Dow Corning Corporation

Paul A Yianni

Stephen E Cray

James McVie

Konstantinos Spyropoulos

The specification describes and claims certain organosilicon compounds and the preparation thereof. The organosilicon compounds comprise (A) a silane according to the general formula R.sup.1.sub.a A.sub.b Si(R'NXR').sub.c or (B) a polysiloxane comprising one or more siloxane units according to the general formula (i) ##EQU1## any remaining units of the polysiloxane being at least predominantly according to the general formula (ii) ##EQU2## A represents a hydroxyl or a hydrolyzable group, R.sup.1 represents a monovalent hydrocarbon group having up to 8 carbon atoms, R.sup.2 represents a hydroxyl group, a group R.sup.1, a group OR.sup.1 or a group COR.sup.1, R.sup.4 represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkenyl group or an aryl group, R' represents a group R.sup.4 or a group X, R' represents a divalent hydrocarbon group which may have nitrogen, oxygen or sulphur present in the carbon chain, X represents a group CO(CHR).sub.n OH in which R represents a hydrogen atom or an alkyl group, a has the value 0, 1, or 2, b has the value 1, 2, or 3, c has the value 1 or 2, the sum of a+b+c=4, m has the value 0, 1 or 2, p has the value 1 or 2, q has the value 0, 1, 2 or 3, r has the value 0, 1 or 2, and n has a value in the range 2 to 7. The organosilicon compounds are useful in compositions for treating fabrics.

Organosilicon compounds

Microemulsions are provided in which the oil phase comprises a reaction product of an organosilicon compound having amino groups and an organosilicon compound having epoxy groups, wherein the reaction product has at least one amino group and two silicon-bond --OR groups. A method for making the microemulsions which comprises reacting the two organosilicon compounds sufficiently to allow the reaction of some of the amine groups with the epoxy groups, but avoiding the excessive crosslinking of the components and their application in the treatment of fibrous materials is also described.

Microemulsions for treating fibrous materials containing the reaction

The specification describes and claims a method of treating fibrous material which comprises applying to the fibrous material a composition comprising an organosilicon compound having a group .dbd.NCO(CH).sub.n OH connected with a silicon atom of the organosilicon compound. The organosilicon compound consists of or comprises (A) a silane according to the genral formula R.sup.1.sub.a A.sub.b Si(R'NXR').sub.c or (B) a polysiloxane comprising one or more siloxane units according to the general formula (i) ##EQU1## any remaining units of the polysiloxane being at least predominantly according to the general formula (ii) ##EQU2## A represents a hydroxyl or a hydrolysable group, R.sup.1 represents a monovalent hydrocarbon group having up to 8 carbon atoms, R.sup.2 represents a hydroxyl group, a group R.sup.1, a group OR.sup.1 or a group COR.sup.1, R.sup.4 represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkenyl group or an aryl group, R.sup.1 represents a group R.sup.4 or a group X, R' represents a divalent hydrocarbon group which may have nitrogen, oxygen or sulphur present in the carbon chain, X represents a group CO(CHR).sub.n OH in which R represents a hydrogen atom, a hydroxyl group, a hydrocarbon group or a hydroxyl substituted hydrocarbon group a has the value 0, 1 or 2, b has the value 1, 2 or 3, c has the value 1 or 2, the sum of a+b+c=4, m has the value 0, 1 or 2, p has the value 1 or 2, q has the value 0, 1, 2 or 3, r has the vale 0, 1 or 2 and n has a value in the range 2 to 7. Fabrics treated according to the method have a satisfactory handle and improved non-yellowing properties.

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Limal, Belgium

Paul A Yianni