3m Innovative Properties Company

3m Innovative Properties

Peter D Condo

David Scott Thompson

Timothy J Hebrink

William Ward Merrill

Catherine A Leatherdale

Steven D Solomonson

John James Stradinger

Richard John Pokorny

William J Schultz

Michael A Johnson

Joseph D Rule

Richard C Allen

Ryan M Braun

Ronald J Tabar

James E Thorson

Andrew John Ouderkirk

John Allen Wheatley

Andrew T Ruff

Kristin LaVelle Thunhorst

Chad A Haraldson

Yaoqi Joe Liu

Jeremy O Swanson

Milton H Andrus, Jr

Stephen A Johnson

Wendy L Thompson

Jung-Sheng Wu

Elisa M Cross

Susan L Kent

Derek W Patzman

Joseph A Gangi

Michael F Weber

Timothy J Nevitt

Kevin R Schaffer

Charles L Bruzzone

Emily S Goenner

Clark Ivan Bright

Kevin M Hamer

D Scott Thompson

Karissa L Eckert

Evan Louis Breedlove

Joseph W Woody, V

Brant Ulrick Kolb

Olester Benson, Jr

Jayshree Seth

James M Nelson

Jimmie Rae Baran, Jr

Robert J Fleming

Neeraj Sharma

Michael D Determan

Lian Soon Tan

Mary I Buckett

Douglas P Goetz

Lyudmila A Pekurovsky

Peihui Zhang

Mark McCormick

Walter Stoss

Grant F Tiefenbruck

Janet R Kirkman

Edward John Anderson

Steven John Pachuta

Matthew N Archibald

Mark Mccormick

Jimmie Baran

Jr Milton H Andrus

A display film includes a transparent cross-linked polyurethane acrylate layer. The transparent cross-linked polyurethane acrylate layer having a glass transition temperature of 10 degrees Celsius or less and a Tan Delta peak value of 0.5 or greater.

Polyurethane acrylate protective display film

A nanocomposite includes at least one polymer and metal oxide nanoparticles dispersed in the at least one polymer. Each polymer can have a number average molecular weight of at least 10000 grams/mole. The at least one polymer includes a first polymer including (meth)acrylic acid monomer units. The metal oxide nanoparticles are surface modified with a carboxylic acid silane surface modifying agent. An aqueous dispersion that can be used to make the nanocomposite and a method of making the nanocomposite is described.

Nanocomposites

Nanocomposites include metal oxide nanoparticles and (meth)acrylic acid polymers where the nanoparticles are surface modified with a carboxylic acid silane and where the (meth)acrylic acid polymer is at least partially neutralized. The compositions are transparent, with high transmission and low haze up to very high nanoparticle loading. The compositions also exhibit improved mechanical properties of impact resistance and tensile modulus.

Transparent elastomeric nanocomposites

Nanocomposite blends include metal oxide nanoparticles and at least two (meth)acrylic acid polymers where the nanoparticles are surface modified with a carboxylic acid silane and where the (meth)acrylic acid polymers are at least partially neutralized. The compositions are transparent, with high transmission and low haze up to very high nanoparticle loading. The compositions also exhibit improved mechanical properties of impact resistance and tensile modulus.

Transparent elastomeric nanocomposite blends

A hardcoat composition includes one or more multifunctional (meth)acrylate monomers, and a nanoparticle mixture dispersed within the one or more multifunctional (meth)acrylate monomers. The nanoparticle mixture includes a first population of semi-reactive nanoparticles having an average particle diameter in a range from 5 nm to 60 nm, and a second population of non-reactive nanoparticles having an average particle diameter in a range from 5 nm to 60 nm.

Flexible hardcoat

A hardcoat composition includes one or more multifunctional (meth)acrylate monomers, and a population of semi-reactive nanoparticles dispersed within the one or more multifunctional (meth)acrylate monomers. The population of semi-reactive nanoparticles have an average particle diameter in a range from 5 nm to 60 nm.

A hardcoat composition includes one or more multifunctional (meth)acrylate monomers, and a nanoparticle mixture dispersed within the one or more multifunctional (meth)acrylate monomers. The nanoparticle mixture includes a first population of semi-reactive nanoparticles having an average particle diameter in a range from 5 nm to 60 nm, and a second population of reactive nanoparticles having an average particle diameter in a range from 5 nm to 60 nm.

A hardcoat composition includes one or more multifunctional (meth)acrylate monomers, and a nanoparticle mixture dispersed within the one or more multifunctional (meth)acrylate monomers. The nanoparticle mixture includes a first population of reactive nanoparticles. The first population of reactive nanoparticles have an average particle diameter in a range from 5 nm to 60 nm, and a second population of non-reactive nanoparticles. The second population of non-reactive nanoparticles have an average particle diameter in a range from 5 nm to 60 nm.

A display film includes a transparent polymeric substrate layer and a transparent energy dissipation layer disposed on the transparent polymeric substrate layer. The transparent energy dissipation layer includes cross-linked polyurethane and a polyacrylate polymer. The transparent energy dissipation layer has a glass transition temperature of 27 degrees Celsius or less and a Tan Delta peak value of 0.5 or greater.

Dual cure protective display film

A display film includes a transparent glass layer having a thickness of 250 micrometers or less, or in a range from 25 to 100 micrometers. A transparent energy dissipation layer is fixed to the transparent glass layer. The transparent energy dissipation layer has a glass transition temperature of 27 degrees Celsius or less, a Tan Delta peak value of 0.5 or greater, or from 1 to 2 and a Young's Modulus (E') greater than 0.9 MPa over a temperature range of &#x2212;40 degrees Celsius to 70 degrees Celsius. In a preferred embodiment, the transparent energy dissipation layer comprises a cross-linked polyurethane layer or a cross-linked polyurethane acrylate layer.

Protective display film with glass

A display film includes a transparent polymeric substrate layer having a 0.2% offset yield stress greater than 110 MPa and a transparent aliphatic cross-linked polyurethane layer having a thickness of 100 micrometers or less disposed on the transparent polymeric substrate layer. The transparent aliphatic cross-linked polyurethane layer has a glass transition temperature in a range from 11 to 27 degrees Celsius and a Tan Delta peak value in a range from 0.5 to 2.5. The display film has a haze value of 2% or less.

Thin protective display film

A display film includes a transparent cross-linked polyurethane layer. The transparent cross-linked polyurethane layer having a glass transition temperature of 10 degrees Celsius or less and a Tan Delta peak value of 0.5 or greater.

Low Tg polyurethane protective display film

A display film comprises a transparent glass layer including two or more co-planar glass layer segments and a thickness defined by a first major surface and a second major surface opposing the first major surface being less than 500 micrometers; interstitial polymer material separating adjacent segments; and transparent energy dissipation layer having a glass transition temperature of 27 degrees Celsius or less and a Tan Delta peak value of 0.5 or greater and being disposed on the first major surface.

Segmented protective display film

A nanocomposite is provided including spherical pyrogenic silica nanoparticles dispersed in a curable resin or a curing agent. The nanocomposite contains less than 2% by weight solvent and less than 0.5% by weight dispersant based on the nanoparticle weight. A composite is also provided including from about 4 to 70 weight percent of spherical pyrogenic silica nanoparticles dispersed in a cured resin, and a filler embedded in the cured resin. Optionally, the composite further contains a curing agent. Further, a method of preparing a nanoparticle-containing curable resin system is provided including mixing from 10 to 70 weight percent of aggregated spherical pyrogenic silica nanoparticles with a curable resin to form a mixture. The mixture contains less than 2% by weight solvent and less than 0.5% by weight dispersant based on the nanoparticle weight. The method also includes milling the mixture in an immersion mill containing milling media to form a milled resin system including silica nanoparticles dispersed in the curable resin.

Nanocomposites containing spherical pyrogenic silica nanoparticles and composites, articles, and methods of making same

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Lake Elmo, MN, United States of America

Peter D Condo