Ciba-geigy Corporation

Ciba Specialty Chemicals Corporation

Ciba-geigy Ag

Peter Mockli

Peter Rohringer

Rudolf Zink

Visvanathan Ramanathan

A process for dyeing keratin-containing fibers, comprises treating said fibers with a tinctorially effective amount of a dye of the formula ##STR1## where D is the radical of a diazo component of the formula ##STR2## R.sub.1 is an unsubstituted C.sub.1 -C.sub.4 alkyl, or C.sub.1 -C.sub.4 alkyl substituted with OH, C.sub.1 -C.sub.4 alkoxy, halogen, CN, amino, C.sub.1 -C.sub.4 monoalkylamino, or di-C.sub.1 -C.sub.4 alkylamino, R.sub.2 and R.sub.3 are independently of each other hydrogen, an unsubstituted C.sub.1 -C.sub.4 alkyl, or C.sub.1 -C.sub.4 alkyl substituted with OH, C.sub.1 -C.sub.4 alkoxy, halogen, CN, amino, C.sub.1 -C.sub.4 monoalkylamino, or di-C.sub.1 -C.sub.4 alkylamino, or R.sub.3 and R.sub.2, together with the nitrogen and carbon atoms joining them together form a 5- or 6-membered ring, R.sub.5 is hydrogen, C.sub.1 -C.sub.4 alkoxy, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -Calkylcarbonylamino, or R.sub.5 and R.sub.2, together with the nitrogen and carbon atoms joining them together form a 5- or 6-membered ring, and An.sup..theta. is a colorless anion.

Processes for dyeing keratin-containing fibres with cationicazo dyes

Keratin-containing fibres, in particular human hair, are dyed using dyes of formulae (1) to (6) indicated in claim 1. These dyes make it possible to dye by the trichromatic principle even in dark shades.

Process for dyeing keratin-containing fibres with cationic dyes

The cationic imidazole azo dyes of the formulae ##STR1## in which A and A.sub.1 independently of one another are each a radical of the formula ##STR2## Z is the radical of an aliphatic or aromatic diamine, R.sub.1 and R.sub.2 are each hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or, together with the two nitrogen atoms to which they are attached and with Z, form a 5-, 6- or 7-membered ring, X is the radical of a bridging member, n is 2, 3 or 4, Z.sub.1 is the radical of an aromatic diamine, Z.sub.2 is the radical of an aliphatic diamine, KK is the radical of a coupling component, R.sub.3 and R.sub.4 are each hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl, R.sub.5 and R.sub.6 independently of one another are each hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and An.sup..crclbar. is a colorless anion, are particularly suitable for the dyeing of paper in red or violet shades having good fastness properties.

Cationic imidazole azo dyes

A pressure-sensitive or heat-sensitive recording material essentially comprising in its color reactant system

Pressure-sensitive or heat-sensitive recording material

Methine-azo compounds of the formula ##STR1## in which A is the complement to a heterocyclic 5- or 6-membered ring which has a quaternized N atom as a ring member, which can contain further hetero atoms and which can be substituted and/or fused with carbocyclic or heterocyclic rings, R is hydrogen, cyano or C.sub.2 -C.sub.3 -alkylene which is bonded to an N atom of ring A to form a 5- or 6-membered ring, B is substituted or unsubstituted phenylene or naphthylene, X.sup..crclbar. is an anion and KK is the radical of a coupling component of the benzene series, of the naphthaline series or of the heterocyclic series, with the provisos that (a) if A is the complement to a quaternized, substituted or unsubstituted pyridine, quinoline or indolenine radical, KK is not the radical of a substituted or unsubstituted phenol, sulfo-free naphthol, naphthylamine, aniline, quinoline, isoquinoline, pyrazole or indole coupling component and (b) if A is the complement to a quaternized, substituted or unsubstituted benzothiazole or pyrimidine radical, KK is not a substituted or unsubstituted phenol or aniline coupling component. These compounds can be used as dyes for dyeing or printing for example polyacrylonitrile, acid-modified polyester and in particular paper.

Methine-azo compounds containing cyclic cationic ammonium groups

Methine-azo compounds of the formulae ##STR1## in which A is the complement to a heterocyclic 5- or 6-membered ring which has a quaternized N atom as a ring member, which can contain further hetero atoms and which can be substituted and/or be fused with carbocyclic or heterocyclic rings,

Methine-azo compounds containing cyclic ammonium groups

Novel water-soluble triazine compounds of the formula ##STR1## in which D and D.sub.1 independently of one another are radicals of diazo components, R and R.sub.1 independently of one another are hydrogen or C.sub.1 -C.sub.4 -aklyl, X is a monosubstituted or disubstituted amino group, a C.sub.1 -C.sub.4 -alkoxy group or an aryloxy group, the symbols Y are basic or cationic groups, which can be identical or different, l is 2, 3, 4, 5 or 6 and n is 0 or 1, and the number of basic and/or cationic groups Y in the molecule must be equal to or greater than the number of SO.sub.3 H groups are useful as dyes for dyeing and printing textile materials, leather and in particular, paper. The dyeings have good general fastness properties and the effluents remain colorless.

Basic water-soluble bis-(.beta.-azo-.alpha.-naphtholamino)-triazine

There are described novel dyes of the formulae ##STR1## in which R.sub.1 and R.sub.2 independently of one another are each hydrogen, unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl, and R.sub.1 and R.sub.2 together with the nitrogen atom, and optionally with the inclusion of further hetero atoms, can also form a 5- to 7-membered heterocycle, or one of the radicals R.sub.1 or R.sub.2 can be linked with the carbon atom, in the o-position with respect to the amino group, of the ring A to form a fused-on, saturated, unsubstituted or substituted 5- or 6-membered ring,

Cyanogenation of benzopyrones and naphthopyrones

Novel dyes, their production and their use

2-(Oxo, or thio)-3-substituted 1,3-benzothiazolyl-4-cyano-7-substituted

There are described novel dyes of the formulae ##STR1## in which R.sub.1 and R.sub.2 independently of one another are each hydrogen, unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl, and R.sub.1 and R.sub.2 together with the nitrogen atom, and optionally with the inclusion of further hetero atoms, can also form a 5- to 7-membered heterocycle, or one of the radicals R.sub.1 or R.sub.2 can be linked with the carbon atoms, in the o-position with respect to the amino group, of the ring A to form a fused-on, saturated, unsubstituted or substituted 5- or 6- membered ring,

Substituted benzopyran compounds

Dye mixtures containing at least two dyes of the formula (1) ##STR1## wherein R is hydrogen, methyl or ethyl, and n is an integer from 2 to 4, exhibit on synthetic textile material a build-up which is considerably better than that of the individual dyes.

Dye mixtures of anthraquinone dyes

The invention relates to transfer printing supports printed with a design which vaporizes in the temperature range from 180.degree. to 210.degree. C., and also to a process for printing synthetic planar textiles using such supports. The transfer printing supports contain, as red component, a 1-amino-4-hydroxyanthraquinone or -4-aminoanthraquinone compound which does not contain sulfo and carboxyl groups and which carries in the 2-position of the anthraquinone nucleus an alkoxy group which contains at least one fluorine atom and preferably at least three fluorine atoms.

Transfer printing supports and dyes for their manufacture: fluoroalkoxy

The invention relates to a process for printing flat-surface structures made from synthetic man-made or regenerated man-made polymer materials, for example polyester, polyacetate and preferably polyacrylonitrile fibres, by transfer printing, by means of auxiliary carriers which are printed with printing inks or printing pastes using dyes of the formula I ##STR1## wherein N IS 0 OR 1,

Transfer dyes and transfer printing process

A process for the dyeing of paper material from an aqueous medium, comprising the use of at least one water-soluble dye of the formula ##STR1## wherein Py represents a pyridyl group of the formula ##STR2## R.sub.1 represents lower alkyl, substituted lower alkyl, allyl, or benzyl, R.sub.2 represents hydrogen, halogen, methyl or ethyl,

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Schonenbuch, Switzerland

Peter Mockli