Societe Bic

Centre National De La Recherche Scientifique

UniversitÉ De Haute-Alsace

Olivier Albenge

Karine Mougin

Romain Metillon

Arnaud Spangenberg

Feriel Ghellal

Anne-Lise Damiano

Christelle Debrauwer

Arnaud Bez

Claire Evrard

Laudine Buge

The present invention concerns a process for preparing an aqueous gel ink with fixed color comprising the following steps: (i) preparing a gel-based matrix of aqueous ink; (ii) preparing an aqueous suspension of silver nanoparticles with fixed color by mixing silver salts with: —water, —a mixture of at least an alkali metal or alkaline earth metal salt of citrate, preferably an alkali citrate salt and an alkali metal hydride, preferably NaBH4, —a further reducing agent, preferably ascorbic acid, —and oxidizing agent, preferably hydrogen peroxide HO(iii) adding under agitation the aqueous suspension of silver nanoparticles obtained in step (ii) to the gel-based matrix of aqueous ink obtained in step (i), to obtain an aqueous gel ink with fixed color with silver nanoparticles dispersed therein.

Process of preparation of an aqueous gel ink with fixed color comprising silver nanoparticles

The present invention concerns a process for preparing an aqueous gel ink with fixed color comprising the following steps: (i) preparing a gel-based matrix of aqueous ink; (ii) preparing an aqueous suspension of silver nanoparticles with a fixed color by mixing silver salts with: —water, —a mixture of at least an alkali metal or alkaline earth metal salt of citrate, —an oxidizing agent, preferably hydrogen peroxide HO, —and polyvinylpyrrolidone; (iii) adding under agitation the aqueous suspension of silver nanoparticles obtained in step (ii) to the gel-based matrix of aqueous ink obtained in step (i), to obtain an aqueous gel ink with fixed color with silver nanoparticles dispersed therein.

The invention relates a process for preparing an aqueous gel ink with fixed color comprising the following steps: (i) preparing a gel-based matrix of aqueous ink; (ii) preparing an aqueous suspension of gold or silver nanoparticles with a fixed color; (iii) adding the aqueous suspension of gold or silver nanoparticles obtained in step (ii) to the gel-based matrix of aqueous ink obtained in step (i).

Process for preparing an aqueous gel ink with fixed color comprising silver or gold nanoparticles

There is a process for preparing in situ an aqueous gel ink with fixed color having the following steps: There is also an aqueous gel ink with fixed color obtained according to the process of the disclosure, comprising 4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid and metallic nanoparticles. There is also a writing instrument comprising an aqueous gel ink with fixed color according to the disclosure.

Process for preparing aqueous gel inks with fixed color, and aqueous gel inks thereof

The present invention concerns a process for preparing in situ an aqueous gel ink with variable color comprising the following steps: (i) preparing a gel-based matrix of aqueous ink comprising 0.005 to 0.1 mol·Lof ester(s) of retinol represented by formula (I), and (ii) adding a solution of 0.002 to 0.05 mol·Lsilver salts (Ag) to the gel-based matrix of aqueous ink prepared in step (i), to obtain an aqueous gel ink with variable color with silver nanoparticles dispersed therein. The present invention also relates to an aqueous gel ink with variable color obtained according to the process of the invention, comprising said ester of retinol represented by formula (I) and silver nanoparticles. The invention finally concerns a writing instrument comprising an aqueous gel ink with variable color according to the invention.

Process of preparation of an aqueous gel ink with variable color comprising silver nanoparticles

A process for preparing in situ an aqueous gel ink with fixed color comprising the following steps: (i) preparing a gel-based matrix of aqueous ink comprising ester(s) of retinol represented by formula (I), and (ii) adding a solution of gold salts (Au3+) to the gel-based matrix of aqueous ink prepared in step (i), to obtain an aqueous gel ink with fixed color with gold nanoparticles dispersed therein. An aqueous gel ink with fixed color obtained according to the process of the invention, comprising the ester of retinol represented by formula (I) and gold nanoparticles. A writing instrument comprising an aqueous gel ink with fixed color.

Process of preparation of an aqueous gel ink with fixed color comprising gold nanoparticles

There is a process for preparing in situ an aqueous gel ink with variable color having the following steps: There also is an aqueous gel ink with variable color obtained according to the process of the disclosure, having a reducing agent, metallic nanoparticles and iron powder. There further is a writing instrument having an aqueous gel ink with variable color according to the disclosure.

Process for preparing aqueous gel inks with variable color, and aqueous gel inks thereof

A process for preparing in situ an aqueous gel ink with variable color comprising the following steps: (i) preparing a gel-based matrix of aqueous ink comprising an N-Acyl-aminophenol, wherein the hydroxyl group is preferably in meta or para position on the benzenic group, and (ii) adding a solution of silver salts to the gel-based matrix of aqueous ink prepared in step (i), to obtain an aqueous gel ink with variable color with silver nanoparticles disposed therein. An aqueous gel ink with variable color obtained according to process for preparing, comprising an N-Acyl-aminophenol, wherein the hydroxyl group is preferably in meta or para position on the benzenic group and silver nanoparticles. A writing instrument comprising an aqueous gel ink with variable color.

A writing instrument including a main body provided with a writing tip. The writing tip being supplied with ink by a free ink-type reservoir equipped with a pressure regulating device for regulating the pressure within the reservoir. The pressure regulating device includes at least one microfluidic valve.

Free ink writing instrument with microfluidic valve

A compensation membrane and a pen or the equivalent including a compensation membrane. The compensation membrane being configured for compensating a pressure difference between the outside and the inside of a free ink reservoir of a pen or the equivalent. The membrane including a first portion having a first rigidity and a second portion having a second rigidity, the first rigidity being less than the second rigidity.

Pressure difference compensation membrane

A writing instrument having a body and a writing tip that is mounted on the body. The body and the writing tip extend along an axial direction, and the writing tip presents a distal end portion having a cross-section that is U-shaped.

Writing instrument having a multi-use tip

A compensation membrane for compensating a pressure difference between the outside and the inside of a free ink reservoir of a pen or the equivalent, the membrane comprising a first portion having a first rigidity, and a second portion having a second rigidity, the first rigidity being less than the second rigidity. A pen or the equivalent comprising a free ink reservoir provided with such a compensation membrane.

A fluid application device including a reservoir intended to contain a free fluid and a fluid delivery device, wherein the reservoir is sealed by a valve having a self-healing material. The fluid application device includes a tubular means for piercing the valve and for simultaneously placing fluid from the reservoir in communication with the fluid delivery device.

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Clichy, France

Olivier Albenge