Dak Americas LLC

Peter S Kezios

Helen Jane Codd

Thomas Taylor

Karl H Buchanan

Karl Buchanan

Helen Codd

Chi-Chin Chen

George F Rollend

Kevin Richard Harrison

Mika Härkönen

Rajat Kapoor

Adina Anghelescu-Hakala

Compositions of high molecular weight poly(hydroxy acid) polymer having good thermal stability and a weight average molecular weight of >100,000 by GPC. The compositions include one or more chain-terminator compounds/impurities which may be incorporated into the polymer and rendered harmless by the presence of appropriate amounts of bi-functional and multi-functional polymerization initiators, processes of preparing the polymer, and uses of the polymer to provide containers and polymer films or film-derived packages prepared therefrom.

Poly(glycolic acid) for containers and films with reduced gas permeability

Compositions of high molecular weight poly(hydroxy acid) polymer having good thermal stability and a weight average molecular weight of &#x3e;100,000 by GPC. The compositions include one or more chain-terminator compounds/impurities which may be incorporated into the polymer and rendered harmless by the presence of appropriate amounts of bi-functional and multi-functional polymerization initiators. A process including first mixing glycolic acid and/or lactic acid (with chain-terminators), and a diol or di-acid initiator, and at least one multifunctional initiator to form a liquid monomer mixture in an agitated polycondensation reactor. Next, polycondensing to form a liquid reaction mixture comprising a pre-polymer having a weight average molecular weight of &#x3e;10,000 by GPC, and greater than 80% by mole hydroxyl or carboxyl end-group termination, then crystallizing to form a first solid reaction mixture. Then, solid state polycondensing the solid reaction mixture to form a solid reaction mixture having a moisture level less than 50 ppm by weight. Then, mixing the solid reaction mixture with an appropriate reactive coupling agent in a melting and mixing extruder to couple and form the reaction mixture and form the final poly(hydroxy acid) polymer.

Three independent approaches to the reduction of gas molecule permeability through a polyethylene terephthalate (PET) polyester film or container wall by increasing the mechanically or thermally induced crystallinity or the overall crystallinity level of a single or multilayer container, where the three approaches may be employed independently or in combination with one another.

Polyester containers and films with reduced gas permeability

A process for making a high molecular weight poly(hydroxy acid) polymer having good thermal stability and a weight average molecular weight of &#x3e;100,000 by GPC. The process includes mixing glycolic acid and/or lactic acid, and a diol or di-acid initiator, and at least one multifunctional initiator to form a liquid monomer mixture in an agitated polycondensation reactor. Polycondensing to form a liquid reaction mixture comprising a pre-polymer having a weight average molecular weight of &#x3e;10,000 by GPC, and greater than 80% by mole hydroxyl or carboxyl end-group termination, then crystallizing to form a first solid reaction mixture. Then solid state polycondensing the solid reaction mixture to form a solid reaction mixture having a moisture level less than 50 ppm by weight. Then mixing the solid reaction mixture with an appropriate reactive coupling agent in a melting and mixing extruder to couple and form the reaction mixture and form the poly(hydroxy acid) polymer.

Process for making poly(glycolic acid) for containers and films with reduced gas permeability

A method of processing a polyester composition without changing the intrinsic viscosity of the polyester polymer by more than 0.025 dL/g such as injection molding a PET resin to form a bottle perform and blow molding a container from the bottle preform.

Co-polyester packaging resins prepared without solid-state polymerization, a method for processing the co-polyester resins with reduced viscosity change and containers and other articles prepared by the process

The invention provides UV-barrier formulations which result in products which effectively resist the transmission of ultraviolet light therethrough. The invention also provides UV-barrier formulations which result in products with improved resistance to ultraviolet light. In particular, the invention provides UV barrier formulations for polyester resins that have improved resistance to ultraviolet radiation, and significantly reduce ultraviolet light transmission in the resulting resin products. The invention also provides products and manufacturing processes based on the above formulations.

UV barrier formulation for polyesters

A process for producing compositions having improved gas barrier properties, and compositions containing a polyester resin and one or more of another thermoplastic resin and a filler, and may be used to form containers that exhibit improved resistance to gas permeation.

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Wilmington, NC, United States of America

Peter S Kezios