L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude

Air Liquide Advanced Technologies U.S. LLC

L'air Liquide Société Anonyme Pour L'etude Et L'exploitation Des Procédés Georges Claude

Air Liquide Large Industries U.S. LP

Newvistas Capital, LLC

Paul Terrien

Jean-Pierre Tranier

Sudhir S Kulkarni

Yong Ding

David J Hasse

Arthur Darde

Edgar S Sanders, Jr

Pascal Marty

Edgar S Sanders

Bhadra S Grover

Michael A Turney

Mathieu Leclerc

Nicolas Chantant

Yasser Jebbari

Alex Augustine

Kevin Weatherford

Alain Guillard

Larry L Baxter

Alain Briglia

Jean-Marc Peyron

Antoine Hernandez

Richard Dubettier-Grenier

Christopher Hoeger

Philippe Court

Sandeep K Karode

Pierre-Philippe Guerif

Pascal Tessier

Trapti Chaubey

Ludovic Granados

Dennis A Vauk

Xavier Traversac

Solene Valentin

Frederick Lockwood

Solène Valentin

Cyril Defaye

Vincent Follaca

Purushottam V Shanbhag

Pascal J Tromeur

Martin Raventos

Youssef Tazi

A single compressor is used to separately compress permeate from cascaded first and second gas separation membrane-based separation units and residue from a fourth gas separation membrane-based separation unit in order to avoid too high a CO2 partial pressure in the compressed permeate. After the permeates from the first and second stages are compressed, the compressed stream is fed to a third gas separation membrane-based separation unit.

Integrated compression and membrane separation process for removal of CO2 from raw natural gas

A method and system for purification of helium and COfrom a stream containing at least Helium, CO2, nitrogen or methane uses a combination of cryogenic, membrane and adsorption technologies.

Method and system for purification of helium using cryogenic, membrane, and adsorption techniques

A method for separating a mixture containing at least nitrogen and methane by cryogenic distillation in a first column operating in a first pressure and a second column operating at a second pressure lower than the first pressure, the mixture being separated in the first column to form a gas enriched in nitrogen and a liquid enriched in methane, at least a portion of the gas enriched in nitrogen being at least partially condensed in a heat exchanger and returned to the first column, the gas enriched in nitrogen is sent into the heat exchanger by the bottom, ascends in a first series of passages of the exchanger and condenses therein at least partially, the liquid formed descending in these passages of the first series and exiting by the bottom of the exchanger.

Method for separating a mixture containing at least nitrogen and methane

A process for the separation of nitrogen from a feed stream containing at least methane and nitrogen, with a methane content between 4 and 12% mol. consists of at least the following steps: separation of the feed stream by means of a rubbery-type membrane to produce a permeate enriched in methane at a pressure greater than 2 bara and a non-permeate which is a nitrogen-enriched residue gas at a pressure greater than 2 bara and processing of the high-pressure residue gas in a cryogenic separation unit to produce a methane rich liquid and a nitrogen-enriched gas wherein the pressure of the membrane permeate is controlled as a function of the nitrogen concentration in the nitrogen-enriched gas.

Process to separate nitrogen from methane by permeation and cryogenic distillation

A process for purifying a gaseous feed stream of natural gas including methane, COand heavy hydrocarbons including step a): cooling the gaseous feed stream in a heat exchanger; step b): introducing the cooled stream into a phase-separating chamber to produce a liquid stream depleted in methane and enriched in heavy hydrocarbons and a gaseous stream; step c): separating the gaseous stream obtained from step b) in a first membrane producing at least one CO-enriched permeate stream and a residual stream enriched in methane; step d): introducing the residual stream obtained from step c) into a phase-separator to produce a liquid stream and a gaseous stream; step e): heating the gaseous stream obtained from step d) by introducing it into the heat exchanger used in step a) counter-currentwise with the feed stream thereby producing a gaseous stream depleted in COand enriched in methane.

Method for purifying natural gas using an economizer

A feed containing methane and nitrogen gas is processed in a three-stage membrane system, each stage of which is selective for methane over nitrogen. The methane enriched permeate from the first stage is removed as product gas. The methane-depleted residue from the second stage is purified in second and third cascaded stages to provide second and third permeates and second and third residues. The third stage permeate is recycled to the feed.

Membrane nitrogen rejection process and system

In a method for separating a mixture containing carbon dioxide, the mixture is cooled in a heat exchanger and partially condensed and a first liquid is separated from the mixture in a first system operating at low temperature comprising at least one first phase separator and a gas from the first system is treated in a membrane system to produce a permeate and a non-permeate, the gas from the first system being divided into two portions, a first portion being sent to the membrane system without being heated and a second portion being heated to at least an intermediate temperature of the heat exchanger and then sent to the membrane system without being cooled.

Apparatus and method for separating COat low temperature comprising a step of separation by permeation

An approach for separating a gaseous mixture includes a multi-stage membrane system in which a rubbery membrane is operated at a low temperature. Various streams are cooled and heated in a multi-fluid heat exchanger. In specific configurations, the multi-fluid heat exchanger is cooled by using no fluids other than fluids derived from the permeate and/or residue generated in the first membrane stage.

Cold membrane nitrogen rejection process and system

A process for producing biomethane by scrubbing a biogas feed stream includes introducing the feed gas stream into a pretreatment unit wherein a CO-depleted gas stream is partially separated from a COstream and an oxygen stream and is compressed to a pressure P1 above 25 bar abs. Subjecting the CO-depleted gas stream to cryogenic separation in a distillation column to separate a nitrogen stream and produce a CH-enriched stream, the distillation column comprising n plates, n being an integer between 8 and 100. Recovering a pressurized CH-enriched stream by pumping the CO-depleted gas stream to a pressure P2 above 25 bar absolute.

Method for distilling a gas stream containing oxygen

A process for purifying a feed gas including methane and heavy hydrocarbons, including: step a): cooling the feed gas in a heat exchanger; step b): introducing the resulting into a first phase separator to produce a liquid stream depleted in methane and enriched in heavy hydrocarbons and a gas stream; step c): separating the gas stream in a membrane from which a methane-enriched permeate stream and a partially condensed residue stream exit; step d): introducing the residue stream from step c) into a second phase separator vessel in order to produce a liquid stream and a gas stream; step e): introducing at least one portion of the gas stream resulting from step d) into a JT expansion means; and step f): heating at least one portion of the expanded stream in the heat exchanger used in step a) counter-current to the feed stream in order to cool the latter.

Method for separating a natural gas stream into a methane-enriched fraction and a fraction enriched in Cand higher hydrocarbons

A process for purifying a natural gas feed gas stream including methane and hydrocarbons, including step a): cooling the feed gas stream; step b): introducing the cooled stream into a first phase separator vessel in order to produce a liquid stream and a gas stream; step c): separating the gas stream resulting from step b) in a membrane unit from which a methane-enriched permeate stream and one partially condensed residue stream enriched in hydrocarbons exit; step d): introducing the residue stream resulting from step c) into a second phase separator vessel to produce a liquid stream and a gas stream; step e): introducing at least one portion of the liquid stream resulting from step d) into a JT expansion means; step f): heating at least one portion of the expanded by introduction into the heat exchanger used in step a) counter-current to the feed stream.

Method for purifying a natural gas stream

A process to produce at least carbon dioxide and carbon monoxide from a feed gas containing carbon dioxide, hydrogen and carbon monoxide; comprises separating at least part of the carbon dioxide from the compressed feed gas by partial condensation and/or distillation producing a carbon dioxide product and a carbon dioxide depleted stream, treating the carbon dioxide depleted stream in a treatment unit to produce a feed stream containing carbon monoxide and hydrogen, less rich in carbon dioxide than the carbon dioxide depleted stream and feeding at least part of the feed stream containing carbon monoxide and hydrogen to a separation unit operating at cryogenic temperatures to produce a carbon monoxide product.

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The apparatus for liquefying a gaseous stream received from a pipeline that is comprised predominantly of ethane and a relatively small amount of other components by using a mixed refrigerant refrigeration cycle loop incorporating heavy hydrocarbons, as well as a distillation column to remove constituents lighter than ethane. Prior to cooling in a main heat exchanger, the gaseous stream is split into two fractions. The main heat exchanger is configured to cool the first fraction before heading to the distillation column for separation therein. An expansion device expands the second fraction to produce a two phase fluid, which is separated in a gas/liquid separator, with the liquid fraction being introduced to the distillation column below the first fraction, and the gas fraction being cooled and then introduced to the distillation column at a point above the first fraction.

Apparatus for ethane liquefaction with demethanization

The process for liquefying a gaseous stream received from a pipeline that is comprised predominantly of ethane and a relatively small amount of other components by using a mixed refrigerant loop incorporating heavy hydrocarbons (butane, and/or pentane), as well as a distillation column to remove constituents lighter than ethane. Prior to cooling in a main heat exchanger, the gaseous stream is split into two fractions. The first fraction is cooled in the main heat exchanger and introduced to the distillation column. The second fraction is expanded to produce a two phase fluid, with the liquid fraction being introduced to the distillation column below the first fraction, and the gas fraction being cooled and then introduced to the distillation column at a point above the first fraction.

Method for ethane liquefaction with demethanization

In a process for the separation of a stream containing carbon dioxide, water and at least one light impurity including a separation step at subambient temperature, the feed stream is compressed in a compressor comprising at least two stages to form a compressed feed stream, the compressed feed stream is purified in an adsorption unit to remove water and form a dried compressed stream, the dried compressed stream or a stream derived therefrom is cooled to a subambient temperature and separated by partial condensation and/or distillation in a separation apparatus, liquid enriched in carbon dioxide is removed from the separation apparatus, the adsorption unit is regenerated using a regeneration gas and the regeneration gas is formed by separating, by permeation in a permeation unit, the dried compressed stream or a gas derived therefrom, the permeate of the permeation unit constituting the regeneration gas.

Process and apparatus for the separation of a stream containing carbon dioxide, water and at least one light impurity including a separation step at subambient temperature

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Philadelphia, PA, United States of America

Paul Terrien