Lg Energy Solution, Ltd.

Lg Chem, Ltd

Oh-Byong Chae

Sang-Wook Woo

Ye-Ri Kim

Seung-Hae Hwang

Je-Young Kim

Eun-Kyung Kim

Hee-Won Choi

Yoon-Ah Kang

Soo-Hee Kang

Geun-Sik Jo

Jun-Hyuk Song

So-Young Choo

Su-Yeon Lee

Seo-Young Jeon

A method for pre-lithiation of a negative electrode including the steps of: interposing a separator between a lithium ion-supplying metal sheet and a negative electrode to prepare a simple cell; dipping the simple cell in an electrolyte for pre-lithiation; and disposing the simple cell dipped in the electrolyte for pre-lithiation between two polymer pads, and carrying out electrochemical charging, while pressurizing the outside of the two polymer pads, to perform pre-lithiation of the negative electrode. Each of the polymer pads has a thickness of 60% to 90% of a thickness of a corresponding jig of the pair of jigs. A pre-lithiated negative electrode and a lithium secondary battery including the pre-lithiated negative electrode are also disclosed.

Method for pre-lithiation of negative electrode, pre-lithiated negative electrode and lithium secondary battery including the same

A method for pre-sodiation of a negative electrode, including the steps of: interposing a separator between a sodium ion-supplying metal sheet and a negative electrode to prepare a simple cell; dipping the simple cell in an electrolyte for pre-sodiation; and electrochemically charging the simple cell dipped in the electrolyte for pre-sodiation to carry out pre-sodiation of the negative electrode wherein the electrochemical charging is carried out while the simple cell is pressurized under a pressure of from 100 kPa to 1,000 kPa. A pre-sodiated negative electrode is also disclosed, including: a current collector; a negative electrode active material layer on at least one surface of the current collector. The negative electrode active material layer includes a negative electrode active material; and a coating layer on the surface of the negative electrode active material layer. The coating layer includes Na-carbonate and Na.

Method for pre-sodiation of negative electrode, pre-sodiated negative electrode, and lithium secondary battery comprising same

A method for pre-lithiation and pre-sodiation of a negative electrode, including the steps of: interposing a first separator between a lithium ion-supplying metal sheet and a negative electrode to prepare a first simple cell. Then, dipping the first simple cell in an electrolyte for pre-lithiation. Next, carrying out a primary electrochemical charging of the first simple cell dipped in the electrolyte for pre-lithiation to obtain a pre-lithiated negative electrode. Then, interposing a second separator between a sodium ion-supplying metal sheet and the pre-lithiated negative electrode to prepare to prepare a second simple cell. Next, dipping the second simple cell in an electrolyte for pre-sodiation; and carrying out secondary electrochemical charging of the second simple cell dipped in the electrolyte for pre-sodiation to obtain a pre-lithiated and pre-sodiated negative electrode. A pre-lithiated/pre-sodiated negative electrode obtained by the method and a lithium secondary battery including the same are also disclosed.

Method for pre-lithiation/pre-sodiation of negative electrode, pre-lithiated/pre-sodiated negative electrode, and lithium secondary battery comprising same

A pre-lithiation apparatus which prevents an electrode from being damaged by the byproducts produced by contact between a lithium source, such as a lithium metal sheet or lithium metal powder, and an electrolyte for pre-lithiation. The pre-lithiation apparatus includes a first reaction vessel comprising a first electrolyte and a first organic solvent and a second reaction vessel comprising a second electrolyte and a second organic solvent, wherein the first electrolyte of the first reaction vessel and the second electrolyte of the second reaction vessel are linked to each other by a salt bridge. A negative electrode to be pre-lithiated is dipped at least partially in the first electrolyte of the first reaction vessel, and a lithium source capable of supplying lithium ions is dipped at least partially in the second electrolyte of the second reaction vessel.

Pre-lithiation apparatus

A method for pre-lithiation and pre-sodiation of a negative electrode, including the steps of: preparing a negative electrode including a negative electrode current collector, and a negative electrode active material layer on at least one surface of the negative electrode current collector. Then, applying and drying a first composition containing a lithium metal powder, a polymer binder and a dispersion medium onto the negative electrode active material layer to form a lithium metal layer. Next, applying and drying a second composition containing a sodium metal powder, a polymer binder and a dispersion medium onto the lithium metal layer to form a sodium metal layer. Then, dipping the negative electrode having the lithium metal layer and the sodium metal layer in an electrolyte for pre-lithiation and pre-sodiation. A pre-lithiated and pre-sodiated negative electrode obtained by the method and a lithium secondary battery including the same are also disclosed.

Anode pre-lithiation-pre-sodiation method, pre-lithiated and pre-sodiated anode, and lithium secondary battery comprising same

A method for pre-lithiation of an electrode, including a first step of providing a pre-lithiation reaction system which includes a first reaction system including lithium metal, a separator, an electrolyte for pre-lithiation and carbon felt, and a second reaction system including the electrolyte for pre-lithiation and an electrode to be pre-lithiated, wherein the lithium metal and the electrode to be pre-lithiated are not in direct contact with each other. The first reaction system and the second reaction system communicate with each other. The first step is followed by a second step of preparing an electrode including an electrode current collector, and an electrode active material layer formed on at least one surface of the electrode current collector; and a third step of allowing the electrode to pass through the second reaction system by a conveying roll to carry out pre-lithiation of the electrode.

Method and apparatus for pre-lithiation of electrode

A separator including: a porous polymer substrate having a plurality of pores; and a coating layer formed on at least one surface of the porous polymer substrate, and including a plurality of lithium-containing composite particles and a binder positioned on the whole or a part of the surface of the lithium-containing composite particles to connect and fix the lithium-containing composite particles with each other, wherein the lithium-containing composite particles includes a lithiated compound and a passivation film formed on the surface of the lithiated compound, and the passivation film includes a solid electrolyte interface (SEI). A lithium secondary battery including the separator and a method for manufacturing the lithium secondary battery are also provided.

Separator including coating layer of lithium-containing composite, lithium secondary battery including the same, and method for manufacturing the secondary battery

In the case in which a lithium metal is used in order to increase the capacity of a lithium secondary battery, reversibility of charging and discharging is reduced due to dendrite, etc. A lithium metal having LiF deposited thereon exhibits high stability, whereby reversibility of charging and discharging is increased. In addition, in the case in which LiF is deposited, the lithium metal, which is a negative electrode material, is not consumed, and the shape of a lithium metal electrode is not greatly changed.

Deposition of lithium fluoride on surface of lithium metal and lithium secondary battery using the same

A lithium metal is physically pressed to a silicon wafer having a uniform intaglio or embossed pattern formed thereon in advance, or liquid lithium is applied to the silicon wafer and may then be cooled in order to form a uniform pattern on the surface of the lithium metal.

Lithium metal patterning and electrochemical device using the same

A method for pre-lithiation of a negative electrode is disclosed, including the steps of: producing a lithium metal laminate which includes i) lithium metal foil; and ii) a buffer layer including carbonaceous material particles, inorganic compound particles, polymer compound particles or their combination, and coated on one surface of the lithium metal foil; producing a negative electrode including a negative electrode current collector, and a negative electrode active material layer formed on at least one surface of the negative electrode current collector; and laminating the lithium metal laminate with the negative electrode in such a manner that the buffer layer of the lithium metal laminate is in contact with the negative electrode active material layer. A lithium metal laminate used for the method is also provided. The pre-lithiation of a negative electrode that includes a buffer layer reduces the problem of rapid volumetric swelling occurring.

Method for pre-lithiation of negative electrode for lithium secondary battery and lithium metal laminate used therefor

A pre-lithiation reaction chamber apparatus including a pre-lithiation reaction vessel which can prevent harmful effects caused by water that may be generated during pre-lithiation is provided. The pre-lithiation reaction vessel includes an electrolyte including a lithium salt, a negative electrode for a lithium secondary battery and a lithium ion-supplying member. Each of the negative electrode for the lithium secondary battery and the lithium ion-supplying member is at least partially in contact with the electrolyte. The pre-lithiation reaction chamber apparatus further includes a water-capturing vessel. The water-capturing vessel includes water-capturing powder, a container configured to receive the water-capturing powder, and a position-changing member configured to change a position of the water-capturing powder in the container.

Pre-lithiation reaction chamber apparatus

A method for manufacturing a lithium secondary battery, including the steps: (S1) forming a preliminary negative electrode by coating a negative electrode slurry including a negative electrode active material, conductive material, binder and a solvent onto at least one surface of a current collector, followed by drying and pressing the negative electrode slurry coated current collector, to form a negative electrode active material layer surface on the current collector; (S2) coating lithium metal foil onto the negative electrode active material layer surface of the preliminary negative electrode in the shape of a pattern in which pattern units are arranged; (S3) cutting the preliminary negative electrode on which the lithium metal foil is pattern-coated to obtain negative electrode units; (S4) impregnating the negative electrode units with an electrolyte to obtain a pre-lithiated negative electrode; and (S5) assembling the negative electrode obtained from step (S4) with a positive electrode and a separator.

Method for manufacturing negative electrode and negative electrode obtained therefrom

A method for patterning a lithium metal surface, including the steps of (S1) forming an intaglio or relief pattern having a predetermined size on a patterning substrate; (S2) either (a) compressing lithium metal physically to a surface of the patterning substrate having the pattern formed thereon to form the predetermined pattern on the surface of the lithium metal, or (b) applying liquid lithium to the surface of the patterning substrate having the pattern formed thereon and solidifying the liquid lithium to form the predetermined pattern on the surface of the lithium metal; and (S3) separating the lithium metal having the predetermined pattern formed thereon from the patterning substrate, wherein the patterning substrate is at least one selected from a silicon wafer or polycarbonate substrate.

Method for patterning lithium metal surface and electrode for lithium secondary battery using the same

A negative electrode for a lithium secondary battery using lithium metal for the negative electrode and a method for manufacturing the same. The method includes forming a protective layer for dendrite prevention of the negative electrode. The method for manufacturing a negative electrode may be achieved by a process including coating a slurry containing fluorocarbon and/or fluorinated metal dispersed in a solvent onto a lithium metal layer and drying the slurry.

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Daejeon, South Korea

Oh-Byong Chae