Vesuvius Crucible Company

Phillipe Dumas

Eric Hanse

Paul M Benson

Quentin K Robinson

Duane L DeBastiani

David Stephenson

The invention concerns a component for the pouring of steel that has a body (2) of a refractory material containing carbon. It has a layer (10) that covers the body partially or completely and is capable of forming a surface layer (10a) that is oxidized and densified and is impermeable to gases when it is brought to a temperature above 1000.degree. C. The layer (10) is comprised of a refractory material containing sintering precursors chosen in the group consisting of calcined alumina, reactive calcined alumina, silica fumes and clays.

Refractory shape having an external layer capable of forming a layer

A dense carbon free surface is provided on a carbon bonded refractory shape which is particularly useful as a pouring tube liner to prevent the formation and build-up of alumina particles which may cause blockage of the tube. The carbon free, dense layer is also hard and erosion resistant making it ideal for use in other applications such as stopper rod noses. The material comprises a refractory mix having a major component of refractory oxides such as alumina and zirconia-mullite. Less than 10 wt. % carbon in the form of graphite and binder is in the mix plus about 2-5 wt. % of a metal such as silicon and an effective mount of sintering aids is also present. The pressed shape is preheated to a temperature of 1000.degree. -1400.degree. C. in air to oxidize the exposed surface of the shape and then to sinter the oxidized surface to form the desired dense, carbon free surface over the entire shape or on selected surface portions thereof.

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Feignies, France

Phillipe Dumas