The United States of America As Represented by the United States

Equitech Int'l Corporation

Other

Savannah River Nuclear Solutions, LLC

The United States of America As Represented by the Department of Energy

Westinghouse Savannah River Company

Battelle Savannah River Alliance, LLC

Patrick E O'Rourke

William R Toole, Jr

William S Prather

Ronald R Livingston

Lewis C Baylor

Kimberly Alicia Strange Fessler

David R Van Hare

George G Wicks

Betty S Jorgensen

Steven M Serkiz

Donald J Pak

David M Immel

Bruce R Buchanan

Stanley E Nave

Jean R Plummer

Jerry E McCarty

Robert J Lascola

Nicholas F Deroller

Edward A Kyser, Iii

W Patrick Carey

Howard L Nekimken

Michael J Whitaker

Ricky A Haggard

Optical cells are described for use in spectroscopy applications. The cells include a series of discrete planar reflectors aligned with one another and spaced apart from one another at each end of the sample cavity. The discrete planar reflectors can be surrounded by transparent windows and divergent energy can be removed from the cell cavity via the windows. The cells can define a unique beam path for the energy beam, and there can be no overlapping optical paths through the cell. The cells can provide well-defined detection signals with very high signal-to-noise ratio.

Multipass optical spectroscopy cell having a single transmission path

Disclosed are spectroscopy systems and methods. A spectroscopy system can include a reference cell and a multi-pass sample cell. The reference arm can include an etalon and a reference cavity containing a reference gas. A system can include a fractional sublimation cold trap. Detectors of the reference and sample arms can detect both intensity and absorption spectra of impinging beams. A frequency calibration based on a reference absorption spectra can be used to analyze a sample absorption spectrum. The analysis can provide information regarding an absorption band shift of the sample absorption spectrum, said shift being related to the isotope concentration of the sample.

Spectroscopic methods and systems for isotopic analysis

Spectrophotometers and spectroscopy processes are described that can provide for in-line calibration at every spectral acquisition as well as for continuous response correction during sample processing. The spectrophotometers include multiple polychromatic light sources that include characteristic emission spectra for use as an internal wavelength drift calibration system that is independent of environmental factors. Correction functions provided by the internal calibration process can be applied continuously and across an entire sample spectrum. The intensity response of each spectrometer in a spectrophotometer can also be monitored and continuously corrected for stray light, dark current, readout noise, etc.

High accuracy absorbance spectrophotometers

A fiber optic probe and optical coupler assembly, and methods for making the assembly and reproducibly aligning a plurality of optical fibers therein. The coupler is used with a probe that includes a housing or probe body, a probe tip, at least one light-transmitting fiber, at least one light-receiving fiber spaced apart from the light-transmitting fiber, and (if desired), in-line devices such as filters and lenses positioned in optical communication with the fibers. The coupler includes at least one aligning pin that helps maintain the transmitting and receiving fibers in precise, reproducible relative alignment therein; thus, the coupler can be cut to install filters and other in-line devices, then readily re-assembled for use with the cut ends precisely and accurately realigned. The coupler is simple and rugged, and can be manufactured and assembled without the need for high-precision machining or optical alignment procedures.

Fiber optic probe and coupler assembly

A fiber optic probe for ATIR (Attenuated Total Internal Reflection) spectrophotometry. The probe includes a housing that contains an optical element or lens, a light-transmitting fiber that directs incident light to the lens, a light-receiving fiber that receives reflected light from the sample interface, a coupler for holding these components in precise alignment, and a flexible armor casing that provides strain relief and protection for the optical fibers. The lens is shaped and dimensioned so that light from the transmitting fiber is reflected at the interface between the lens and the surrounding medium (such as a liquid to be analyzed). The reflected light is transmitted via the transmitting fiber to a suitable spectrophotometer, where the light signal is recorded and analyzed to determine the composition of the sample. The probe is particularly suitable for analyses of fluids and slurries with high optical absorbance.

Fiber optic probe for attenuated total internal reflection spectrophotometry

A fiber optic Raman probe and optical coupler assembly, and a method for making the assembly and reproducibly aligning a plurality of optical fibers therein. The probe includes a housing or probe body, a probe tip with a window for protecting the interior of the housing, at least one light-transmitting fiber, at least one light-receiving fiber spaced apart from the light-transmitting fiber, an optical coupler, and (if desired), in-line devices such as filters and lenses positioned in optical communication with the fibers. The coupler assembly includes aligning means that helps maintain the fibers in precise, reproducible relative alignment of the fibers; thus, the assembly with the fibers can be cut to install filters and other in-line devices, then readily re-assembled with the cut ends accurately re-aligned, for use. The probe is simple and rugged, and can be manufactured and assembled without the need for high-precision machining or optical alignment procedures.

Fiber optic raman probe and coupler assembly

A multiplexed spectrophotometry apparatus, including a rotary multiplexer fitted with a plurality of fiber terminals, a spectrophotometer mounted to the multiplexer and rotatable therewith, and a programmable on-board computer. The spectrophotometer includes precision optics, a charge coupled device (CCD) detector, electronics, and a cooling system, all contained in a compact, streamlined housing that is shaped to promote the radiation of heat from the spectrophotometer and thereby prevent excessive heating during operation of the apparatus. The spectrophotometer is mounted directly to the multiplexer so that any selected terminal can readily be brought into precise, reproducible alignment with the spectrophotometer input. All components of the apparatus are contained in a compact housing adapted for either rack-mounted or bench-top use.

Multiplexed spectrophotometry system

A fiber optic probe and optical coupler assembly for light scattering measurements, and a method for making the assembly and aligning a plurality of optical fibers therein. The probe includes a probe body with a window across its tip for protecting the interior, at least one light-transmitting fiber, at least one light-receiving fiber, and (if desired), in-line devices such as filters and lenses positioned in optical communication with the fibers. A fiber optic coupler maintains the relative alignment of the fibers, which can be cut to install filters and other in-line devices. The coupler allows the cut ends to be re-aligned quickly and accurately without the need for time-consuming procedures or costly precision alignment equipment. The probe is simple, rugged, requires no high-precision machining or optical alignment procedures in assembly, and is economical to manufacture.

Fiber optic probe

An optical probe for conducting light scattering analysis is disclosed. The probe comprises a hollow housing and a probe tip. A fiber assembly made up of a transmitting fiber and a receiving bundle is inserted in the tip. A filter assembly is inserted in the housing and connected to the fiber assembly. A signal line from the light source and to the spectrometer also is connected to the filter assembly and communicates with the fiber assembly. By using a spring-loaded assembly to hold the fiber connectors together with the in-line filters, complex and sensitive alignment procedures are avoided. The close proximity of the filter assembly to the probe tip eliminates or minimizes self-scattering generated by the optical fiber. Also, because the probe can contact the sample directly, sensitive optics can be eliminated.

Rugged fiber optic probe for raman measurement

An apparatus and method for determining acid concentrations in solutions having acid concentrations of from about 0.1 Molar to about 16 Molar is disclosed. The apparatus includes a chamber for interrogation of the sample solution, a fiber optic light source for passing light transversely through the chamber, a fiber optic collector for receiving the collimated light after transmission through the chamber, a coating of an acid resistant polymeric composition upon at least one fiber end or lens, the polymeric composition in contact with the sample solution within the chamber and having a detectable response to acid concentrations within the range of from about 0.1 Molar to about 16 Molar, a measurer for the response of the polymeric composition in contact with the sample solution, and, a comparer of the measured response to predetermined standards whereby the acid molarity of the sample solution within the chamber can be determined. Preferably, a first lens is attached to the end of the fiber optic light source, the first lens adapted to collimate light from the fiber optic light source, and a second lens is attached to the end of the fiber optic collector for focusing the collimated light after transmission through the chamber.

Optical high acidity sensor

A tetraethyl orthosilicate-based, sol-gel glass composition with additives selected for various applications. The composition is made by mixing ethanol, water, and tetraethyl orthosilicate, adjusting the pH into the acid range, and aging the mixture at room temperature. The additives, such as an optical indicator, filler, or catalyst, are then added to the mixture to form the composition which can be applied to a substrate before curing. If the additive is an indicator, the light-absorbing characteristics of which vary upon contact with a particular analyte, the indicator can be applied to a lens, optical fiber, reagant strip, or flow cell for use in chemical analysis. Alternatively, an additive such as alumina particles is blended into the mixture to form a filler composition for patching cracks in metal, glass, or ceramic piping.

Tetraethyl orthosilicate-based glass composition and method

A method for validating a process stream for the presence or absence of a substance of interest such as a chemical warfare agent; that is, for verifying that a chemical warfare agent is present in an input line for feeding the agent into a reaction vessel for destruction, or, in a facility for producing commercial chemical products, that a constituent of the chemical warfare agent has not been substituted for the proper chemical compound. The method includes the steps of transmitting light through a sensor positioned in the feed line just before the chemical constituent in the input line enters the reaction vessel, measuring an optical spectrum of the chemical constituent from the light beam transmitted through it, and comparing the measured spectrum to a reference spectrum of the chemical agent and preferably also reference spectra of surrogates. A signal is given if the chemical agent is not entering a reaction vessel for destruction, or if a constituent of a chemical agent is added to a feed line in substitution of the proper chemical compound.

Method for verification of constituents of a process stream just as they

A fiber optic probe for detecting scattered light, with transmitting and receiving fibers having slanted ends and bundled together to form a bevel within the tip of the probe. The probe comprises a housing with a transparent window across its tip for protecting the transmitting and receiving fibers held therein. The endfaces of the fibers are slanted, by cutting, polishing and the like, so that they lie in a plane that is not perpendicular to the longitudinal axis of the respective fiber. The fibers are held in the tip of the probe using an epoxy and oriented so that lines normal to the slanted endfaces are divergent with respect to one another. The epoxy, which is positioned substantially between the transmitting and receiving fibers, is tapered so that the transmitting fiber, the epoxy and the receiving fiber form a bevel of not more than 20 degrees. The angled fiber endfaces cause directing of the light cones toward each other, resulting in improved light coupling efficiency. A light absorber, such as carbon black, is contained in the epoxy to reduce crosstalk between the transmitting and receiving fibers.

Fiber optic probe having fibers with endfaces formed for improved

A temperature probe and a method for using said probe for temperature measurements based on changes in light absorption by the probe. The probe comprises a first and a second optical fiber that carry light to and from the probe, and a temperature sensor material, the absorbance of which changes with temperature, through which the light is directed. Light is directed through the first optical fiber, passes through the temperature sensor material, and is transmitted by a second optical fiber from the material to a detector. Temperature-dependent and temperature-independent factors are derived from measurements of the transmitted light intensity. For each sensor material, the temperature T is a function of the ratio, R, of these factors. The temperature function f(R) is found by applying standard data analysis techniques to plots of T versus R at a series of known temperatures. For a sensor having a known temperature function f(R) and known characteristic and temperature-dependent factors, the temperature can be computed from a measurement of R. Suitable sensor materials include neodymium-doped boresilicate glass, accurate to .+-.0.5.degree. C. over an operating temperature range of about -196.degree. C. to 400.degree. C.; and a mixture of D.sub.2 O and H.sub.2 O, accurate to .+-.0.1.degree. C. over an operating range of about 5.degree. C. to 90.degree. C.

Method and apparatus for optical temperature measurement

A support structure bearing at least one probe for making spectrophotometric measurements of a fluid using a source of light and a spectrophotometer. The probe includes a housing with two optical fibers and a planoconvex lens. A sleeve bearing a mirror surrounds the housing. The lens is separated from the mirror by a fixed distance, defining an interior space for receiving a volume of the fluid sample. A plurality of throughholes extending through the sleeve communicate between the sample volume and the exterior of the probe, all but one hole bearing a screen. A protective jacket surrounds the probe. A hollow conduit bearing a tube is formed in the wall of the probe for venting any air in the interior space when fluid enters. The probe is held at an acute angle so the optic fibers carrying the light to and from the probe are not bent severely on emergence from the probe.

Growing community of inventors

Martinez, GA, United States of America

Patrick E O'Rourke