Pq Corporation

Petra M Gill

Raymond P Denkewicz, Jr

Eric Von Borgstedt

Michael James McDonald

Judith L Thompson

Disclosed are silicate-dextrin-clay adhesive compositions and process for making the same for use in paper products, such as, paper tubes, corrugated boards and corner boards.

Silicate-dextrin clay adhesive compositions

The present invention pertains to a crystalline hydrated layered sodium silicate/amorphous sodium silicate composite material with predetermined hardness ion sequestration properties achieved by control of the process for forming the material, and a process for making the material. The process for producing the crystalline hydrated layered sodium silicate/amorphous sodium silicate composite consists of producing a crystalline sodium disilicate by heating a sodium silicate at a specified time and temperature. The resulting material may include amorphous material, and the crystalline sodium disilicate can be either alpha-phase or delta-phase disilicate. This crystalline sodium disilicate is then hydrolyzed with up to 50.0 milliequivalents per gram of either H.sub.3 O.sup.+0 ions or OH.sup.- ions. The resulting material can sequester Ca.sup.2+ ions, Mg.sup.2+ ions, or both, depending on the results desired, processing conditions, and starting materials used.

Composite silicate materials

The present invention pertains to a crystalline hydrated layered sodium silicate/amorphous sodium silicate composite material with predetermined hardness ion sequestration properties achieved by control of the process for forming the material, and a process for making the material. The process for producing the crystalline hydrated layered sodium silicate/amorphous sodium silicate composite consists of producing a crystalline sodium disilicate by heating a sodium silicate at a specified time and temperature. The resulting material may include amorphous material, and the crystalline sodium disilicate can be either alpha-phase or delta-phase disilicate. This crystalline sodium disilicate is then hydrolyzed with up to 50.0 milliequivalents per gram of either H.sub.3 O.sup.+ ions or OH.sup.- ions. The resulting material can sequester Ca.sup.2+ ions, Mg.sup.2+ ions, or both, depending on the results desired, processing conditions, and starting materials used.

An adhesive composition comprising (in percent by weight) from about 0.05 to about 0.50% of sodium silicate, from about 10 to about 47% of dextrin, from about 17 to about 70% of an alkali metal silicate, from about 0.05 to about 0.50% of sodium metaborate octahydrate or sodium metaborate tetrahydrate, and from about 18.0 to about 62.0% water and a process for preparing the same. The adhesive composition is useful in the manufacture of paper products, such as, paper tubes, corrugated boards and corner boards.

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Warminster, PA, United States of America

Petra M Gill