Continental Oil Company

Oliver C Kerfoot

Charles R Clark

Carl D Kennedy

M Duane Gregory

Delmar D Krehbiel

An improved anionic waterflood additive is prepared by partially chlorinating a normal alkane having about 10 to about 18 carbon atoms to about 2 to about 15 weight percent chlorine content, employing the chlorinated alkane to alkylate an aromatic hydrocarbon, such as benzene; sulfonating the thus formed alkylate or a fraction thereof to form a sulfonic acid; converting the sulfonic acid to a sulfonate by reacting with a base component, such as an alkali metal hydroxide, ammonium hydroxide, or an alkali metal carbonate; and overbasing the sulfonate by admixing with an excess of base component such that the ratio: 'weight of excess base component/weight of sulfonate' is about 0.03 to about 3.0. The anionic waterflood additive is injected into a petroliferous formation, the formation is waterflooded, and oil is recovered.

Waterflood method using overbased normal alkylaromatic sulfonates

An improved anionic overbased waterflood additive comprises a base component, a first sulfonate component derived from an alkylation reaction product employing a branched-chain alkene as the alkylating agent, and a second sulfonate component derived from an alkylation reaction product employing a partially chlorinated normal alkane as the alkylating agent, wherein the base component is present in the weight ratio range of 3/100 to 300/100, base component to total sulfonate, and wherein the weight ratio of the first sulfonate component to the second sulfonate component is in the range of 1/9 to 9/1. The overbased waterflood additive may be formed prior to injection into a petroliferous formation or may be formed in situ by first injecting the total sulfonate followed by the base component.

Oil recovery method using overbased waterflood additive containing

An improved anionic waterflood additive is prepared by alkylating an aromatic hydrocarbon such as benzene with a branched-chain alkene having about 10 to about 35 carbon atoms such as a propylene tetramer dimerization reaction product in the presence of an alkylation catalyst such as AlCl.sub.3 ; sulfonating the thus formed alkylate product or a fraction thereof to form a sulfonic acid; converting the sulfonic acid to a sulfonate by reacting with a base component such as an alkali metal hydroxide, ammonium hydroxide, or an alkali metal carbonate; and overbasing the sulfonate by admixing with an excess of base component such that the ratio; 'weight of excess base component/weight of sulfonate' is about 0.03 to about 3.0. The anionic waterflood additive is injected into a petroliferous formation, the formation is waterflooded, and oil is recovered.

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Ponca City, OK, United States of America

Oliver C Kerfoot