Uniax Corporation

University of California

Paul Smith

Alan J Heeger

Yong Cao

Fred Wudl

Alejandro Andreatta

Jin-Chih Chiang

Jin Chiang

Shizuo Tokito

Jean C Wittmann

Jeffrey D Moulton

Optical quality transparent conductors such as bodies, films and coatings formed from substituted and unsubstituted polyanilines in nonconductive substrates such as polymers or polymer plus solvents with protonic acid are disclosed as are methods of forming such conductors from fluid forms of the polyaniline/substrate/acid mixtures.

Optical quality transparent conductors

Compositions of electrically conductive substituted and unsubstituted polyanilines in nonconductive substrates such as polymers or polymer plus solvents with protonic acids are disclosed as are methods of forming such compositions and use of same to form conductive articles.

Processible forms of electrically conductive polyaniline

Colored, electrically conductive compositions comprising substituted and unsubstituted polyanilines and functionalized protonic acids and blends with insulating and semiconducting substrate polymers or polymers plus solvents are disclosed as are methods of forming colored electrically conductive articles of polyaniline/substrate/acid mixtures.

Colored electrically conductive polyaniline compounds

Microfibrils are formed which include conductive conjugated polymer. These microfibrils are incorporated into polymer admixtures which are thermo-formed into conductive shaped articles.

Melt-processible conducting polymer blends based on fibrils of

Polyanilines are provided that are soluble and that form crystaline solids upon precipitation. The solid polyanilines are electrically conductive, soluble, and can be fabricated into various shaped articles for use in, for example, batteries, electrodes, photovoltaic cells, semi-conductor devices and the like.

Electrically conductive polyaniline

Conducting articles such as fibers, films, tapes and the like are fabricated from intractable conducting polymers such as polyacetylene. The articles are prepared by (a) forming a gel of a carrier polymer in a compatible solvent, (b) polymerizing, within the gel, a selected monomer, and (c) doping the article so provided. The articles are highly electrically conductive as well as mechanically quite strong.

Conductive articles of intractable polymers

Microfibrils are formed which include conductive conjugated polymer. These microfibrils are incorporated into polymer admixtures which are thermoformed into conductive shaped articles.

Solutions and plasticized compositions of electrically conductive substituted and unsubstituted polyanilines in nonpolar organic fluid phases with functionalized protonic acids are disclosed as are methods of forming such solutions or compositions and use of same to form conductive articles.

Oriented conjugated polymer shaped articles can be formed by the process of (a) providing a carrier solution made up of

Process for forming polymers

Polyanilines are provided that are soluble and that form crystaline solids upon precipitation. The solid polyanilines are electrically conductive, soluble, and can be fabricated into various shaped articles for use in, for example, batteries, electrodes, photovoltaic cells, semiconductor devices and the like.

Broadly the invention is a method for forming a highly-oriented crystal structure on a substrate in a known orientation comprising the steps of forming a film of highly-oriented poly(tetrafluoroethylene) with an orientation angle of less than 20.degree. on a surface of the substrate with its nominal orientation director along a desired orientation director and then depositing a crystal-forming material on the highly-oriented poly(tetrafluoroethylene) to form the structure. Specific examples include a method for growing a highly-oriented crystal on filament substrates, a method for producing extruded polymer articles (fibers, tapes, and solids) containing oriented crystal growth to improve the characteristics thereof, and a method for storing and retrieving data.

Deposition of highly-oriented PTFE films and uses therefor

Shaped articles such as fibers, films, tapes, rods and the like are fabricated from composites of nonconducting, flexible chain carrier polymers and conductive, conjugated polymers. The shaped, composite articles are electrically conductive and also display excellent mechanical properties, i.e., with respect to tensile strength, elongation at break, and the like. Methods of preparing the novel composite articles are disclosed as well.

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Santa Barbara, CA, United States of America

Paul Smith