Other

Olga Fedorovna Starikova

Jury Ivanovich Michurov

Alexandr G Liakumovich

Yakov Abramovich Gurvich

Simona T Kumok

Evgeny L Styskin

Grigory I Rutman

Vladimir Avgustovich Yanshevsky

Vladimir A Yanshevsky

Alexandr Afroimovich Grinberg

Vladimir K Gusev

Grigory Iosifich Rutman

A method for preparing sterically hindered bis- or polyphenols of the formula: ##STR1## wherein R' is hydrogen, a C.sub.1 -C.sub.4 alkyl; R' and R'' the same or different and are each: ##STR2## wherein R is a tertiary C.sub.4 -C.sub.8 alkyl, R.sub.1 and R.sub.2 are the same or different and represent a C.sub.1 -C.sub.8 alkyl or a C.sub.6 -C.sub.8 cycloalkyl, or a C.sub.7 -C.sub.9 aralkyl, which comprises reacting the starting sterically hindered 2,4,6-trialkylphenols of the formula: ##STR3## wherein A is a C.sub.1 -C.sub.8 alkyl or a C.sub.6 -C.sub.8 cycloalkyl or a C.sub.7 -C.sub.9 aralkyl or a 3,5-dialkyl-2-hydroxybenzyl of the formula: ##STR4## B is a C.sub.1 -C.sub.8 alkyl, or a C.sub.6 -C.sub.8 cycloalkyl, or a C.sub.7 -C.sub.9 aralkyl, or a 3,5-dialkyl-4-hydroxybenzyl of the formula: ##STR5## wherein R.sub.1 and R are as identified above, with acetals, aldehydes or donors of C.sub.1 -C.sub.5 aldehydes in an acidic medium at a temperature within the range of from 60.degree. to 200.degree. C. in the presence of an acidic catalyst, followed by isolation of the desired product. The method according to the present invention makes it possible to prepare sterically hindered bis- or polyphenols in a single stage, whereby the process technology is substantially simplified as compared to those of the prior art. The method of the present invention precludes formation of waste water and atmospheric pollutants. The method ensures preparation of the desired products possessing high quality in high yield without any additional crystallization.

Method for preparing sterically hindered bis- or polyphenols

A method of producing 2,2'-methylenebis(4,6-dialkylphenols) residing in that 2,4-dialkylphenols interact with acetals in the presence of an acid catalyst at a temperature from 30.degree. C to 140.degree. C with the formation of a reaction mixture containing the desired product and with subsequent separation of the desired product from said mixture, the starting reagents being taken in amounts of 1 mole of 2,4-dialkylphenol per 1-10 moles of acetal. The method is technologically simple and accomplished without the formation of waste water.

Method of producing 2,2 '-methylenebis(4,6-dialkylphenols)

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Moscow, Russia

Olga Fedorovna Starikova