Sabic Global Technologies B.v.

Shpp Global Technologies B.v.

Peter Johnson

Robert Russell Gallucci

Jean-Francois Morizur

Amanda Marie Flores

Paul Dean Sybert

Thomas L Evans

James Franklin Hoover

Andrew S Frazee

Roy Ray Odle

Manojkumar Chellamuthu

Dadasaheb V Patil

Hee Won Kong

Timothy Edward Long

Mark Alan Sanner

Matthew L Kuhlman

Franklin Ehrensbeck

James Patrick Schulte, Ii

Kwan Hongladarom

James Francklin Hoover

A poly(etherimide) includes repeating units derived from polymerization of a biphenol dianhydride and an organic diamine. A method of making the poly(etherimide) includes contacting the biphenol dianhydride and the organic diamine under conditions effective to provide a poly(etherimide). The poly(etherimide) can be useful in a variety of articles, for example in an optoelectronic component.

Poly(etherimide), method for the manufacture thereof, and articles comprising the poly(etherimide)

A method of making polyetherimide comprising reacting a first diamine having four bonds between the amine groups, a second diamine having greater than or equal to five bonds between the amine groups, 4-halophthalic anhydride and 3-halophthalic in the presence of a solvent and a polymer additive to produce a mixture comprising 3,3'-bis(halophthalimide)s, 3,4&#x2032;-bis(halophthalimide)s, 4,4&#x2032;-bis(halophthalimide)s, solvent and the polymer additive wherein the molar ratio of 3-halophthalic anhydride to 4-halophthalic anhydride is 98:02 to 50:50 and the molar ratio of the first diamine to the second diamine is 98:02 to 02:98; and reacting the mixture with an alkali metal salt of a dihydroxy aromatic compound to produce a polyetherimide having a cyclics content less than or equal to 5 weight percent, based on the total weight of the polyetherimide, wherein the polymer additive dissolves in the solvent at the imidization reaction temperature and pressure.

Methods of manufacture for polyetherimide

A polyimide composition includes 1 to 99 weight percent, preferably 70 to 99 weight percent, more preferably 75 to 95 weight percent of a first polyimide; and 1 to 99 weight percent, preferably 1 to 30 weight percent, more preferably 2 to 25 weight percent of a second polyimide, wherein the first polyimide and the second polyimide are different, and wherein the polyimide composition has a melt flow rate that is greater than a melt flow rate of the first polyimide and less than a melt flow rate of the second polyimide; an apparent viscosity that is less than an apparent viscosity of the first polyimide and less than an apparent viscosity of the second polyimide; and a notched Izod impact strength that is greater than a notched Izod impact strength of the first polyimide and greater than a notched Izod impact strength of the second polyimide.

Linear and branched polyimide composition

A branched polyimide of the formula (I) wherein G is a group having a valence of t, present in an amount of 0.01 to 10 mol %, or 0.05 to 5 mol %, or 0.1 to 4 mol %, or 0.1 to 3 mol %, each of Q, M, D, V, and R are as defined herein, q is 0 or 1, m is 0 or 1, d is 0 or 1, p is 1 or 2, t is 2 to 6, preferably 2 to 4, and each n is independently the same or different, and is 1 to 1,000, provided that the total of all values of n is greater than 4, wherein the branched polyimide has a zero-shear viscosity in a range from 500 to 15,000 Pa&#xb7;s, a rheology ratio of 1.1 to 5, and a strain hardening ratio of 1 to 6. 

Compositions and articles made from branched polyetherimides

Articles having improved flame retardance and chemical resistance properties can be made from blends containing a cross-linkable polycarbonate resin having repeating units derived from a dihydroxybenzophenone. Predictive equations can be used to relate properties of the blend and the polycarbonate resin to the final properties of the article, and permit design of articles with desired combinations of properties.

Processes for designing cross-linkable polycarbonates and articles formed therefrom

Polycarbonate articles having improved properties due to their substantially cross-linked nature are disclosed. The substantially cross-linked articles are formed by forming a product from a polymeric composition comprising a cross-linkable polycarbonate resin containing a photoactive group derived from a benzophenone, and exposing the formed product to an effective dosage of ultraviolet radiation to cause substantial cross-linking throughout the article. Such cross-linking can also be used to obtain films having good scratch resistance properties.

Substantially crosslinked polycarbonate articles

Crosslinkable polycarbonate resins having improved properties are disclosed. The crosslinkable polycarbonate resins are formed from a reaction of at least a benzophenone, a first dihydroxy chain extender, and a carbonate precursor, and may include a second dihydroxy chain extender as well.

Crosslinkable polycarbonate resins

Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive that is a cross-linkable polycarbonate resin containing a photoactive group derived from a dihydroxybenzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.

Methods for improving chemical and flame resistance with multi-functional photoactive additives

Processes for increasing the chemical resistance of a surface of a formed article are disclosed. The formed article is produced from a polymeric composition comprising a photoactive additive containing photoactive groups derived from a monofunctional benzophenone. The surface of the formed article is then exposed to ultraviolet light to cause crosslinking of the photoactive additive and produce a crosslinked surface. The crosslinking enhances the chemical resistance of the surface. Various means for controlling the depth of the crosslinking are also discussed.

Processes for enhancing flame retardance and chemical resistance of polymers

Photoactive additives, such as cross-linkable polycarbonate resins, are disclosed. The additive is formed from the reaction of a monohydroxybenzophenone, a dihydroxybenzophenone, a diol chain extender, and one or more linker moieties having functional groups that react with the phenolic groups on the other ingredients. If desired, a secondary linker moiety and/or an end-capping agent can be used. When added to a base polymeric resin, the photoactive additive permits crosslinking when exposed to ultraviolet light.

Photoactive additives with photoactive monomers and endcaps

Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive containing a photoactive group derived from a monofunctional benzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.

Blends containing photoactive additive

Processes for increasing the chemical resistance of a surface of a formed product are disclosed. The formed product is produced from a polymeric composition comprising a photoactive additive containing photoactive groups derived from a dihydroxybenzophenone. The surface of the formed product is then exposed to ultraviolet light to cause crosslinking of the photoactive additive and produce a crosslinked surface. The crosslinking enhances the chemical resistance of the surface. Various means for controlling the depth of the crosslinking are also discussed.

Photoactive additives are disclosed. The additive is formed from the reaction of a dihydroxybenzophenone, one or more linker moieties having functional groups that react with the phenolic groups, a diol chain extender, and an end-capping agent. If desired, a secondary linker moiety can be used. When added to a base polymeric resin, the photoactive additive permits crosslinking when exposed to ultraviolet light.

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Evansville, IN, United States of America

Peter Johnson