3m Innovative Properties Company

Solventum Intellectual Properties Company

Peter U Osswald

Joachim Zech

Henning Hoffmann

Andreas R Maurer

Peter Bissinger

Hendrik M Grupp

Christoph Schulte

Klaus Hintzer

George W Griesgraber

Marc Peuker

Andreas Johannes Boehm

Malte Korten

Helmut Pauser

Gallus Schechner

Manfred Harre

Rudolf Schmid

Daniel D Oberpertinger

Johann Fetz

Bernd Kuppermann

Hendrick Grupp

Hyung-Min Shim

Hendrik Grupp

The invention relates to a process of taking a dental impression, the process comprising the steps of providing a radiation-curable dental impression composition, placing the radiation-curable dental impression composition in contact with dental tissue, applying radiation to the radiation-curable dental impression composition, letting the radiation-curable dental impression composition cure, removing the cured dental impression composition from the dental tissue, the radiation-curable dental impression composition comprising mercapto-functional polyorganosiloxane(s), VQM resin(s), photo-initiator(s) for initiating a curing reaction between, and optionally filler(s). The invention also relates to a cured dental impression obtained by radiation curing the radiation-curable dental impression composition, a kit of parts containing the radiation-curable dental impression composition and a dental impression tray filled with the radiation-curable dental impression composition.

Process of taking a dental impression with a radiation-curable composition containing mercapto-functional polyorganosiloxanes and VQM resins

The invention relates to a radiation-curable silicone composition for additive-manufacturing technology comprising mercapto-functional polyorganosiloxane(s) as Component A, organosiloxane(s) with at least two aliphatic unsaturated carbon-carbon moieties as Component B, photo-initiator(s) as Component C for initiating a curing reaction between Component A and Component B, dye(s) as Component D dissolved in mercapto-functional polyorganosiloxane(s) as Component E, the mercapto-functional polyorganosiloxane(s) having a fraction of (mercaptoalkyl)methylsiloxane units of at least 50 mol %, wherein Component D is dissolved in Component E before Component D is combined with the other components of the radiation-curable silicone composition. The invention also relates to a process of producing a radiation-curable composition wherein the process comprises the steps of providing a solution of dye(s) in a composition comprising mercapto-functional polyorganosiloxane(s) having a fraction of (mercaptoalkyl)methylsiloxane units of at least 50 mol %, combining the solution containing the dye(s) dissolved in the mercapto-functional polyorganosiloxane(s) with mercapto-functional polyorganosiloxane(s), organosiloxane(s) with at least two aliphatic unsaturated carbon-carbon moieties, photo-initiator(s) for initiating a curing reaction between Component A and Component B, optionally filler(s), stabilizer(s) and additive(s).

Radiation-curable composition containing mercapto-functional polyorganosiloxanes for additive-manufacturing technology

The invention relates to a medical composition comprising guanidinyl-containing polymer(s) and polyanionic polymer(s). The medical composition is useful for absorbing water-containing fluids and can be used as dental retraction composition or as part of a medical treatment device.

Medical composition containing guanidinyl-containing polymer(s) and carrageenane(s)

The invention relates to a curable composition for dental retraction comprising a resin matrix comprising at least one polyorganosiloxane with at least two olefinically unsaturated groups as component A1, at least one organohydrogenpolysiloxane as component A2, optionally at least one vinyl functional QM silicone component as component A3, at least one alkylsiloxane having at least one carbinol, silanol, or alkoxy moiety as component B, optionally surfactant(s) as component E, optionally additive(s) as component F, a filler system comprising filler(s) as component D, a catalyst system comprising addition cure catalyst component C-A suitable to cure components A1 and A2, condensation cure catalyst component C-B suitable to cure component B, the curable composition being provided as a kit of part comprising a Catalyst Part I and a Base Part II the Catalyst Part I comprising components C-A, C-B, A1, the Base Part II comprising components A2, A1, B, wherein each of components D, E and F and A3, if present, can be present either in the Catalyst Part I or the Base Part II or the Catalyst Part I and the Base Part II, and wherein component B is present in an amount of 6 wt. % or more with respect to the whole composition.

Curable composition for dental retraction

The invention relates to a process of processing a radiation-curable composition with an additive-manufacturing technique comprising a radiation-curing step, the radiation-curable composition comprising mercapto-functional Component A comprising at least three mercapto moieties, crosslinker Component B with at least three vinyl or allyl moieties, photo-initiator(s) Component C for initiating a curing reaction between Component A and Component B, wherein the radiation-curable composition does not comprise urethane (meth)acrylate oligomers in an amount of more than 4 wt. % with respect to the whole composition. 3-dim articles which can be produced are typically transparent and have adequate mechanical properties. The radiation-curable composition is in particular useful for producing clear-tray aligners for dental and orthodontic purposes.

Process of processing a radiation-curable thiolen based composition with additive-manufacturing technology

The invention relates to a radiation-curable silicone composition for additive-manufacturing technology comprising mercapto-functional polyorganosiloxane(s) as Component A, organosiloxane(s) with at least two aliphatic unsaturated carbon-carbon moieties as Component B, photo-initiator(s) as Component C for initiating a curing reaction between Component A and Component B, dye(s) as Component D, and at least one of the following as Component E: solvent being able to dissolve the dye(s); and/or surfactant(s) being able to dissolve the dye(s).

The invention relates to a dental composition for use as a dental retraction material comprising filler(s), paste forming liquid(s) and guanidinyl-containing polymer(s). The dental composition is typically stored in a capsule with a thin nozzle enabling the delivery of the material in the sulcus of a tooth.

Dental retraction composition with guanidinyl-containing polymer

The invention relates to a kit of parts comprising a Base Paste (B) and a Catalyst Paste (C), Base Paste (B) comprising a cationically hardenable component, Catalyst Paste (C) comprising a starter component suitable to contribute to the hardening of the cationically hardenable compound, the composition obtained when combining the compositions of Base Paste (B) and Catalyst Paste (C) comprising in addition a porous water-adsorbing component and water, the porous water-adsorbing component being selected from molecular sieves, zeolites, silica gel and mixtures thereof, wherein either the porous water-adsorbing component is present in Base Paste (B) and the water is present in Catalyst Paste (C), or the water-adsorbing component is present in Catalyst Paste (C) and the water is present in Base Paste (B). The invention also relates to a dental retraction composition obtainable by mixing Base Paste (B) and Catalyst Paste (C) and to a process of taking a dental impression and/or conducting a dental retraction using the kit of parts.

Kit of parts containing a cationically hardenable composition and use as dental retraction material

A process for taking a dental impression and/or conducting a dental retraction. The process includes the steps of:

Process for taking a dental impression and curable composition for use in a dental impressioning and retraction process

The present invention relates to a kit of parts comprising Paste (A), Paste (B) and Paste (C), the pastes being characterized as follows: Paste (A) comprising at least one polyorganosiloxane with at least two olefinically unsaturated groups, and at least one organohydrogenpolysiloxane, at least one alkylsiloxane having at least one carbinol, silanol, alkoxy, carboxyl or amino group, optionally filler(s) and optionally additive(s); Paste (B) comprising at least one polyorganosiloxane optionally with olefinically unsaturated groups, at least one addition cure catalyst, optionally at least one alkylsiloxane having at least one carbinol, silanol, alkoxy, carboxyl or amino group, optionally filler(s) and optionally additive(s) Paste (C) comprising a softener, a condensation cure catalyst, optionally filler(s), and optionally additive(s) optionally at least one polyorganosiloxane optionally with olefinically unsaturated groups. The invention is also directed to a system for storing and delivering Paste (A), Paste (B) and Paste (C), the system comprising three compartments for storing the respective pastes, means for delivering the respective pastes to an outlet orifice and an interface for receiving a mixing tip. The kit of parts or the system is in particular useful for conducting a dental retraction and dental impression process.

Kit of parts for conducting a dental impression and retraction process

The invention is related to a dental impression composition which is curable at a temperature below about 50 C, the composition comprising: (A) a curable organopolysiloxane polymer as component (A), (B) a crosslinker compound capable of cross-linking said organopolysiloxane polymer as component (B), (C) a catalyst as component (C) capable of catalyzing a crosslinking reaction of component (A) and component (B), (D) a hydrophilizing agent as component (D), (E) a filler as component (E), (F1) a stabilizer as component (F1) selected from compounds comprising a phosphite moiety and mixtures thereof, (F2) a stabilizer as component (F2) selected from antioxidants and mixtures thereof, the composition being present in the form of a base paste and a catalyst paste physically separated from another, the base paste comprising components (A), (B), (D), (E), (F1), (F2), the catalyst paste comprising components (A), (C), (E).

Stabilized dental impression composition, kit of parts and use thereof

The invention relates to a curable dental composition being prepared by mixing a base paste and a catalyst paste, 'the base paste comprising component(s) (A) with curable moieties (AC),' the catalyst paste comprising a catalyst (C) being able to initiate or catalyse a crosslinking reaction involving components (A) upon mixing base paste and catalyst paste, the curable composition comprising a component (X) with reactive moieties, component (X) being either produced during the curing reaction or being present in either the base paste or the catalyst paste before the crosslinking reaction is initiated or catalysed, component X being different from component(s) (A), either base paste or catalyst paste comprising a reactant (Y), reactant (Y) being able to interact with component (X), but not taking part in the crosslinking reaction, the curable composition being able to produce energy in an amount sufficient to increase the temperature T1 of the composition being present 20 s after mixing the base paste and the catalyst paste to a temperature T2 being from about 6 to about 20&#xb0; C. above T1.

Curable composition with shortened setting time, process of production and use thereof

The invention relates to a composition for taking dental impressions, the composition comprising a siloxane component (A) comprising terminal vinyl groups, a siloxane component (B) comprising Si&#x2014;H groups, a catalyst (C) being able to catalyze a curing reaction between components (A) and (B) and a silicone oil (D), wherein the silicone oil has a viscosity at 23 DEG C of at least about 600,000 mPa*s and is present in an amount from about 1 to about 20 wt.% with respect to the weight of the whole composition. The invention also relates to a method of producing such a composition and a method for adjusting the Shore hardness A of a composition.

Siloxane compounds containing composition, method of production and use thereof

The invention relates to a curable dental composition comprising a curable polyether group containing polymer as component (A), an initiator capable of initiating a curing reaction of component (A) as component (B) and a certain F-containing compound as component (C). The invention also relates to a method of production and use of the curable dental composition or a respective kit of parts for the preparation of or as impression material or for the preparation of crowns and bridges.

Polyether group containing dental composition containing an F-containing compound, process of production and use thereof

The present invention relates to a curable dental composition comprising a surfactant and an F-containing compound. The dental composition can be used e.g. as impression material and/or for the production of crown and bridges.

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Tuerkheim, Germany

Peter U Osswald