Rhone-Poulenc, Inc.

Rhodia Limited

Peter S Gradeff

Fred G Schreiber

John F Davison

Kenan Yunlu

Vincent J Charte

Heiko Mauermann

Carlos M Ramirez

Jean Grosbois

Robert S De Simone

Marshall R Angeles

Stanley T Murayama

Leon Farber

Giuseppe Formica

Ceric hydrocarbyl silyloxides are provided, as well as a process for preparing them, which comprises reacting ceric ammonium nitrate with a hydrocarbyl silanol, including a lower aliphatic silanol, under anhydrous conditions in the presence of an anhydrous base at a temperature within the range from about -30.degree. C. to about 200.degree. C. but preferably from 0.degree. to about 150.degree. C. until ceric hydrocarbyl silyloxide and the nitrate salt of the base are formed; the nitrates formed during the reaction can be separated from the reaction mixture and the ceric hydrocarbyl silyloxides isolated pure or as complexes with the solvent, or in some cases the ceric hydrocarbyl silyloxides can be used without separation from the reaction mixture in the presence of the nitrates.

Ceric hydrocarbyl silyloxides and process for their preparation

Alkoxy-type derivative compounds are a process for preparing alkoxy-type derivatives of trivalent Group 3b metals, e.g., cerium (III), such as alkoxides, siloxides or alkanolatoamines from an anhydrous complex of trivalent Group 3b metals, e.g. cerium ammonium nitrate complex, in the presence of an alcohol, silanol or alkanolamine and a base or by employing the complex and alkali salts of the alcohol, silanol, or alkanolamine.

Alkoxy-type derivative compounds and process for preparing alkoxy-type

A process is provided for preparing ceric hydrocarbyl silyloxides, which comprises transetherifying a ceric alkoxide with the silanol having the desired hydrocarbyl group and the desired number of hydroxyl groups under anhydrous conditions at a temperature within the range from about -30.degree. C. to about 200.degree. C., thereby displacing the aliphatic alcohol of the alkoxide and forming the ceric hydrocarbyl silyloxide of the silanol.

Process for the preparation of ceric hydrocarbyl silyloxides by

Described is a wood composition and a method for its preparation by treating wood with a first aqueous solution comprising one or more lanthanide derivatives, optionally rinsing with water and finally treating the wood with a second aqueous solution comprising one or more bases or one or more acid salts thereby precipitating a water-insoluble lanthanide complex within the wood. In addition, the method may be practiced by reversing the order of the treatment steps.

Lanthanide impregnated wood composition and method for permanently

Ceric hydrocarbyloxy nitrates having the general formula: ##STR1## are obtained by reaction of ceric ammonium nitrate with x moles of ammonia and an aliphatic, cycloaliphatic or aromatic alcohol having from two to twenty carbon atoms, and are useful in the preparation of ceric hydrocarbyl oxides difficult or expensive of access by other routes, and in synthesis of other organic ceric compounds.

Ceric hydrocarbyloxy nitrates and their use in organic synthesis

Described is a method of treating wood without pressure using compositions comprising aqueous solutions of one or more lanthanide derivative. Also described is a composition comprising wood and lanthanides or lanthanide derivatives.

Method of preserving wood with lanthanide derivatives

A process is provided for preparing colloidal dispersions of alcohol-dispersible association complexes of ceric dioxide and a hydroxyphenyl carboxylic acid having from about seven to about twenty carbon atoms in a molar ratio CeO.sub.2 /acid of at least about 6:1 which comprises:

Colloidal alcohol-dispersible association complexes of ceric dioxide and

Described is a method of treating wood using compositions comprising an organic solution (non-aqueous solution) of one or more lanthanide derivatives. Also described is a composition comprising wood and lanthanides or lanthanide derivatives. In one embodiment, the treatment occurs under vacuum.

Described is a composition of wood, or wood-derived matrix and one or more lanthanide elements of lanthanide element derivatives bonded to the matrix, a method of making the composition and a method of use. The composition is useful as an antifouling additive in paints.

Antifouling paints containing matrices cross-linked with lanthanides and

Described is a method of treating wood with compositions comprising aqueous solutions of one or more lanthanide derivatives, whereby the composition is contacted with the wood under vacuum.

Method of preserving wood with lanthanide derivatives lanthanide

A method for stabilizing diesel fuel for substantially reducing precipitation by adding to the diesel fuel an organometallic compound containing derivatives of one or more trivalent rare earth elements, excluding cerium.

Rare earth compositions for diesel fuel stabilization

A compound having the formula ##STR1## wherein R is one or more moieties selected from the group consisting of hydrogen and alkyl having from 1 to 20 carbon atoms, R.sup.2 is an alkyl group having from 1 to 20 carbon atoms, R.sup.1 is an alkyl group having from 1 to 20 carbon atoms, m is an integer from 0 to 3, y is an integer from 1 to 3, x and z are each an integer from 0 to 2, n and p are each an integer from 1 to 20, with the proviso that m+yp=4n, the sum of x, y and z is 3.

Ceric alkanolatoamines

A procedure for preparing anhydrous cerous nitrate ammonium nitrate complex comprising treating dried anhydrous ceric hexanitro ammonium complex (ceric ammonium nitrate) with a reducing agent such as ammonia whereby Ce.sup.+4 is reduced to Ce.sup.+3 under anhydrous conditions. The resulting Ce.sup.+3 species, a complex of Ce.sup.+3 nitrate and ammonia nitrate, can be used as a source of anhydrous Ce.sup.+3 ions.

Anhydrous cerous nitrate-ammonium nitrate complex and a process for its

The invention is a method for pressure treatment of wood using compositions comprising aqueous solutions of one or more lanthanide derivatives. Wood is immersed in a pressure vessel containing a lanthanide derivative composition, and hydrostatic pressure is applied. The treatment is carried out at temperatures not exceeding about 95.degree. C., and more preferably at between about 20.degree. C. and about 30.degree. C. Pressure should be greater than about atmospheric, and preferably about 10 psi to about 300 psi.

Growing community of inventors

Pottersville, NJ, United States of America

Peter S Gradeff