Dow Corning Corporation

Norbert Auner

Udo C Pernisz

Martin Grasmann

A silacyclobutene compound having the formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently chloro, triorganosiloxy, organooxy, triorganosilyl, or a monovalent hydrocarbon group; R.sup.3 is a monovalent hydrocarbon group free of conjugated aliphatic unsaturation or triorganosilyl; R.sup.5 is hydrogen or a monovalent hydrocarbon group free of conjugated aliphatic unsaturation; and R.sup.4 and R.sup.6 are independently hydrogen or a monovalent hydrocarbon group free of conjugated aliphatic unsaturation or together are an alkanediyl group, wherein the alkanediyl group and the carbon atoms to which it is attached form a carbocyclic ring having 4 to 7 carbon atoms; provided that R.sup.3 is not aryl. Methods of preparing the silacyclobutene compounds, silane polymers containing at least one silacyclobutene unit, and siloxane polymers containing at least one silacyclobutene unit.

Silacyclobutene compounds, methods of preparing same, and polymers

A silacyclobutane compound having the formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently chloro, triorganosiloxy, organooxy, triorganosilyl, or a monovalent hydrocarbon group; R.sup.3 is a monovalent hydrocarbon group free of conjugated aliphatic unsaturation, triorganosilyl, or hydrogen; and R.sup.4 is a monovalent saturated hydrocarbon group; provided that when R.sup.3 is hydrogen, neither R.sup.1 nor R.sup.2 is chloro or organooxy. Methods of preparing the silacyclobutane compounds, silane polymers containing at least one silacyclobutane unit, and siloxane polymers containing at least one silacyclobutane unit.

Silacyclobutane compounds, methods of preparing same, and polymers

Photoluminescent polydisilacyclobutanes are made by reacting a dialkenyldihalocarbosilane with an organolithium reagent in the presence of a solvent at 0-25 .degree. C.

Photoluminescent polydisilacyclobutanes

Photoluminescent polydisilacyclobutanes are made by reacting a dialkenyldihalosilane with an organolithium reagent in the presence of a solvent at 0-25.degree. C. Optional reactants such as aromatic acetylenic hydrocarbons or bicyclic dienes may also be included.

Silyl cation of the formula Si.sup.+ R.sub.2 R' wherein R denotes a hydrogen, a hydrocarbon or fluorine and R' denotes a norbornyl or cyclopentenyl containing substituent is free of co-ordination with a solvent and is stable at a temperature of upto at least 40.degree.C. Also disclosed is a compound consisting of the cation and a borate or carborane anion, a composition comprising the cation and a solvent and a process for making the cation.

Silyl cations and process for making them

Photoluminescent bicyclic polydisilacyclobutanes are made by reacting a dialkenyldihalocarbosilane with an organolithium reagent in the presence of a solvent at 0.degree.-25.degree. C.

Photoluminescent bicyclic polydislacyclobutanes

Silacyclobutene monomers, and polymers based on silacyclobutene building blocks, exhibit photoluminescence in the blue region of the visible spectrum when excited by ultraviolet light.

Growing community of inventors

Berlin, Germany

Norbert Auner