Bayer Aktiengesellschaft

Ec Erdolchemie Gmbh

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Ec Erdoelchemie Gmbh

Ingal International Gallium Gmbh

Peter M Lange

Alfred Mitschker

Reinhold M Klipper

Harold Heller

Bernhard Schleppinghoff

Hans-Josef Buysch

Karlheinz Wolf

Joachim Wolff

Jens Herwig

Werner Struver

Friedrich Martinola

Hans-Volker Scheef

Herbert Corte

Otto Netz

Erich Rauenbusch

Christian Golker

Bruno Schulwitz

Rudolf Merten

Klaus Sasse

Kirkor Sirinyan

Martin Scheer

Herbert Voege

Berthold Keggenhoff

Heinrich Krimm

Siegfried Oeckl

Gunther Ellendt

Heinrich F Moeschler

Thomas Weise

Hubert Rast

Peter Mues

Friedrich Werner

Jochen Koll

Gerhard Zoebelein

Marcel Petinaux

Christian Gabel

Arundev H Naik

Hans-Karl Soest

Hans Karl Haak

Gunter Siegers

Heiko Hoffmann

Hans-Joachim Kramer

Andries P Van Der Meer

Otto Telle

Werner Horlitz

Hans-Ludwig Niederberger

Gunter Lossmann

Cornelius J Smit

Paul Schaffers

Heinrich-Ferdinand Moeschler

Wolfgang Kreiss

A propellant system for launching a large-caliber projectile includes a propellant having at least three partial charges. The first partial charge is adapted to acceleration requirements of the projectile; the second partial charge has a higher combustion velocity than that of the first partial charge; and the third partial charge has a lower combustion velocity than that of the first partial charge. The propellant system further includes an electric energy supply and control device connected to the propellant for igniting the propellant. The electric energy supply and control device has a plasma generator for affecting a combustion behavior of the propellant such as to obtain for said first partial charge, after ignition of the propellant, a maximum gas pressure level of always the same magnitude independently from an initial propellant temperature, and to obtain, for the third partial charge, a conversion such as to prolong the maximum gas pressure level in a predeterminable manner.

Propellant for large-caliber ammunition

Known antibacterial quinolonecarboxylic acid derivatives such as ciprofloxacin are administered to animals in their food in the form of weak cation exchangers loaded therewith. The taste is much improved and the animals accept the material more readily.

Preparation and use of ion exchange resins loaded with

In the removal of pure aromatics from aromatic-containing hydrocarbon mixtures by liquid-phase extraction or extractive distillation using a selective solvent, the specific cost of separation can be reduced at the same yield of aromatics or the yield of aromatics can be increased at the same specific cost of separation if the liquid-phase extraction or the extractive distillation is carried out in the presence of a reactive solid. At the same time, substantially aromatic-free raffinates are obtained.

Process for removing pure aromatics

Tert.-olefins are obtained in high purity by cleavage of their alkyl ethers, when the catalysts used for this purpose are styrene/divinylbenzene resins which contain sulphonic acid groups and have a macroporous structure and the polymer matrix of which has an internal surface area of at least 400 m.sup.2 /g, a pore volume (porosity) of 0.6-2.5 ml/g and a mean pore diameter of 40-1000 .ANG.. These catalysts show long service lives.

Process for the preparation of tert.-olefins

A process for the preparation of a bifunctional anion exchange resin by partial quaternization of a weakly basic anion exchanger containing tertiary amino groups which process comprises (a) partially loading the weakly basic anion exchanger with a strong acid and (b) quaternizing the partially loaded anion exchanger by means of a customary alkylating agent.

Process for the preparation of bifunctional anion exchange resins, new

The invention relates to a process for preparing anion exchangers based on crosslinked, water-insoluble organic polymers containing aromatic nuclei, in which, in the first step, N-hydroxymethylphthalimide is produced by reaction of phthalimide with aqueous formaldehyde solution in swelling agents in the presence of bases; if desired, this N-hydroxymethylphthalimide is converted in a 2nd step to the bis)phthalimidomethyl)ether or an ester of N-hydroxymethylphthalimide; said polymers are aminomethylated wtih N-hydroxy-methylphthalimide, bis)phthalimidomethyl) ether or an ester of N-hydroxymethylphthalimide in the presence of Friedel-Craft catalysts and swelling agents and the amidomethylated polymers are finally saponified to form the aminomethylated polymers, wherein, in the first reaction step, the base used for producing N-hy-droxymethylphthalimide is sodium hydroxide solution and this sodium hydroxide solution is added in such an amount and at such a rate that the reaction of phthalimide with formaldehyde takes place in the pH range of 5 to 6.

Process for preparing synthetic resins having anion exchanger properties

In the process for recovering gallium from aqueous, alkaline solutions by adsorption of the gallium on to bead-polymerized synthetic resins impregnated with 8-hydroxyquinolines and elution thereof with aqueous acids, the synthetic resins employed according to the invention are macroporous polydivinylbenzene or macroporous divinylbenzene copolymers which have been obtained by bead polymerization of divinylbenzene or mixtures of aromatic mono-, di- and/or trivinylbenzenes containing at least 50% by weight of divinylbenzene, in the presence of methyl isobutyl ketone, and which have been loaded with 160-190 g of Kelex 100 per liter of resin; in addition the resin is washed with sodium hydroxide solution after the elution step and before the commencement of each individual service cycle.

Process for recovering gallium

The invention relates to new bead-shaped crosslinked macroporous copolymers containing epoxide groups and basic amino groups, which are obtainable by reacting polymerizable glycidyl compounds, before or during free radical bead polymerization, which is carried out in the presence of agents which impart porosity and, if appropriate, with the addition of polyvinyl compounds which can be polymerized by free radical polymerization, with amines which are capable of reacting with at least two epoxide groups, a process for their preparation and their use, for example, for binding biologically active substances, for the preparation of strongly basic anion exchangers and hydrophilic chromatography resins for biomaterials.

Bead-shaped crosslinked copolymers containing epoxide groups and basic

In the purification of acarbose by contacting an acarbose-containing solution with a cation exchanger to adsorb the acarbose, eluting the ion exchanger and collecting an eluate fraction enriched in purified acarbose, the improvement wherein the cation exchanger is a polymer obtained by polymerizing an aromatic compound possessing at least one vinyl group and at least one hydrophilic monomer in the presence of a solvent for the monomer which is a precipitant for the crosslinked polymer formed, isolating the resistant polymer, and sulphonating the polymer in the presence of a swelling agent for the polymer. The invention gives sharp separation and other processing advantages.

Process for the purification of acarbose with polymers

A new method of diazotization consists in using as the diazotizing agent in an aqueous, aqueous organic or organic medium the system comprising salt of nitrous acid+acid insoluble in the reaction medium, in particular organic or inorganic cation exchangers having acid groups. The diazonium salt solutions thus prepared are immediately reacted with coupling components to give azo dyestuffs, the insoluble acid and/or its salt being separated off before or after the coupling.

Process for preparing aromatic diazonium salts by diazotation of amines

Polyisocyanates are produced by reacting a polyamide solution with a phosgene solution. After the product polyisocyanate has been recovered, the solvent or a portion of the solvent employed is treated with crosslinked polymers insoluble in the solvent which polymers contain primary and/or secondary alcoholic hydroxyl groups and/or primary and/or secondary amino groups. After treatment, the polymer and any reaction products are removed. The solvent may then be reused. Preferred solvents are chlorobenzene and o-dichlorobenzene. The preferred polymers are bead polymers or bead copolymers of (meth)acrylic acid or styrene/divinyl benzene copolymer.

Process for the production of polyisocyanates

The invention relate to a process for reducing the wash water required by weakly basic anion exchangers containing primary and/or secondary amino groups when fed with water containing carbon dioxide; in accordance with the process the exhausted, weakly basic anion exchangers are treated with dilute aqueous mineral acids before being regenerated.

Process for reducing the wash water requirement of weakly basic anion

Stable, concentrated aqueous solutions of, in particular, anionic reactive dyestuffs are obtained in a comparatively simple manner by freeing from salts, preferably by means of membrane separation processes, solutions of these substances just as they are obtained in the course of synthesis, and by replacing, with the aid of ion exchangers, the cations which cause sparing solubility.

Process for the preparation of concentrated solutions of anionic

The invention relates to a new process for the preparation of strongly acid cation exchangers loaded with catalytically active metals by loading the cation exchangers with a solution of a salt of the catalytically active metal and reducing the cation exchangers loaded with metal ions, according to which the loading of the cation exchangers is carried out at temperatures from 50.degree. to 120.degree. C. and formic acid is used as the reducing agent; the invention also relates to the catalyst resins which can be obtained by the process.

Catalyst resins and process for their preparation

In the purification of acarbose by contacting an acarbose-containing solution with a cation exchanger to adsorb the acarbose, eluting the ion exchanger and collecting an eluate fraction enriched in purified acarbose, the improvement wherein the cation exchanger is a polymer obtained by polymerizing an aromatic compound possessing at least one vinyl group and at least one hydrophilic monomer in the presence of a solvent for the monomer which is a precipitant for the crosslinked polymer formed, isolating the resistant polymer, and sulphonating the polymer in the presence of a swelling agent for the polymer. The invention gives shapr separation and other processing advantages.

Polymers for the purification of acarbose

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Leverkusen, Germany

Peter M Lange