitin Vaish

Marakani Venkata Ramani

Mannish V Badani

Dave Sharber

Jake Oberholtzer

Radhakrishna Sreenivasarao Arakali

Use of a specific combination of catalysts for the first and second steps of the process for the conversion of CHP to BPA provides high yields of BPA and low impurity yields, without a requirement for the intermediate purification steps. In the first step, CHP is cleaved in the presence of an acid treated clay such as acid treated Montmorillonite clay to produce phenol and acetone. In the second step, the phenol and acetone produced is reacted, preferably without intermediate purification, in the presence of a cation exchange resin catalyst that includes a cation exchange resin and a mercaptan or mercaptoalkanoic acid promoter to produce BPA.

Integrated process for the production of bisphenol A from cumene hydroperoxide

Use of a specific combination of catalysts for the first and second steps of the process for the conversion of CHP to BPA provides high yields of BPA and low impurity yields, without a requirement for the intermediate purification steps. In the first step, CHP is cleaved in the presence of a sulfated metal oxide catalyst such as sulfated Zirconia to produce phenol and acetone. In the second step, the phenol and acetone produced is reacted, preferably without intermediate purification, in the presence of a cation exchange resin catalyst that includes a cation exchange resin and a mercaptan or mercaptoalkanoic acid promoter to produce BPA.

A process for the preparation of hydroquinone compounds comprising, reacting an aromatic hydroxy compound with an oxidizing agent in a biphasic solvent system. The reaction is carried out in the presence of a transition metal hydroxy phosphate catalyst to produce the corresponding hydroquinone compound.

Processes for preparing benzoquinones and hydroquinones

A process for producing a phenol product generally comprises a first step comprising reacting in a first reactor a feed stream comprising cumene hydroperoxide and water with an acid catalyst to produce an effluent comprising the phenol product, acetone, and at least 1% by weight residual cumene hydroperoxide, and a second step comprising passing the effluent into a second reactor and decomposing the residual cumene hydroperoxide, wherein during said process the ratio of phenol to acetone is maintained at a molar ratio of greater than 1:1, and wherein the water in each of the first and second steps is present in an amount more than 0 and less than or equal to 5 weight percent based on the total weight of the feed stream or effluent, and wherein the process is continuous.

Process for producing phenol

A continuous process comprising: contacting a mixture comprising dihydroxy aromatic compound, water and an alkylating agent with a catalyst system in the presence of a flowing carrier gas, to form a mono alkylated dihydroxy aromatic compound, wherein the catalyst system is obtained by the calcination of a catalyst precursor system comprising a metal oxide precursor, a transition metal element and a pore former.

Process for the monoalkylation of dihydroxy aromatic compounds

A process for forming a cycloalkylidene bisphenol comprises: reacting a cycloalkanone compound of formula:where [A] is a substituted or an unsubstituted aromatic group, R&#x2013;Rindependently represent a hydrogen or a C&#x2013;Chydrocarbyl group; and 'a' and 'b' are integers independently having values from 0&#x2013;3; with an aromatic hydroxy compound of formula [A]-OH, where [A] is as previously described; at a mole ratio of greater than or equal to about 20, in the presence of a sulfonic acid type ion exchange resin catalyst crosslinked with greater than or equal to about 8 weight percent of divinylbenzene, and a promoter selected from the group consisting of a mercaptan compound and a resorcinol compound; to form a cycloalkylidene bisphenol of formula:where [A], R&#x2013;R, &#x201c;a&#x201d; and &#x201c;b&#x201d; are as previously described. Moreover, any acid catalyst can be used with a resorcinol promoter.

Methods for preparing cycloalkylidene bisphenols

A method of preparing a polycyclic compound containing a ketone functionality comprising:

Preparation of ketone containing cyclic compounds

A metal oxide catalyst precursor composition comprises a pore former and a catalyst reagent.

Catalyst and method for the alkylation of hydroxyaromatic compounds

A process for separating sulfonic acid compounds from a phenolic solvent is provided by contacting the phenolic solvent with a hydrotalcite-type material (HTM). The process can be applied in the conventional industrial process for converting cumene to phenol to remove sulfonic acid compounds from the phenol product. A process and a facility for producing purified phenol by converting cumene to phenol are provided. In the conversion of cumene to phenol, the phenol often contains carbonyl-type impurities. The phenol and carbonyl-type impurities are reacted in the presence of a sulfonic acid cation exchange resin catalyst (IER) to produce a reaction product that may contain sulfonic acid compounds. The reaction product is contacted with an HTM to reduce the amount of sulfonic acid compounds which may be present and to produce a purified phenol-containing stream. The purified phenol-containing stream may be further purified using conventional separation techniques, such as distillation.

Production and purification of phenol

A system for purifying a cumene hydroperoxide cleavage product mixture comprises a cumene hydroperoxide cleavage product mixture feed containing impurities in fluid communication with an aqueous alkaline solution feed; the cumene hydroperoxide cleavage product mixture and aqueous alkaline solution feeds are in fluid communication with a neutralization drum having an aqueous salt phase outlet; an aqueous salt phase feed containing impurities in fluid communication with a heat treatment vessel having a heat-treated aqueous salt phase outlet; and a heat-treated aqueous salt phase feed containing water-soluble derivatives of the impurities in fluid communication with the cumene hydroperoxide cleavage product mixture prior to the neutralization drum.

System and method for purifying cumene hydroperoxide cleavage products

A process for converting carbonyl-type impurities contained in a phenolic solvent to high-boiling derivatives is provided by contacting the phenolic solvent with a hydrotalcite-type material (HTM). The phenol can be separated from the high-boiling derivatives using conventional separation techniques, such as distillation, so the invention also provides a process for separating carbonyl-type impurities, such as hydroxyacetone (HA), from a phenolic solvent. The process can be applied in the conventional industrial process for converting cumene to phenol to remove carbonyl-type impurities from the phenol product. A process and a facility for producing purified phenol by converting cumene to phenol are provided. In the conversion of cumene to phenol, the phenol often contains carbonyl-type impurities. The phenol and carbonyl-type impurities are reacted in the presence of an HTM to produce phenol and high-boiling derivatives. The phenol may be further purified using conventional separation techniques, such as distillation, to remove the high-boiling derivatives.

Production and purification of phenol: hydroxyacetone removal by hydrotalcite

A method of preparing cumylphenol comprises reacting phenol and alpha-methylstyrene in the presence of an acid catalyst and an alkylbenzene. The method provides an inexpensive, selective process to cumylphenol.

Growing community of inventors

Bengaluru, India

Pramod Shankar Kumbhar