Kabushiki Kaisha Kobe Seiko Sho

Kobe Steel, Ltd.

Norio Masaie

Hiroyuki Shimizu

Kazuhiko Ito

Akira Matsuguchi

Kuniaki Miyazaki

Tomoyuki Tachibana

Kaoru Masuda

Mika Nishida

Atsushi Furuya

Yoshikazu Sasa

Takenori Nakayama

Shinji Sakashita

Eri Yamamoto

Akiyoshi Kataoka

Yasuo Araike

Koji Seita

A titanium oxide raw material for a welding material, which can achieve the improvement in a bead shape and high-speed welding. The titanium oxide raw material has the form of particles and has a composition containing 58.0 to 99.0 mass % of TiO2, 2.5 mass % or less of Si, 3.0 mass % or less of Al, 5.0 mass % or less of Mn, 35.0 mass % or less of Fe, 5.0 mass % or less of Mg and 2.0 mass % or less of Ca, wherein the surface of each of the particles is coated with an oxide and/or a composite oxide of at least one element selected from Ti, Fe, Mn, Al and Si and the atom percentages of Ti, Fe, Mn, Al, Si and O in the oxide and/or the composite oxide fulfill the following three formulae.1=Al+Si=10,1&#x3c;Ti/(Fe+Mn)=100,O/(Fe+Mn)=100

Titanium oxide raw material for welding material

Disclosed herein is a manufacturing method, excellent in wire drawability, of a seamed flux-cored welding wire having both favorable feedability and low hydrogen content characteristic. The method for manufacturing a seamed flux-cored wire, comprises the steps of: drawing a tube-like formed wire including a flux filled therein using a lubricant; removing the lubricant from the drawn wire by a physical means; and coating a lubricant (coating an oil) for wire feeding on the wire surface. The respective steps are carried out in an in-line manner. In the wire drawing step, a wire drawing lubricant containing a sulfur-bearing high-pressure lubricant is used, and the overall wire drawing from the tube-like formed wire to a roughly product-diameter wire is carried out by means of a roller die.

Method for manufacturing seamed flux-cored welding wire

A welding wire of the type consists of a plated or uncovered solid wire and a flux-cored wire for carbon steel or stainless steel, wherein one or more of hydrocarbon compounds selected from the group consisting of saturated or unsaturated hydrocarbon compounds, which have from 5 to 12 carbon atoms and a linear or branched structure, and hydrocarbon compounds having a cyclic structure are deposited on a wire surface. A lubricating oil and/or lubricating particles are chemically combined with a wire surface through the one or more hydrocarbon compounds. The total amount of the hydrocarbon compounds, and a lubricating oil and/or lubricating particles deposited on the wire surface is in the range of 0.1 to 5 g per 10 kg of the wire.

Wire for welding

A welding wire capable of improving wettability between weld metal and wire surface, thereby providing excellent drawability and weldability in resistance welding of wires is provided. A wire is dipped in an aqueous solution of a sulfide of alkali metal or ammonium sulfide to generate iron sulfide (FeS.sub.2 or FeS) on the surface, whereby the wettability of weld metal to wire surface is improved in the resistance welding of the resulting wires. The S in the iron sulfide is preferably present in an amount of 0.1-20 atomic % as measured by X-ray photoelectron spectroscopy. At least one sulfide of S with an element of Mn, Ti, Cu, Cr, Ni, Al or Zn can be used instead of or in addition to the iron sulfide.

Welding wire

A flux-cored wire for arc welding, wherein a specific surface area, which is defined by the equation of {(Sa/Sm)-1} where Sm is an apparent surface area and Sa is a real surface area in a region to be measured on a surface of the wire, is in the range of from 0.005 to 0.035; and molybdenum disulfide is stuck on the surface of the wire in an amount of from 0.004 to 0.24 g/m.sup.2, and no plating is applied on the surface of the wire. Moreover, a solid wire for arc welding wherein the specific surface area {(Sa/Sm)-1} is in the range of from 0.0005 to 0.05; and molybdenum disulfide is stuck on the surface of the wire in an amount of from 0.001 to 0.5 g/m.sup.2, and no plating is applied on the surface of the wire.

Flux-cored wire and solid wire for ARC welding

A lubricant for wire feeding and wire drawing which comprises polytetrafluoroethylene powder, 0.5-40 .mu.m (or 0.5-20 .mu.m) in particle diameter, dispersed in water or an aqueous dispersion containing polytetrafluoroethylene powder, 0.1-0.4 .mu.m in particle diameter. A welding wire whose surface is coated with a lubricant mentioned above and a welding wire which has been drawn by the aid of a lubricant mentioned above.

Lubricant for wire feeding and wire drawing and a welding wire

A flux-cored wire for arc welding, wherein a specific surface area, which is defined by the equation of {(Sa/Sm)-1} where Sm is an apparent surface area and Sa is a real surface area in a region to be measured on a surface of the wire, is in the range of from 0.005 to -0.035; and molybdenum disulfide is stuck on the surface of the wire in an amount of from 0.004 to 0.24 g/m.sup.2, and no plating is applied on the surface of the wire. Moreover, a solid wire for arc welding wherein the specific surface area {(Sa/Sm)-1} is in the range of from 0.0005 to 0.05; and molybdenum disulfide is stuck on the surface of the wire in an amount of from 0.001 to 0.5 g/m.sup.2, and no plating is applied on the surface of the wire.

Flux-cored wire and solid wire for arc welding

Disclosed is a flux cored wire for low alloy steels and high alloy steels which is excellent in arc stability and moisture absorption resistance of fume/slag. In this flux-cored wire, the flux components and the flux ratio are specified within the following ranges: namely, Na compound (Na.sub.2 O equivalent amount)+K compound (K.sub.2 O equivalent amount) (flux wt %): 1.5-6.0%; soluble Na compound (Na.sub.2 O equivalent amount) (flux wt %): 1.5% or less; soluble K compound (K.sub.2 O equivalent amount) (flux wt %): 0.8% or less; SiO.sub.2 (flux wt %): 5-30%; TiO.sub.2 +ZrO.sub.2 +Al.sub.2 O.sub.3 (flux wt %): 5-40%; flux ratio (wire wt %): 10-30%. Further, the flux components satisfy the formula of {soluble Na compound (Na.sub.2 O equivalent amount)+0.1.times.soluble K compound (K.sub.2 O equivalent amount)}/{SiO.sub.2 +0.5.times.(TiO.sub.2 +ZrO.sub.2 +Al.sub.2 O.sub.3)}: 40.times.10.sup.-3 or less. In addition, one or more kinds of a Li compound (Li.sub.2 O equivalent amount) and a Cs compound (Cs.sub.2 O equivalent amount) may be added in the total amount of 0.1-3.0 wt % so as to satisfy the formula of {soluble Na compound (Na.sub.2 O equivalent amount)+0.1.times.soluble K compound (K.sub.2 O equivalent amount)-Li compound (Li.sub.2 O equivalent amount)-Cs compound (Cs.sub.2 O equivalent amount)}/{SiO.sub.2 +0.5.times.(TiO.sub.2 +ZrO.sub.2 +Al.sub.2 O.sub.3)}=20.times.10.sup.-3 or less.

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Fujisawa, Japan

Norio Masaie