University of Michigan

The Penn State Research Foundation

University of Southern California

Princeton University

Uchicago Argonne, LLC

Noel Christopher Giebink

Stephen R Forrest

Mark Edward Thompson

Gary P Wiederrecht

Michael R Wasielewski

Yiru Sun

Baomin Wang

Thomas N Jackson

Haoyu Li

William Hancock

Chiao-Yu Cheng

Keith Mickolajczyk

Stephane Kena-Cohen

Yixin Yan

Yiyang Gong

The present disclosure generally relates to organic photosensitive optoelectronic devices and polaron pair recombination dynamics to impact efficiency and open circuit voltages of organic solar cells. The present disclosure also relates, in part, to methods of making organic photosensitive optoelectronic devices comprising the same.

Method of improving exciton dissociation at organic donor-acceptor heterojunctions

A method for generating antireflective coatings for polymeric substrates using a deposition process and/or a dissolving process can provide a coating onto the outer surface of the substrate. Some embodiments can include a GLAD generated fluoropolymer coating or a co-evaporated fluoropolymer coating on a substrate that may achieve ultralow refractive index as well as improved adhesion and durability properties on polymeric substrates. In some embodiments, the deposition process is performed such that a fluoropolymer can be evaporated to form chain fragments of the fluoropolymer. The chain fragments diffused into the substrate can subsequently re-polymerize, interlocking with the polymer chains of the substrate. In some embodiments, the co-evaporation process can form a nanoporous polymer chain scaffold of the fluoropolymer, from which a sacrificial material can be dissolved out. The formed coating can be a multilayer or continuously-graded antireflective coating that has strong adhesion with the substrate.

Broadband and omnidirectional polymer antireflection coatings

A method of generating a light-matter hybrid species of charged polaritons at room temperature includes providing an organic semiconductor microcavity being a doped organic semiconductor sandwiched in a microcavity capable of generating an optical resonance and coupling light to the polaron optical transition in the organic semiconductor microcavity thereby forming polaron-polaritons. The doped organic semiconductor may be a hole/electron transport material having a polaron absorption coefficient exceeding 10cmand capable of generating a polaron optical transition with a linewidth smaller than a predetermined threshold. The optical resonance of the microcavity has a resonance frequency matched with the polaron optical transition.

Charged polaron-polaritons in an organic semiconductor microcavity

An optical system and method to overcome luminescent solar concentrator inefficiencies by resonance-shifting, in which sharply directed emission from a bi-layer cavity into a glass substrate returns to interact with the cavity off-resonance at each subsequent reflection, significantly reducing reabsorption loss en route to the edges. In one embodiment, the system comprises a luminescent solar concentrator comprising a transparent substrate, a luminescent film having a variable thickness; and a low refractive index layer disposed between the transparent substrate and the luminescent film.

Resonance-shifting luminescent solar concentrators

Evanescently-coupled planar waveguides for enhancing total internal reflection fluorescence microscopy are disclosed. The waveguides include multiple thin layers of one or more materials on a cover slip arranged resonantly enhance the optical field at the surface of the layer stack by evanescently coupling to a leaky guided mode.

Waveguides for enhanced total internal reflection fluorescence microscopy

The present disclosure relates to focusing luminescent concentrators wherein directional emission, obtained by placing an absorber/emitter within a microcavity or photonic crystal, may be oriented by a macroscopic concentrator and focused to a point or line for 3D or 2D concentration, respectively. The focusing luminescent concentrators disclosed herein may provide high concentration ratios without the need for tracking, and may reduce re-absorption losses associated with conventional concentrators. The present disclosure further relates to photovoltaic cells and/or optical detector devices comprising a focusing luminescent concentrator. The devices and methods presently disclosed are also useful, for example, in solar, thermal and thermophotovolatic applications.

Focusing luminescent and thermal radiation concentrators

A device is provided. The device includes a first organic light emitting device, which further comprises a first electrode, a second electrode, and an organic emissive layer disposed between the first electrode and the second electrode. The device also includes a first laser device, which further comprises an optical cavity and an organic lasing material disposed within the optical cavity. A focus mechanism is disposed to focus light emitted by the first organic light emitting device onto the first laser device. Preferably, the focus mechanism provides light incident on the first laser device at least 10 times greater, and more preferably at least 100 times greater, in intensity than the light emitted by the first organic light emitting device.

Organic laser

Novel combination of materials and device architectures for organic light emitting devices is provided. An organic light emitting device, is provided, having an anode, a cathode, and an emissive layer disposed between the anode and the cathode. The emissive layer includes a host and a phosphorescent emissive dopant having a peak emissive wavelength less than 500 nm, and a radiative phosphorescent lifetime less than 1 microsecond. Preferably, the phosphorescent emissive dopant includes a ligand having a carbazole group.

Stable blue phosphorescent organic light emitting devices

Organic light emitting devices having a low-index electrode and a substrate with a surface treatment are provided. The combination of a relatively low-index electrode and a surface-treated substrate may eliminate guided modes and increase the light outcoupled by the device. It has been found that the combination surprisingly provides up to 1.5 times more outcoupled light than would be expected based on the performance of similar devices having higher-index electrodes.

Light emitting device with high outcoupling

The present invention relates to organic light emitting devices (OLEDs), and more specifically to OLEDS that emit light using a combination of fluorescent emitters and phosphorescent emitters for the efficient utilization of all of the electrically generated excitons.

Fluorescent filtered electrophosphorescence

A device comprising an organic light emitting layer may be optically pumped to create excited states within the layer. When an electric field is applied across the layer, the excited states may dissociate into geminate polaron pairs within the organic layer. The dissociated states may change back to excitons when the electric field is rapidly reduced or removed. The organic light emitting layer may be optically pumped by an adjacent OLED, allowing for an electrically-driven device.

Growing community of inventors

State College, PA, United States of America

Noel Christopher Giebink