Elf Atochem S.a.

Atohaas Holding, C.v.

Arkema Inc.

Philippe Heim

Bruno Vuillemin

Philippe Teyssie

Philippe Bayard

Patrice Gaillard

Jin-shan Wang

Pascal Nicol

David H Rein

Stephane Nowe

Paul Rempp

Pierre Lutz

Roger Fayt

Sunil K Varshney

Jinshan Wang

Bernard Boutevin

Gilles Meunier

Jean-Michel Bruneau

Jean-Pierre Parisi

Jacques Magne

Bachar Hamoui

Richard Legay

Lucien Renard

Patrick Delprat

The impact-resistant thermoplastic compositions comprising (A) a rigid thermoplastic methacrylic polymer or copolymer matrix P containing mostly methyl methacrylate units, (B) at least one impact-modifying additive and (C) at least one elastomer copolymer which contains grafting sites, at least on pendant chains, and is obtained from at least one vinylaromatic monomer (C) and from at one monomer chosen from the monomers (C): C-Clinear or branched alkyl acrylates, C-Calkoxyalkyl acrylates and aralkyl acrylates, dienes (C) and ethylenically unsaturated monomers (C) having one or more pendant initiating functional groups, the said copolymer (C) being grafted by thermoplastic polymer groups P and being dispersed in the matrix (A) in the form of nodules, which can be called 'particles', from 10 nm to 500 nm in size and able to have a droplet, capsule-type monoinclusion and/or salami-type multi-inclusion morphology.

Impact-resistant composition based on thermoplastic methacrylic (co)polymer

Living random (meth)acrylic copolymers, facilely converted into random co(meth)acrylates and block copolymers thereof, comprise the anionic copolymerizates of at least one comonomer A with at least one comonomer B selected from among the (meth)acrylates and maleimides, at least one of the comonomers A and B comprising a (meth)acrylate, in the presence of (i) at least one alkali or alkaline earth metal, mono- or difunctional initiator and (ii) at least one ligand, for example a nonnitrogenous macrocyclic complexant, e.g., a crown ether, or an alkali metal alcoholate.

Anionically copolymerized living random (meth) acrylic copolymers and

Anionically copolymerized living random (meth)acrylic copolymers and

A multifunctional anionic polymerization initiator which is in the form of a star-shaped polymer, and which is soluble in a nonpolar medium and is substantially free of residual double bonds. The initiator is denoted by the general formula (PA).sub.a N.sup.n- nLi.sup.+. PA is a polymer block of a vinylaromatic or diene monomer A. The variable 'a' is the number of branches in the block PA. N is a crosslinked core comprising no or practically no residual double bonds and has the formula (PMc)(RLi).sub.p. Mc is a monomer containing at least two polymerizable double bonds per molecule. PMc is a crosslinked core of at least one polymerized monomer Mc, containing 3 to 30% of residual double bonds in relation to the initial double bonds originating from the monomer Mc. R is an alkyl, aryl, arylalkyl, alkylaryl, cycloalkyl, or alkenyl. The variable 'p' is the number of residual double bonds in PMc which are neutralized by RLi. The variable 'n' is the number of anionic sites present in the crosslinked core N. A process of making and using the initiator to prepare star-shaped polymers.

Multifunctional initiator for obtaining star-shaped polymers by an

The invention relates to an adhesive composition for plastics based on (meth)acrylic (co)polymer derived from 80 to 100% by weight of methyl methacrylate and from 0 to 20% by weight of at least one monomer containing ethylenic unsaturation which can be copolymerized with the methyl methacrylate. The adhesive composition comprises 1,3-dioxolane combined with formic acid or a mono-, di- or tetraglyme, dissolved (meth)acrylic (co)polymer, and optionally diluent additives. The invention further relates to articles made of (meth)acrylic (co)polymer obtained by casting, extrusion or injection and comprising a bonding joint formed from the said adhesive composition.

Adhesive composition for (meth)acrylic (co)polymer materials

The invention relates to compositions for flame-retardant cast panels made of (meth)acrylic polymers. The composition comprises at least one (meth)acrylic ester monomer, (meth)acrylic acid and at least one phosphorus compound which is anhydrous and is chosen from phosphoric acids, phosphoric acid esters or their mixtures, optionally in combination with an optionally halogenated neutral phosphoric ester. The amount of (meth)acrylic acid and of phosphorus compound, by weight with respect to the total mixture constituting the composition, is such that the flame-retardancy coefficient FRC: ##EQU1## is greater than 0.95.

Composition for flame-retardant cast panels made of (meth)acrylic

An initiation system for the anionic polymerization of (meth)acrylic monomers and, optionally, nonacrylic vinyl monomers is disclosed. The initiation system comprises (1) a functional initiator and (2) an alkali metal alcoholate having the formula R'OM', in which M' is an alkali metal and R' is a group R.sup.1 (OR.sup.2).sub.m where R.sup.1 is a C.sub.1 -C.sub.6 alkyl or arylalkyl radical, R.sup.2 is a C.sub.2 -C.sub.4 alkylene radical and m is equal to 1, 2 or 3. The initiation system is applied to the formation of (meth)acrylic homopolymers and block copolymers of (meth)acrylic monomers and, optionally, nonacrylic vinyl comonomers.

Initiation system for the anionic polymerisation of (meth)acrylic

A diblock copolymer obtained by polymerizing acrylic, methacrylic or nonacrylic vinyl monomers in the presence of a polymerization initiating amount of an initiation system including (1) at least one functional initiator and (2) an alkali metal alcoholate. The alcoholate has the formula:

Initiation system for the anionic polymerization of (meth)acrylic

Mechanically strong; heat-resistant and transparent PMMA polymers having a high content of syndiotactic triads, a number average molecular weight ranging from 5,000 to 500,000 and a polydispersity index ranging from 1.01 to 1.5, are prepared by anionically polymerizing methyl methacrylate, characteristically at a temperature of at least 0.degree. C., in the presence of (a) at least one organolithium or organosodium initiator and (b) at least one AlR.sup.1 R.sup.2 R.sup.3 ligand, for example at least one di- or tri-phenoxy alkyl aluminum compound.

Highly syndiotactic PMMA polymers

A multifunctional anionic polymerization initiator which is in the form of a star-shaped polymer soluble in an apolar medium and substantially free of residual double bonds. The initiator is denoted by the general formula (PA).sub.a N.sup.n- nLi.sup.+. PA is a polymer block of a vinylaromatic or diene monomer A. The variable 'a' is the number of branches in the block PA. N is a crosslinked core comprising no or practically no residual double bonds and has the formula (PMc)(RLi).sub.p. Mc is a monomer containing at least two polymerizable double bonds per molecule. PMc is a crosslinked core of at least one polymerized monomer Mc, containing 3 to 30% of residual double bonds in relation to the initial double bonds originating from the monomer Mc. R is an alkyl, aryl, arylalkyl, alkylaryl, cycloalkyl, or alkenyl. The variable 'p' is the number of residual double bonds in PMc which are neutralized by RLi. The variable 'n' is the number of anionic sites present in the crosslinked core N. A process of making and using the initiator to prepare star-shaped polymers.

Imidation-modified MMA (co)polymers, characteristically having a Tg from 20.degree. to 30.degree. C. higher than the Tg of the corresponding unmodified MMA (co)polymer, are produced by reacting an amine, e.g., methylamine or cyclohexylamine, with a suspension, in a hydrophobic nonsolvent reaction medium, of beads of such MMA polymer/copolymer.

Preparation of imide-modified methyl methacrylate (MMA)

In a first step of this process an elastomer latex is prepared in aqueous emulsion in the presence of at least one ionic surfactant and at least one ethylenically unsaturated monomer; then in a second step at least one vinyl monomer, which is insoluble in water or sparingly soluble in water, is added to the latex thus obtained and the ionic charges introduced by the said latex are neutralised by adding to the mixture of latex and monomer at least one transfer agent carrying ionic charges opposite to those of the surfactant used in the first step, in order to effect the transfer of particles of the latex into the vinyl monomer; then in a third step the aqueous phase is separated from the organic phase comprising the latex and the vinyl monomer; and in a fourth step the bulk polymerisation of the organic phase is carried out in such a way as to obtain the cast sheet after cooling and release from the mould.

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Pau, France

Philippe Heim