Amoco Corporation

Rogers Corporation

Other

Paul D Frayer

Richard Layton

Paul J Huspeni

Markus Matzner

James W Cleary

Brian A Stern

This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the 'Description of the Invention.' The instant copolyesters display orientation in the molten state, good fiber ratings and high strength; they have melting points in the range of from about 340.degree. to about 400.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of over 240.degree. C. up to about 280.degree. C. and higher, when measured under a load of 264 psi. When blended, certain properties are improved, particularly they are easier to melt fabricate, have a decreased tendency to blister and increased strength. These polymers and blends may be used advantageously in ovenware, electronic components, electrical equipment, and other end uses requiring high temperatures.

Heat resistant polymers and blends of hydroquinone poly

Blends of liquid crystalline polymers of hydroquinone

This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the 'Description of the Invention.' The instant copolyesters display orientation in the molten state, good fiber ratings and high strength. Advantageously, the polymers of the present invention display a significant improvement in viscosity and moldability of the neat polymer. The polymers have excellent mechanical and surface properties including blister resistance, strength, toughness, and ability to vapor phase solder, and form strong fibers while still maintaining a high heat distortion temperature. They have melting points in the range of from about 250.degree. to about 360.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of up to 240.degree. C., when measured under a load of 264 psi. The polymers may be blended to tailor properties. These polymers and blends may be used advantageously in producing fibers and in electrical equipment, electronic components and other end uses requiring moderately high temperatures.

High strength polymers and blends of hydroquinone

This invention provides molding compositions which comprise reinforced filled wholly aromatic polyesters and which can be molded into useful articles having low warpage values and good tensile strengths.

Molding compositions comprising reinforced filled wholly aromatic

High strength polymer of hydroquinone poly(iso-terephthalate) containing

A molded article of permanent ovenware comprising (A) 35-85% by weight of a wholly aromatic polyester resin; (B) 15-65% by weight of a specifically defined talc containing a minimum amount of materials decomposable at elevated temperatures; and (C) 0-20% titanium dioxide, wherein the wholly aromatic polyester resin (A) is a blend comprising a first resin based on repeating units of hydroquinone, isophthalic acid (or mixtures of iso- and terephthalic acids), and para-hydroxybenzoic acid, and a second resin based on repeating units of biphenol, isophthalic acid, terephthalic acid and para-hydroxybenzoic acid. The ovenware shows excellent resistance to blistering, bubbling and cracking during molding and oven use.

Plastic ovenware compositions

A high modulus, high strength melt processable copolyester consisting essentially of recurring units (I), (II), (III) and (IV): ##STR1## wherein said copolyester has a melting point in the range of from about 340.degree. C. to 400.degree. C., a crystallization temperature of from about 300.degree. C.-340.degree. C., and a crystallization rate of at least 1,000 counts/minute.

Hydroquinone poly(iso-terephthalates) containing residues of

Disclosed are novel blends of fully aromatic copolyesters which comprise (a) 1-19 parts by weight of a polyester comprising recurring moieties of dihydroxybenzene, nonvicinal benzene dicarboxylate, para oxybenzoate to (b) 1 part by weight of a polyester comprising recurring moieties of diphenol, nonvicinal benzene dicarboxylate, para oxybenzoate; wherein the polyester (a) has a melting point in the range of about 340 C. to 400 C., a crystallization temperature of from about 300-340 C., and a crystallization rate of at least 1,000 counter per minute. The blends display improved surface properties, particularly improved blistering resistance.

Polymer compositions having improved molding characteristics

This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (V). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the 'Description of the Invention'. The instant copolyesters display orientation in the molten state, good fiber ratings and high strength; they have melting points in the range of from about 340.degree. to about 400.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of over 240.degree. C. up to about 280.degree. C. and higher, when measured under a load of 264 psi. When blended, certain properties are improved, particularly they are easier to melt fabricate, have a decreased tendency to blister and increased strength. These polymers and blends may be used advantageously in ovenware, electronic components, electrical equipment, and other end uses requiring high temperatures.

High modulus, high strength melt-processible polyester of hydroquinone

This invention relates to molding compositions comprising wholly aromatic polyesters which contain carbon black, wherein the molding compositions exhibit a uniform color and can be molded into strong thermally stable articles.

Molding compositions comprising wholly aromatic polymers which contain

A barrier for an electroluminescent lamp having a phosphor-particle-containing layer disposed between corresponding electrodes consists of an integral multilayer polymeric film. A first layer of barrier material is integrally bonded in face-to-face contact with the exposed outer surface of the lamp body and the material has a characteristic vapor transmission rate significantly below the vapor transmission rate of the material of the lamp body; a second layer of barrier material is integrally bonded in face-to-face contact with the first barrier layer and the material has a vapor transmission rate significantly greater than the vapor transmission rate of the material of the first barrier layer; and a third layer of barrier material is integrally bonded in face-to-face contact with the second barrier layer and the material has a vapor transmission rate significantly less than the vapor transmission rate of the material of the second barrier layer. The barrier layer materials are thus selected to provide alternating zones of hydrophobic and hydrophilic character, with interfacial boundaries between the layers, to restrict and delay permeation of moisture through the barrier into the lamp, the effective retardation of vapor transmission through the barrier into the lamp being greater than the sum of the retardation characteristics of the individual barrier layers.

Encapsulated electroluminescent lamp

A co-solvent accelerator for a polyamide-acid/ether solution which accelerates the conversion thereof to polyimide is presented. The co-solvent accelerator comprises high boiling pyrrolidone-based solvents, especially those with a boiling point of above about 250.degree. C. such as N-cyclohexyl-2-pyrrolidone (CHP). Said co-solvents are employed in concentrations of from about 0.5% to about 10% by weight, preferably 3% to about 10%.

Co-solvent accelerator for conversion of polyamide-acid solution to

A high temperature processing aid for melt processing polyimide polymers and a method of doing same is presented wherein a compatible, high boiling point N-alkyl- or N-alicyclic-substituted pyrrolidone is added to a polyimide polymer in amounts sufficient to lower the glass transition temperature of said polyimide.

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Martinez, GA, United States of America

Paul D Frayer