Dynamit Nobel Aktiengesellschaft

Norbert Vollkommer

Egon N Petersen

Hermann Richtzenhain

Gerhard Bier

Georg Blumenfeld

Wilhelm Vogt

Werner Schmidt

Herbert Klinkenberg

Gerhard Schade

Hans Huber

Dagmar Kottek

Moustafa El-Chahawi

Werner Trautvetter

Erich Behr

Manfred Gorlitz

Helmut Wemheuer

Georg Blumfeld

Disclosed is a thermosetting adhesive and sealant composition of:

Thermosetting adhesive and sealant compositions

Thermosetting adhesive and sealing compositions are described, consisting of:

Thermosetting adhesive and sealing compounds

The invention relates to halogenous polyesters with the recurrent general formula ##STR1## in which at least part of the R's, e.g. 1 to 100 mole-%, preferably 100 mole-%, or 2 to 10 mole-%, are of the general formulas ##STR2## and 0 to 99 mole-%, preferably 0 or 90 to 98 mole-%, of the R's correspond to a phenylene radical and/or a naphthylene radical and/or an alkylene radical of 3 to 10 carbon atoms and/or a cycloalkylene radical, and the R's represent an organic moiety which is contained in bivalent saturated alcohols and corresponds to a branched or unbranched saturated alkylene radical of 2 to 10 carbon atoms and/or to a cycloalkylene radical and/or which is derived from an alkyleneterephthalate containing hydroxyl groups, preferably an oligomeric ethyleneterephthalate and/or an oligomeric propyleneterephthalate and/or an oligomeric butyleneterephthalate, wherein Z represents the groups ##STR3## and X represents hydrogen, bromine or chlorine, wherein at least some of the X's are bromine or chlorine, and in which polyesters, in some cases, a portion of the R's are residues of unsaturated dicarboxylic acid derivatives which, together with ethylenically unsaturated comonomers, preferably styrene, are capable of forming peroxide-curable unsaturated polyester resin (UP resin) solutions, and their preparation as well as their use as fire-retardant molding compositions or articles, and also dicarboxylic acid esters some of which can be used in the preparation of the polyesters as well as the preparation of these dicarboxylic acid esters. Preferably the xylene nucleus in (2) is substituted by Br.sub.4.0 to 2.8 and Cl.sub.0 to 1.2.

Bis-carbalkoxy compounds and their preparation

Halogen-containing bis-acrylates and bis-methacrylates corresponding to the formula ##STR1## in which R represents hydrogen or a methyl group and X represents chlorine and/or bromine, are provided as well as a process for producing such compounds. The compounds are useful for the formation of polymers and copolymers and as cross-linking agents. Also included in the invention are the polymers and copolymers based on the above-described halogen-containing bis-acrylates and bis-methacrylates, methods for the production of said polymers and the use of said polymers as flame proofing agents, etc.

Halogen-containing unsaturated bis-esters and polymers and copolymers

A polymer having as a component thereof a moiety corresponding to a monomer having the following formula ##STR1## wherein n=0 or 1, X is bromine, chlorine or a mixture thereof and R represents hydrogen or methyl, a method of preparing the same and the use of such a polymer, including a copolymer thereof in a plastic composition containing a normally flammable plastic.

Acrylate-based polymers and copolymers and their use as flameproofing

A process for preparing a poly-(alkylpentamethyleneterephthalamide) which comprises heating an aqueous solution of the corresponding nylon salt and still water soluble low molecular weight oligomer, the mixture of nylon salt and oligomer having 20 to 50 mole percent carbonamide groups and 50 to 80 mole percent salt groups, from a temperature at least as low as 150.degree. C. at atmospheric pressure up to a polycondensation temperature of at least 250.degree. C.

Method of preparing modified or unmodified

Linear or unsaturated polyesters prepared from bis-carbalkoxy compounds

Halogen-containing bis-acrylates and bis-methacrylates corresponding to the formula ##STR1## in which R represents hydrogen or a methyl group and X represents chlorine and/or bromine, are provided as well as a process for producing such compounds. The compounds are useful for the formation of polymers and copolymers and as a cross-linking agents. Also included in the invention are the polymers and copolymers based on the above-described halogen-containing bis-acrylates and bis-methacrylates, methods for the production of said polymers and the use of said polymers as flame proofing agents, etc.

Halogen-containing unsaturated bis-esters

Tetrahaloxylene diesters of formulas 1 and 2: ##STR1## wherein R= hydrogen or a methyl group, and each X is bromo, with the proviso that some of the X's can be chloro. The compounds are useful as flame retardants for plastics.

Tetrabromoxylylene diacrylates and substituted acrylates

An improvement in an unsaturated polyesters having recurring units of the formula ##STR1## wherein A is the residue of an alcoholic moiety and B is the residue of an acid moiety, which improvement resides in the fact that some of the A residues are chloroxylylene containing residues having the formula ##STR2##

Solution of an unsaturated polyester and a copolymerizable monomer

A polymer having as a component thereof a moiety corresponding to a monomer having the following formula ##STR1## WHEREIN N = 0 OR 1, X is bromine, chlorine or a mixture thereof and R represents hyrogen or methyl, a method of preparing the same and the use of such a polymer, including a copolymer thereof in a plastic composition containing a normally flammable plastic.

Acrylate-based polymers and their use as flameproofing agents

A polymeric formal having the general formula ##STR1## wherein p is 0 or 1, n is a positive integer from 2 to 200 and R represents optionally halogen-substituted straight-chained or branched-chained alkyl radicals having 3 to 8 carbon atoms, an aryl radical or an aralkyl radical which can be substituted on one or both sides with alkyl or hydroxyalkyl ether groups; improved methods for the preparation of such formals, tetrabromoxylylene-bis-(.beta.-hydroxyethylether) compounds employed in the preparation of such formals and the use of such polymeric and oligomeric formals as flame retardant agents in plastic compositions especially thermoplastic and polycondensation plastic compositions.

Polymeric and oligomeric formals

Unsaturated polyesters derived from chloroxylylene diols

Polyether ester polymers of tetrahydrofuran and .gamma.-butyrolactone or hexamethyleneoxide and .gamma.-butyrolactone. The polymers are prepared by contacting the mentioned monomers in the presence a fluoride or chloride of antimony or a chloride of tin or titanium. The polymers can be used as components in the preparation of polyurethanes.

Polyether esters

An unsaturated polyester having recurring units of the formula ##STR1## wherein A is an alcoholic moiety, Q is a moiety of other saturated dicarboxylate acids and B is a moiety of an unsaturated dicarboxylic acid, n is 1 to 4, the sum l + m + g is 2 to 20 and l may be 0 or a whole number, said polyester generally having between 1 and 80 mole percent of a chlorinated phenylene acetic acid moiety whose formula is ##STR2## a solution of said such unsaturated polyester, particularly a solution of the same in a copolymerizable monomer, formed objects thereof and a process for the preparation of such unsaturated polyester.

Growing community of inventors

Troisdorf, Germany

Norbert Vollkommer