Union Carbide Corporation

Union Carbide Chemicals & Plastics Technology Corporation

Other

Union Carbide Chemicals and Plastics Company, Inc.

Oliver W Smith

Joseph V Koleske

David John Trecker

George Wayne Borden

Robert J Knopf

John N Argyropoulos

Charles H Carder

Robert Arthur Taller

Kenneth L Hoy

David R Bassett

Russell J Outcalt

Haywood G France

Julius John Brezinski

Unsaturated cycloaliphatic esters like higher hydrocarbyl, functionally substituted or polyunsaturated cyclohex-3-ene carboxylates, made directly by cycloaddition of dienes with dienophillic (meth/eth)acrylates, and their derivatives like epoxides and urethanes, provide useful thermal and radiation curable coatings, inks, sealants, adhesives, solvents, acid scavengers, and intermediates for other uses.

Production of unsaturated cycloaliphatic esters and derivatives thereof

This invention relates to polyurethane (meth)acrylates that are prepared from certain liquid hydrocarbon diols and/or derivatives of said liquid hydrocarbon diols, polyfunctional isocyanates, and hydroxyalkyl acrylates and methacrylates. The polyurethane (meth)acrylates are useful as decorative and functional coatings, inks, adhesives, sealants, and formed parts.

Polyurethane (meth)acrylates and processes for preparing same

Aqueous dispersions of particles stabilized by a basic dispersant are rendered suitable for particle encapsulation or coating processes by polymerization from the aqueous phase by treatment with certain ethylenically-unsaturated carboxylic acids.

Method for enhancing encapsulation efficiency in coating particles in

This invention relates to a process for preparing a malonic acid derivative compound of formula (i) depicted herein in high yield and high purity by reacting a malonic acid derivative compound of formula (ii) depicted herein with an alkylating agent of formula (iii) depicted herein in the presence of a solvent and a base.

Process for the production of malonic acid derivative compounds

Low energy-curable coatings compositions of (1) an epoxide, (2) a polyisocyanate and as a catalyst and initiator a mixture of (3) a stannous salt and (4) a liquid polycarboxylic acid produced by the reaction of a polycaprolactone and an intramolecular polycarboxylic acid anhydride.

Low-energy-curable coatings compositions

High solids, low energy curing compositions of (1) a carboxyl-modified polycaprolactone polyol which is the reaction product of a polycaprolactone polyol and an intramolecular carboxylic acid anhydride, (2) a monocarboxylic acid compound, (3) a stannous salt and (4) a polyepoxide. The compositions are useful as inks or coatings.

Low energy-curable high solids coatings

Compositions comprisng an ester diol alkoxylate in conjunction with aqueous acrylic latex have been produced that are useful as coatings, inks and adhesives.

High solids compositions containing ester diol alkoxylate and aqueous

Compositions of an acrylated epoxidized soybean oil, which is the reaction product of epoxidized soybean oil with acrylic acid or methacrylic acid, and a photosensitizer are useful for coatings and inks; a pigment can optionally be present. The compositions can be cured by radiation.

Ink and coating compositions and method

The urethane derivatives of acrylated epoxidized soybean oil, which is the reaction product of epoxidized soybean oil with acrylic acid or methacrylic acid, are produced by the reaction of acrylated epoxidized soybean oil with an organic isocyanate. The derivatives are useful alone, or in conjunction with a photosensitizer, and/or a pigment as inks and coatings in the methods of this invention whereby they are cured by exposure to radiation.

Method for coating or printing using acrylated epoxidized soybean oil

Compositions comprising an ester diol alkoxylate in conjunction with an organic polyisocyanate have been produced that are useful as coatings, inks and adhesives.

High solids compositions containing ester diol alkoxylate and organic

The urethane derivatives of acrylated epoxidized soybean oil, which is the reaction product of epoxidized soybean oil with acrylic acid or methacrylic acid, are produced by the reaction of acrylated epoxidized soybean oil with an organic isocyanate. They are useful alone, or in conjunction with a photosensitizer, and/or a pigment as inks and coatings. The compositions can be cured by radiation.

Acrylated epoxidized soybean oil urethane compositions and method

Method for coating or printing using as the coating or printing medium compositions of an acrylated epoxidized soybean oil, which is the reaction product of epoxidized soybean oil with acrylic acid or methacrylic acid, and a photosensitizer are useful for coatings and inks, and a pigment. The compositions can be cured by radiation.

Derivatives of esterdiol alkoxylates obtained by reaction thereof with an epoxide, as well as the anhydride capped products thereof. Formulations containing the above are also claimed.

Epoxide derivatives of ester diol alkoxylates and compositions thereof

Blends of derivatives of esterdiol alkoxylates obtained by reaction thereof with an anhydride, isocyanate or epoxide and an acrylic latex. The blends are useful as coatings.

Blends of acrylic latexes and derivatives of ester diol alkoxylates

Derivatives of esterdiol alkoxylates obtained by reaction thereof with an isocyanate, as well as the anhydride capped products thereof. Formulations containing the above are also claimed.

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South Charleston, WV, United States of America

Oliver W Smith