Umicore Ag & Co Kg

Paul Spurk

Marcus Pfeifer

Thomas Kreuzer

Egbert Lox

Yvonne Demel

Nicola Soeger

Jürgen Gieshoff

Markus Koegel

Stephan Malmberg

Elena Mueller

Adolf Schäfer-Sindlinger

Barry Van Setten

Hendrik-David Noack

Tobias Kuhl

Egbert S J Lox

Gerald Jeske

Katja Adelmann

Wilfried Mueller

Michael Seyler

Olivier Teysset

Thomas Le Tallec

Stèphanie Frantz

Nicola Söger

Markus Pfeifer

Egbert SJ Lox

Elena Müller

Stephan Dipl-Ing Malmberg

The invention proposes a method for the purification of exhaust gases which are generated by a diesel engine with a charging turbine, and a special device for carrying out said method. The device comprises, in the flow direction of the exhaust gas, a dosing device for a reducing agent from a reducing agent reservoir (), an SCR catalytic converter (), an oxidation catalytic converter () and a diesel particle filter (). The system is particularly suitable for the purification of the exhaust gases of diesel vehicles in which engines with a turbocharger (charging turbine ()) and an exhaust-gas recirculation device are used, which engines generate exhaust gases which, in addition to carbon monoxide, hydrocarbons and particles, have nitrogen oxides with an NO/NOratio of between 0.3 and 0.7.

Method and device for the purification of diesel exhaust gases

The invention relates to a process for coating ceramic honeycomb bodies with a coating suspension containing, in a carrier liquid, catalyst components as solids and/or in dissolved form. The honeycomb bodies have parallel flow channels running through them. The walls of the flow channels generally have an open pore structure. To coat the channel walls and in particular also the interior surfaces of the pores with the coating suspension, it is proposed that the flow channels be temporarily alternately closed and the coating suspension be forced through the open pore structure of the channel walls. The coating is subsequently dried and calcined. To close the flow channels, it is possible to use thermally or chemically decomposable or soluble compositions which are decomposed or dissolved either during calcination or by means of a subsequent chemical treatment. The coated honeycomb bodies are preferably used for the purification of exhaust gases from automobiles.

Catalytically coated ceramic honeycomb bodies

The present invention relates to a catalytic converter which comprises a molecular sieve and a mixed oxide, and to a method for the selective catalytic reduction of nitrogen oxides in exhaust gases of diesel engines.

Catalytic converter for the selective catalytic reduction of nitrogen oxides in the exhaust gas of diesel engines

The invention relates to a catalyst for removal of nitrogen oxides from the exhaust gas of diesel engines, and to a process for reducing the level of nitrogen oxides in the exhaust gas of diesel engines. The catalyst consists of a support body of length L and of a catalytically active coating which in turn may be formed from one or more material zones. The material zones comprise selectively catalytically reductive (SCR-active) mixed oxide consisting of cerium oxide, zirconium oxide, rare earth sesquioxide and niobium oxide and optionally tungsten oxide. In addition, the material zones comprise at least one compound selected from the group consisting of barium oxide, barium hydroxide, barium carbonate, strontium oxide, strontium hydroxide, strontium carbonate, praseodymium oxide, lanthanum oxide, magnesium oxide, mixed magnesium/aluminum oxide, alkali metal oxide, alkali metal hydroxide, alkali metal carbonate and mixtures thereof. Noble metal may optionally also be present in the catalyst.

Catalyst for removing nitrogen oxides from the exhaust gas of diesel engines

The invention relates to a catalyst for removal of nitrogen oxides from the exhaust gas of diesel engines, and to a process for reducing the level of nitrogen oxides in the exhaust gas of diesel engines. The catalyst consists of a support body of length L and of a catalytically active coating which in turn may be formed from one or more material zones. The material zones comprise a copper-containing zeolite or a zeolite-like compound. The materials used include chabazite, SAPO-34, ALPO-34 and zeolite &#x3b2;. In addition, the material zones comprise at least one compound selected from the group consisting of barium oxide, barium hydroxide, barium carbonate, strontium oxide, strontium hydroxide, strontium carbonate, praseodymium oxide, lanthanum oxide, magnesium oxide, magnesium/aluminum mixed oxide, alkali metal oxide, alkali metal hydroxide, alkali metal carbonate and mixtures thereof. Noble metal may optionally also be present in the catalyst.

Method for catalytically coating ceramic honeycomb bodies

Soot filters for removing soot from the exhaust gas of lean-burn engines become blocked with progressive operating duration on account of the deposition of soot, and must therefore be regenerated at regular intervals. It has been found that reliable operation of the soot filter is possible only if an active regeneration is carried out from time to time by increasing the exhaust-gas temperature to the soot ignition temperature. For this purpose, an oxidation catalytic converter is usually arranged upstream of the soot filter, and the exhaust-gas temperature is increased by means of the catalytic combustion of additionally injected fuel. Here, the oxidation catalytic converter is subjected to high temperature loading and therefore ages very quickly. It has surprisingly been found that the ageing of the oxidation catalytic converter can be slowed if said oxidation catalytic converter is split into at least two separate catalytic converters and the distance between said separate catalytic converters is 2 to 30 mm.

Catalyst system and use thereof

The invention relates to a catalyst arrangement for purifying the exhaust gases of internal combustion engines operated under lean conditions. It is proposed that a thinwalled, porous carrier be coated on one side with a nitrogen oxide storage catalyst and on the other side with an SCR catalyst. When the exhaust gas is passed through the catalytic coatings and the support material, a significant improvement in the nitrogen oxide conversion is achieved compared to a series arrangement of the catalysts on separate carriers. Wall flow filters have been found to be useful as thin-walled carriers.

Catalyst arrangement and method of purifying the exhaust gas of internal combustion engines operated under lean conditions

An exhaust gas treatment unit for the selective catalytic reduction of nitrogen oxides under lean exhaust gas conditions which contains at least one catalyst with catalytically active components for selective catalytic reduction (SCR components). The exhaust gas treatment unit is characterised in that the catalyst also contains, in addition to SCR components, at least one storage component for nitrogen oxides (NOx components).

Exhaust gas treatment unit for the selective catalytic reduction of nitrogen oxides under lean exhaust gas conditions and a process for the treatment of exhaust gases

The present invention relates to a method of removing nitrogen oxides from the exhaust gas of a lean-burn internal combustion engine by selective catalytic reduction (SCR) using ammonia. The exhaust gas is routed first over a platinum-containing pre-catalyst and then over an SCR catalyst. The ammonia needed for the selective catalytic reduction is added to the exhaust gas upstream of the pre-catalyst at an exhaust-gas temperature below 250&#xb0; C., while it is supplied to the exhaust gas between the pre-catalyst and the SCR catalyst at an exhaust gas temperature above 150&#xb0; C. By adopting this procedure, a very large temperature range for the selective catalytic reduction with high nitrogen conversion rates is obtained.

Method of removing nitrogen oxides from the exhaust gas of a lean-burn internal combustion engine and exhaust-gas purification system therefor

A process for reducing the nitrogen oxides present in a lean exhaust gas from an internal combustion engine by selective catalytic reduction on a reduction catalyst using ammonia, wherein a fraction of the nitrogen monoxide present in the exhaust gas is oxidized to nitrogen dioxide before the exhaust gas, together with ammonia, is passed over the reduction catalyst. The reduction catalyst contains a zeolite exchanged with transition metals and oxidation of the nitrogen monoxide is performed in such a way that the exhaust gas contains 30 to 70 vol. % of nitrogen dioxide before contact with the reduction catalyst.

Process for reducing nitrogen oxides

Process and catalyst for reducing nitrogen oxides

The present invention provides an exhaust gas treatment unit for an internal combustion engine. A first catalyst unit produces ammonia from corresponding constituents in a rich exhaust gas composition. A second catalyst unit that is located downstream of the first catalyst unit temporarily stores the ammonia produced by the first catalyst unit in the presence of a rich exhaust gas composition. In the presence of a lean exhaust gas composition, the nitrogen oxides present in the exhaust gas are subjected to a reduction reaction using the temporarily stored ammonia as reducing agent. The exhaust gas treatment unit also contains a third catalyst unit that is located between the other two catalyst units, and oxidizes the nitrogen oxides present in the exhaust gas at lean exhaust gas conditions to a such an extent that 25 to 75 vol. % of the nitrogen oxides entering the second catalyst unit consist of nitrogen dioxide.

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Weiterstadt, Germany

Paul Spurk