Stamicarbon B.v., Licensing Subsidiary of Dsm

Ineos Vinyls UK Ltd.

Politecnico Di Milano

Pio Forzatti

Enrico Tronconi

Gianpiero Groppi

Carlo Giorgio Visconti

Luca Lietti

Roberto Zennaro

Stefano Rossini

Ferruccio Trifiro

Mauro Favaretto

Elsa Mignone

Andrea Marsella

Diego Carmello

Pierluigi Villa

Marzio Piazza

Massimo Iovane

Marco Paturzo

Isabella Nova

Lidia Castoldi

A multi-structured tubular element for producing a reactor for effecting exothermic/endothermic chemical reactions, comprises two or more monolithic thermoconductive bodies, assembled together so that each has a part of the side surface interfaced with the side surface of one or more monolithic thermoconductive bodies adjacent thereto, so as to form as a whole, a honeycomb structure containing a plurality of longitudinal channels extending from one end to the other of said tubular element, suitable for being filled with a granular catalytic solid.

Multi-structured reactor made of monolithic adjacent thermoconductive bodies for chemical processes with a high heat exchange

Reactor for Fischer-Tropsch reaction which is carried out in a three-phase system essentially consisting of a reacting gaseous phase, a reacted liquid phase and a solid catalytic phase, wherein the solid catalytic phase consists of packed or structured bodies of catalytic material encaged within at least one honeycomb monolithic structure with a high thermal conductivity.

Reactor for exothermic or endothermic catalytic reactions

There is disclosed a catalyst support for selective gas phase reactions in a tubular fixed bed reactor comprising a metallic monolith having channels the walls of which are adapted to receive a catalytically active phase or an intermediate layer acting as a carrier for a catalytically active phase. The monoliths are coated with catalytically active material and loaded lengthwise into tubular reactors, the channels being parallel to the length of the reactors. The catalysts are particularly useful in the chlorination/oxychlorination of alkenes and alkanes, and the oxidation of alkenes. Compared with the use of conventional catalysts in pellet form or in the form of ceramic monoliths the catalysts of the invention offer greater yields and selectivity, the avoidance of hot spots, greater catalyst life and flexibility in use.

Metallic monolith catalyst support for selective gas phase reactions in tubular fixed bed reactors

This invention provides a catalyst composition suitable for the gas phase oxidation, ammoxidation and oxidative dehydrogenation of olefins to unsaturated aldehydes, unsaturated nitriles and dienes respectively. The catalyst composition comprises, as active catalyst component, a solid solution of Fe, Sb and Ti oxides which has a rutile type crystal structure which is present in the composition in an amount of at least 80 wt. %, and which is represented by the empirical formula Fe.sub.x Sb.sub.y Ti.sub.z O.sub.w, wherein, for x=1, y is in the range of 0.5 to 10, z is in the range of 0.16 to 209 and w represents the number of oxygen atoms corresponding to the oxides of the above elements. The catalyst component is prepared by co-precipitating metal oxides from solutions of corresponding metal salts followed by calcination at 600.degree.-1000.degree. C. of the washed and dried precipitate.

Process for preparing an oxidation catalyst

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Monza, Italy

Pio Forzatti