Bayer Aktiengesellschaft

Peter Heitkamper

Klaus Konig

Kurt Findeisen

Wilhelm Brandes

Albrecht Marhold

Gerd Hanssler

Bernd-Wieland Kruger

Klaus Sasse

Rudolf Fauss

Josef Pedain

Stefan Penninger

Kuno Wagner

Klaus-Helmut Muller

Manfred Schmidt

Hartmut Knofel

Manfred Schonfelder

Rudolf Sundermann

Peter Fuhrmann

Johannes Koster

Reinhard Freimuth

Helmut Porkert

Gunther Hammen

The present invention relates to aqueous compositions containing

Aqueous coating adhesive and sealant compositions containing

The present invention relates to an improved process for the preparation of toluidines. This process comprises the reductive deamination of 2,3-diaminotoluenes and/or 3,4-diaminotoluenes in the presence of one or more iron oxide catalyst.

Process for the preparation of toluidines

Fungicidal substituted aminophenyl carbamates of the formula ##STR1## in which X represents --CO--NR.sup.8 R.sup.9 ; --CO--OR.sup.9 ; --CO--SR.sup.9 ; --CO--R.sup.10 ; --SO.sub.2 R.sup.9 or hydrogen, in which

Pesticidal substituted aminophenyl carbamates

The present invention is directed to a diisocyanate which corresponds to the formula ##STR1## The present invention is also directed to the preparation of this diisocyanate and to its use for the production of polyisocyanate polyaddition products.

Diisocyanate, a process for its production and its use

A process for the preparation of 4-amino-1,2,4-triazol-5-one of the formula ##STR1## in which R is alkyl, comprising in a first step reacting phosgene with an acylhydrazide of the formula ##STR2## to produce an oxadiazolinone of the formula ##STR3## and in a second step reacting the oxadiazolinone with hydrazine hydrate.

Preparation of 4-amino-1,2,4-triazol-5-ones

Fungicidal substituted aminophenyl carbamates of the formula ##STR1## in which X represents --CO--NR.sup.8 R.sup.9 ; --CO--OR.sup.9 ; --CO--SR.sup.9 ; --CO.sup.R.sup.10 ; --SO.sub.2 R.sup.9 or hydrogen, in which

Substituted aminophenyl carbamates

.alpha.-(4-isocyanatophenoxy)-.psi.-(4-isocyanato-3-methyl-phenoxy)-alkanes and mixtures thereof with the corresponding methyl-free and/or dimethyl substituted diisocyanates are made by phosgenating the corresponding diamine(s). These diisocyanates do not form a precipitate when reacted with a polyol and produce polyurethanes having outstanding properties.

Diisocyanates, a process for their production and their use in the

The present invention is directed to 4,4'-diisocyanato phenylbenzylether, its method of production by reaction of the corresponding diamine with phosgene and the use of the diisocyanate for the production of polyisocyanate polyaddition products, preferably polyurethane plastics.

4,4'-diisocyanto-phenylbenzylether, a process for the preparation

Bis-(4-isocyanatophenoxy)-alkanes corresponding to the formula ##STR1## in which R represents a divalent, saturated aliphatic hydrocarbon radical having from 2 to 6 carbon atoms with at least two carbon atoms between the two ether oxygen atoms, and

Bis-(4-isocyanatophenoxy)-alkanes and a process for the production

A process for the preparation of urethanes. Urethanes having the general formula R.sub.1 (NHCOOR.sub.2).sub.n are reacted with an alcohol at a temperature of 120.degree. to 400.degree. C. in amounts such that, for every mol of the urethane, at least one mol of the alcohol is present. R.sub.1 is a radical obtained by removing the isocyanate groups from an n-functional organic isocyanate, which isocyanate has a boiling point greater than 100.degree. C. at atmospheric pressure. R.sub.2 is a radical obtained by removing the hydroxyl group from a monohydric alcohol which has a boiling point greater than 140.degree. C. at atmospheric pressure.

Process for the preparation of urethanes

Low molecular weight N- and O-substituted diurethanes and/or polyurethanes are prepared by reacting a diamine and/or polyamine containing a primary amino group with an N-aryl-0-alkyl urethane in the presence of at least one high boiling alcohol. This reaction may be carried out at a temperature of from 180.degree. to 350.degree. C. and a pressure of approximately 0.1 to 1,500 mbar. The arylamine corresponding to the N-ary-0-alkyl urethane which forms during this reaction is continuously removed from the reaction mixture.

Process for the preparation of N- and O-substituted diurethanes and/or

A process for the preparation of N,O-disubstituted urethanes. Urea or polyurets, primary amines and alcohols are reacted at 120.degree.-350.degree. C. in the presence of N-substituted urethanes and/or N-mono- or N,N'-disubstituted ureas or polyureas. In a preferred embodiment, the reactants further include catalysts known to be useful in esterification of carboxylic acids. The urethanes produced in accordance with this process are particularly useful as starting materials for preparation of isocyanates.

Process for the preparation of N,O-disubstituted urethanes useful for

A process for the preparation of N,O-disubstituted urethanes. Primary amines and alcohols are reacted with organic compounds having carbonyl groups at 120.degree. to 350.degree. C. Suitable carbonyl-containing compounds include N-unsubstituted urethanes. N-mono-substituted, N,N'-disubstituted ureas, or polyureas may be used in combination with the N-unsubstituted urethane. The product urethanes are particularly suitable for the preparation of isocyanates.

Process for the preparation of N,O-disubstituted urethanes suitable as a

A carbamic acid ester corresponding to the formula R.sup.1 --NH--CO--OR.sup.2 is thermally cleaved to form isocyanate R.sup.1 --NCO and alcohol R.sup.2 --OH fractions. This cleavage is accomplished by boiling the carbamic acid ester, condensing the vapor given off in a first fractionation column, and condensing the vapor from the first fractionation column in a second fractionation column. The boiling of the carbamic acid ester is carried out in a manner such that the average dwell time in the reaction vessel is from 1 to 20 hours, the temperature is from 160.degree. to 260.degree. C. and the pressure is from 0.001 to 2 bar. The isocyanate fraction obtained by this cleavage process may be used as a starting material for a transurethanation reaction in which a lower boiling isocyanate R.sup.3 --NCO is produced. The radicals R.sup.1, R.sup.2, and R.sup.3 are defined herein.

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Dormagen, Germany

Peter Heitkamper