Dentsply Research & Development Corp.

Pamela H Hare

Paul D Hammesfahr

Steven R Jefferies

Robert V Hare

Disclosed is a new urethane polyacrylate having at least one terminal isocyanato acrylic pendent radical. Preferably the molecular chain within the acrylate caps has been extended with a polyhydroxy compound just before final end capping with isocyanato acrylic. The isocyanato acrylic is preferably isocyanato ethyl methacrylate and the urethane is diisocyanate capped polyether and the polyether radical is oxyalkylene. The method for producing the urethane polyacrylate involves end capping a polyol with diisocyanate yielding a reaction product with two reactive equivalents of isocyanate and then capping less than all of the isocyanate with a hydroxyacrylate, after which the remaining isocyanate is reacted with polyol to provide chain extension. The chain extending polyol is then capped with a isocyanato acrylic. Also disclosed is a new impression material for application to mammalian tissue and curing in contact therewith; the impression material including a free radical polymerizable resin, alkyl benzensulfonyl titanate, polymerization initiator, and filler; and a method of use.

Chain extended urethane diacrylate and dental impression formation

A dental impression package pre-loaded with dental impression material adapted for taking accurate impressions of a patient's teeth and/or gums by professional personnel is provided. The impression material used is flowable to a desired degree and has a viscosity of substantially one million centipoises. Packaging a pre-loaded dental impression tray is accomplished by first quickly immersing the loaded tray in a solution of natural latex for a few seconds and then quickly removing the coated product followed by quickly immersing it in a coagulating solution of acetic acid for a few seconds to stabilize the latex coating; withdrawing the stabilized coated product; drying it; and suitably packaging the product for storage and sale. If the impression material is of a light-curable nature, the packaging is of light-opaque nature.

Pre-loaded dental impression package and method of making

Disclosed is a method for producing an intra-oral dental bandage membrane and/or therapeutic membrane containing therapeutic agent. Actinic light is used to polymerize the membrane composition material to fix the composition in position locked with rigid dental structure such as teeth. The polymerizable substance is manipulated and shaped in a fluid state and then set, as shaped very rapidly in situ. Also disclosed is a new treatment membrane that in a preferred form is a non-symetrical oligomer that is a urethane polyacrylate.

Wound dressing membrane

Disclosed is a new urethane polyacrylate having at least one terminal isocyanato acrylic pendent radical. Preferably the molecular chain within the acrylate caps has been extended with a polyhydroxy compound just before final end capping with isocyanato acrylic. The isocyanato acrylic is preferably isocyanato ethyl methacrylate and the urethane is diisocyanate capped polyether and the polyether radical is oxyalkylene. The method for producing the urethane polyacrylate involves end capping a polyol with diisocyanate yielding a reaction product with two reactive equivalents of isocyanate and then capping less than all of the isocyanate with a hydroxyacrylate, after which the remaining isocyanate is reacted with polyol to provide chain extension. The chain extending polyol is then capped with a isocyanato acrylic. Also disclosed is a new impression material for application to mammalian tissue and curing in contact therewith, the impression material including a free radical polymerizable resin, alkyl benzensulfonyl titanate, polymerization initiator and filler and the method of use.

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Georgetown, DE, United States of America

Pamela H Hare