Chemische Werke Huls Aktiengesellschaft

Peter Hegenberg

Ferdinand List

Rudolf Strobele

Hermann Rohl

Gerhard Hellemanns

Werner Eversmann

Otto Rauhut

Crude 1,10-decanedicarboxylic acid produced by the nitric acid oxidation at 20.degree.14 60.degree. C. of cyclododecanone, cyclododecanol or a mixture thereof can be purified by distillation to a purity suitable for use in the production of polyamides and polyesters by reducing prior to distillation, e.g., by heating to 70.degree.-90.degree. C., the organically bound nitrogen content and as required the nitric acid content, e.g., by washing, and water content thereof so that the sample which is distilled has maximum contents thereof of 0.05%, 0.02% and 0.1% by weight, respectively, and distilling the pre-purified sample at a sump temperature of 215.degree.-225.degree. C. and at a pressure of 0.5 - 2 torr.

Process for the purification of 1,10-decanedicarboxylic acid

Apparatus for the continuous production of saturated aliphatic dicarboxylic acids by the catalyzed nitric acid oxidation of the corresponding cycloalkanols and cycloalkanones with recirculation of the reaction sludge and the reaction gases, which comprises cooling the reaction sludge by passing it through the tubes of a multiple tube heat exchanger, separating the reaction gases downstream of the heat exchanger, and dispersing the recycled portion of the reaction gases in the reaction sludge upstream of the heat exchanger, in a volume amount 0.1 to 2.0 times the volume of the reaction sludge circulating per unit time and in a pressure ratio of initial gas pressure to pressure in the circulation reactor at the gas feed point of (x + 0.25) : x to (x + 1.5) : x, wherein x is the pressure at the gas feed point, to form a homogeneously dispersed three-phase mixture of the recycled reaction gases in the reaction sludge in the tubes of the heat exchanger.

Apparatus for the continuous production of saturated aliphatic

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Marl, Germany

Peter Hegenberg