Standard Oil Company (indiana)

Amoco Corporation

Philip M Rose

Chi-Hung Lin

David R Kreider

Jack F Stevens

Benjamin S Tovrog

Yoon S Song

Nan Wei

Albert McCullum

Ronald P Stark

Kwok-fu Lee

This invention relates to an apparatus and process for feeding powder or dry solids catalyst into a flowing liquid stream. More particularly, the invention includes an apparatus which includes a novel purging device and means for isolating a metering means from a liquid stream, and process for injecting finely divided flowable powder or catalyst into a flowing liquid stream, which in turn is fed into a reactor utilized for the production of polypropylene or polyolefins.

Powder feeder apparatus

The process and the system are used for carrying out the quench-cooled, vapor-phase polymerization of olefin monomer in a horizontally disposed reactor vessel which comprises contacting olefin monomer, or a mixture of olefin monomers, with a polymerization catalyst system in the presence of hydrogen in the reactor vessel to form a polymer product. The improvement comprises introducing a titanium-containing catalyst component of the catalyst system into the top side of the reactor vessel at a point adjacent to the upstream end of the reactor vessel and introducing a cocatalyst plus modifer component of the catalyst system into the top side of the reactor vessel at a distance, downstream of the point of introduction of the titanium-containing catalyst component, which is equal to 25% of the inside diameter of the reactor vessel.

Method and apparatus for minimizing polymer agglomerate or lump

In a process for quench-cooled, vapor-phase polymerization of olefin monomer comprising (a) contacting an olefin monomer, or mixture of olefin monomers, with a polymerization catalyst in the presence of hydrogen in a reactor vessel to form polymer product, and (b) removing, condensing and recycling off-gas from such reactor, an improvement comprises separating entrained polymerizing solid fines from said off-gas and recycling such solids directly to the reactor without substantial continued polymerization of such solids while in the presence of a substantially different concentration of hydrogen than in the reactor.

Method and apparatus for recycle of entrained solids in off-gas from a

The double reverse helix agitator with an internal conveying screw is used in a gas phase olefin polymerization reactor having at least one polymerization section and has helical flights defined by helical blades which are mounted to a shaft, which extend in opposite axial directions and which have approximately the same radius from the axis of rotation of the agitator. The shaft has a spiral screw thread thereon for conveying polymer particles axially by the agitator through a reactor vessel.

Double reverse helix agitator

In a gas phase olefin polymerization using a transition metal compound/aluminum alkyl catalyst system, polymerization can be terminated rapidly by injecting an amount of carbon oxide and then restarting efficiently by addition of an amount of aluminum alkyl.

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Naperville, IL, United States of America

Philip M Rose