Ashland Oil, Inc.

Battelle Memorial Institute

Marion Laboratories

Snyder Laboratories, Inc.

Phyllis L Brusky

Richard A Markle

George E Cremeans

Joel D Elhard

Chelliah Daniel

Donald M Bigg

Sylvester Sowell

Jai H Kyung

Robert A Grimm

Joseph G Holehouse

Biau-Hung Chang

John H Baker

Thermally reversible isocyanate-based polymers

Thermally-reversible polymer compositions are obtained by reacting compounds with isocyanate and labile-hydrogen functionality. High-performance characteristics are incorporated into the polymer by using aromatic polycarbonate, aromatic polyester, polyarylsulfide, and polyarylimidazolidine oligomers. The compositions are useful as hot-melt adhesives, coatings and especially finish surface coatings on composite materials such as polypropylene and polyethylene terephthalate, moldings and in injection reaction molding applications and composite and laminate fabrication.

Thermally-reversible isocyanate-based polymers

Thermally-reversible polymer compositions are obtained by reacting compounds with isocyanate and labile-hydrogen functionality. High-performance characteristics are incorporated into the polymer by using polyimide, aromatic polycarbonate, aromatic polyester, polyphenylene sulfide, and poly(parabanic acid) oligomers. Low-temperature flexibility and toughness are imparted to the polymers by using prepolymers such as polycaprolactone diols, polytetramethylene ether glycols and polyaliphatic carbon diols. Ionic bonding and liquid-crystal functionality may also be incorporated into the compositions. The compositions are useful as hot-melt adhesives, coatings, and moldings and in injection reaction molding applications and composite and laminate fabrication.

Thermally-reversible isocyanate polymers

Processes for treating polymeric surfaces to produce smooth, durable, slippery coatings which are able to withstand the rigors of sterilization and, long term exposure to human blood and other bodily fluids without substantial loss of their slipperiness.

Process for coating polymer surfaces and coated products produced using

Disclosed is a method for preparing poly(2-hydroxyethyl methacrylate) polymers (PHEMA) by a precipitation/suspension polymerization technique wherein a reaction mixture comprising hydroxyethyl methacrylate monomer (HEMA), solvent, and a free-radical initiator is subjected to heating for a time adequate for said PHEMA to be formed. The improvement in process of the present invention comprises restricting said HEMA to contain less than about 0.5 wt-% polyfunctional acrylate content, incorporating a suspending agent in said reaction mixture, agitating said reaction mixture during said heating, and restricting said solvent to one having a solubility parameter of between about 7.5 and 9, to produce PHEMA polymer particles ranging in size from about 30 to 1,000 microns and having a molecular weight ranging from about 500,000 to 2,000,000.

Preparation of PHEMA by precipitation/suspension polymerization

A process for preparing menthane diisocyanate by reaction of a terpinyl monoisocyanate with isocyanic acid in a medium which is an excess of isocyanic acid, a polar solvent, or a mixture of solvents which includes a polar solvent in the presence of a catalyst which is a Bronsted acid or a Lewis acid is disclosed.

Preparation of menthane diisocyanate by addition of isocyanic acid to

Isobutyric acid or a functional equivalent; e.g., a lower alkyl ester is oxidatively dehydrogenated to effect the vapor phase conversion thereof to the corresponding .alpha.,.beta.-ethylenically unsaturated derivative by contact with a heterogeneous catalyst in the presence of molecular oxygen. The catalyst is composed of calcined phosphates of iron containing cobalt or lanthanum as a modifier or dopant component.

Catalytic oxydehydrogenation process

Isocyanic acid is formed directly from nitric oxide, carbon monoxide and hydrogen by contacting a supported bifunctional iridium or rhodium metal catalyst at an elevated temperature with a feed stream of said reactants.

Production of isocyanic acid

Isobutyric acid or a functional equivalent, e.g., a lower alkyl ester is oxidatively dehydrogenated to effect the vapor phase conversion thereof to the corresponding .alpha.,.beta.-ethylenically unsaturated derivative by contact with a heterogeneous catalyst in the presence of molecular oxygen. The catalyst is composed of calcined phosphates of iron containing tellurium as a modifier or dopant component.

Growing community of inventors

Columbus, OH, United States of America

Phyllis L Brusky