Compagnie De Raffinage Et De Distribution Total France

Total Raffinage Distribution S.a.

Patrick Ansquer

Claude Marty

Jean-Michel Orgebin

Pierre Maroy

Rene Blondeau

A process for the fixed-bed sweetening of sour petroleum distillates with fraction temperatures of from about 125.degree. to about 350.degree. C. and having an acid number of 0.03 mg of KOH/g or higher. The reduction of the acidity and the oxidation of the mercaptans necessary for the sweetening of the distillates are carried out together in a single stage by passing the distillate, in the presence of an oxidizing agent but in the absence of a basic solution, and particularly of an alkali-metal hydroxide solution, over an oxidation catalyst whose specific surface ranges from 1 to 10 m.sup.2 /gram, and preferably from 2 to 6 m.sup.2 /gram, and whose micropore volume ranges from 0.01 to 0.10 cm.sup.3 /gram, and preferably from 0.02 to 0.05 cm.sup.3 /gram.

Process for the fixed-bed sweetening of sour petroleum distillates with

The invention relates to a process for the sweetening of a petroleum fraction in a fixed catalytic bed in the presence of an oxidizing agent, by catalytic oxidation of the mercaptans which it contains, in the presence of a catalyst in the form of a support impregnated with a metal chelate and in the absence of an aqueous base, the water content of the support is maintained within a predetermined range of values by action on the solvent power of the feedstock for the water of the support as a function of temperature.

Procedure for the fixed-bed sweetening of petroleum fractions

A process for sweetening a petroleum fraction by catalytic oxidation of mercaptans contained therein in a fixed bed of the supported catalyst, with the oxidation reaction being carried out in the absence of an aqueous phase and in the presence of an oxidizing agent, and the water molecules formed during the oxidation reaction being removed from the catalyst support by washing the latter periodically with a substantial quantity of a polar solvent that is miscible with water.

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Lillebonne, France

Patrick Ansquer