Signet Armorlite, Inc.

Paul D Schlunt

Thomas J Engardio

Jimmie E Adcock

Photochromic matrix compositions and tie layer compositions useful for the preparation of photochromic polycarbonate lenses are disclosed. The tie layer compositions facilitate adhesion of the photochromic matrix composition to the polycarbonate lens. The photochromic matrix compositions can contain a flexible hydrophilic dimethacrylate monomer, one or more hydrophobic monomers, a flexible hydrophobic multi(meth)acrylate monomer, one or more urethane methacrylate oligomers, and one or more photochromic dyes. The tie layer compositions can contain one or more methacrylate monomers, a (meth)acrylated oligomer with a polycarbonate backbone, one or more urethane methacrylate oligomers, and a solvent or solvent mixture. Methods of preparing photochromic polycarbonate lenses are also disclosed, involving the serial application of the tie layer composition, then the photochromic matrix composition to the lens.

Compositions for the preparation of composite photochromic polycarbonate lenses

Compositions and methods for the preparation of composite photochromic polycarbonate lenses

A method of manufacturing a composite photochromic ophthalmic lens having an index of refraction of at least 1.49 is disclosed. The method comprises providing against a front portion of a mold, a first ophthalmic lens-forming composition including a polymerizable monomer, oligomer, or polymer and a photochromic compound; filling a rear portion of the mold with a second ophthalmic lens-forming composition, sufficiently different from the first ophthalmic lens-forming composition such that a distinct phase boundary results between the two compositions after complete curing of the two compositions, the second ophthalmic lens-forming composition including a polymerizable monomer, oligomer or polymer that is different from the monomer, oligomer or polymer of the first ophthalmic lens-forming composition, such that the second ophthalmic lens-forming composition is in contact with the first lens-forming composition, wherein either the first or second ophthalmic lens-forming composition is gelled before adding the other ophthalmic lens-forming composition, in an ungelled state, to the mold; and curing the first and second ophthalmic lens-forming compositions simultaneously, while the first and second ophthalmic lens-forming compositions are in intimate contact.

Methods for preparing composite photochromic ophthalmic lenses

Photochromic compositions are disclosed herein. The compositions comprise mixtures of methacrylate monomers, which when polymerized, provide a polymer matrix that exhibits improved fading characteristics of incorporated photochromic dyes and good photochromic temperature stability. The compositions are particularly useful as a composite layer on polymer-based ophthalmic lenses.

Growing community of inventors

Oceanside, CA, United States of America

Paul D Schlunt