Konica Corporation

Konica Minolta Opto, Inc.

Konica Corporation, a Corporation of Japan

Nobuo Kubo

Noriyasu Kuzuhara

Hiroki Umeda

Takatoshi Yajima

Sota Kawakami

Makoto Honda

Toshiaki Shibue

Takashi Takebe

Masataka Takimoto

Koji Tasaka

Eiichi Ueda

Nobuyuki Takiyama

Chiaki Nagaike

Yasuo Kurachi

Takashi Murakami

Akihisa Nakajima

Shigeto Ohmori

Hirokazu Sato

Akira Sato

Masaru Iwagaki

Kazuhiro Miyazawa

Shigeki Oka

Hirokazu Koyama

Satoshi Okano

Daisuke Doi

Disclosed is an optical film that has excellent adhesion and surface hardness between the film substrate and a hard coat layer or other functional layer, has improved brittleness, is transparent, and has low moisture absorption and high heat resistance. Additionally disclosed are an antireflective film, a polarizing plate, and a display device using the same. The optical film has at least a hard coat layer or a back coat layer as a functional layer containing a resin on a film substrate, and is characterized in that said film substrate contains a thermoplastic acrylic resin (A) and a cellulose ester resin (B), with the content ratio by mass of said thermoplastic acrylic resin (A) and said cellulose ester resin (B) being in a range thermoplastic acrylic resin (A):cellulose ester resin (B)=95:5 to 50:50.

Optical film, anti-reflection film, polarizing plate and liquid crystal display device

Disclosed is a polarizing plate having low moisture absorption, wherein fading deterioration of a polarizer is improved. A liquid crystal display using the polarizing plate is also disclosed. The polarizing plate is obtained by sandwiching a polarizer composed of a polyvinyl alcohol with an acrylic film (a) having a water vapor permeability of 100-500 g/m&#xb7;24 hr and a cellulose ester film (b1) containing no phosphate plasticizer or a cellulose ester film (b2) containing a phosphate plasticizer and an acid scavenger. The polarizing plate is arranged on at least one side of a liquid crystal cell, with the cellulose ester film (b1) or (B2) being on the liquid crystal cell side.

Polarizing plate and liquid crystal display

An acryl resin-containing film which is transparent and highly heat-resistant and has been significantly improved in brittleness is disclosed, satisfying the following equations (1) to (4), exhibiting a tension softening point of 105 to 145&#xb0; C. and a photoelastic coefficient of &#x2212;5.0&#xd7;10to 8.0&#xd7;10cm/N, while causing no ductile fracture. There is also disclosed a liquid crystal display which has achieved an improved yield in works of stamping a polarizing plate or sticking the plate to a panel and reduced color shift occurred depending on viewing angle.|(589)|&#x2266;10 nm&#x2003;&#x2003;Equation (1)|(589)|&#x2266;20 nm&#x2003;&#x2003;Equation (2)|(480)&#x2212;(630)|&#x2266;5 nm&#x2003;&#x2003;Equation (3)|(480)&#x2212;(630)|&#x2266;10 nm&#x2003;&#x2003;Equation (4) Numerical values of 589, 480 and 630 in parentheses represent the wavelength (nm) of a light used to measure an individual birefringence.

Acryl resin containing film, polarizing plate by use thereof and liquid crystal display

This invention provides an acrylic resin containing film, which is transparent and highly heat resistant and has significantly improved brittleness, and a polarizing plate using the acrylic resin containing film. Further yield in punching work and laminating work of the polarizing late is improved and a liquid crystal display device which can maintain good visibility in long term use is also provided by the polarizing plate. The acrylic resin containing film is composed mainly of an acrylic resin and is characterized in that the film contains the acrylic resin and the cellulose ester resin in a weight ratio of 51:49 to 95:5 and further contains a retardation control agent.

Acrylic resin containing film, and polarizing plate and a liquid crystal display device employing the same

Disclosed is a process for producing a polarizing plate which is transparent, has resistance against high temperatures and high humidity, and is significantly improved in brittleness. Specifically disclosed is a process for producing a polarizing plate comprising two polarizing plate protective films and a polarizer intercalated between the polarizing plate protective films, which is characterized in that at least one of the two polarizing plate protective films is an acrylic film comprising an acrylic resin (A) and a cellulose ester resin (B) at a ratio of 85:15 to 55:45 by mass, and the acrylic film is drawn in at least one direction at a draw ratio of 10 to 150% inclusive and is subsequently bonded to the polarizer with an aqueous adhesive agent.

Process for producing polarizing plate, polarizing plate produced by the process, and liquid crystal display device using the polarizing plate

The present invention is to provide an optical film which exhibits low hygroscopicity, high transparency, high heat resistance and markedly lowered brittleness, and particularly to provide an optical film which is appropriately employed as a polarizing plate protective film for large liquid crystal display devices and outdoor liquid crystal display devices. The above optical film is characterized in that acrylic resin (A) and cellulose ester resin (B) are incorporated at a weight ratio of 95:5-30:70, weight average molecular weight Mw of aforesaid acrylic resin (A) is at least 80,000, total substitution degree (T) of the acyl group of aforesaid cellulose ester resin (B) is 2.0-3.0, the substitution degree of the acyl group having 3-7 carbon atoms is 1.2-3.0, and weight average molecular weight Mw of aforesaid cellulose ester resin (B) is at least 75,000. It is characterized that the total substitution degree of the acyl group other than carbon atoms of 3-7 of the cellulose ester resin (B) is at most 1.3.

Optical film, polarizing plate and display device using the same, and manufacturing method thereof

Object of the present invention is to provide an acrylic-resin-containing film which exhibits high transparency, high heat resistance, and markedly improved brittleness, a polarizing plate using the acrylic-resin-containing film which improves a yield of operation such as punching of a polarizing plate or bonding panels and a liquid crystal display device which can keep to exhibit excellent visibility in long-terms usage in harsh environment. These objects have been achieved by the acrylic-resin-containing film comprising a acrylic resin (A) and a cellulose ester resin (B), or comprising the acrylic resin (A), the cellulose ester resin (B) and at least a resin (D) which is other than the resins (A) and (B) and has a glass transition temperature Tg of 120-300&#xb0; C. The film is characterized in that it has a haze of less than 2%, a tensile softening point of 120-150&#xb0; C. and undergoes no ductile fracture.

Acrylic-resin-containing film, polarizing plate and liquid crystal display device using the same

A method of producing and optical film, comprises the steps of: mixing a resin and grains, heating a mixture of the resin and the grains and kneading the heated melted mixture, thereby preparing a mixture material of the resin and the grains; dissolving the mixture material in a solvent, thereby preparing a resin solution; and casting the resin solution so as to form an optical film.

Method of manufacturing optical film

The method to produce the vertical alignment type liquid crystal display employs

Method for producing vertical alignment liquid crystal display

A manufacturing method of an optical film provided with a convexoconcave structure, comprises the steps of: coating a resin solution including a first resin solved by a solvent onto an endless or roll-like mold provided with a convexoconcave structure, and forming a resin solution layer on the mold; laminating a film substrate onto the resin solution layer to make a laminated film before the solvent in the resin solution layer is completely dried, the film substrate including a second resin, which is capable of absorbing the solvent or is soluble by the solvent; and peeling the laminated film from the mold before the solvent in the laminated film is completely dried.

Method for manufacturing an optical film having a convexoconcave structure

Disclosed is an optically anisotropic film used for a liquid crystal display of a vertical alignment liquid crystal mode comprising a fatty acid cellulose aster film, a retardation value (Rt value) in the thickness direction of the fatty acid cellulose ester film is from 60 to 300 nm, and the number of luminescent points having a size exceeding 50 &#x3bc;m is zero per 250 mm, and the number of luminescent points having a size of 5 to 50 &#x3bc;m is 200 or less per 250 mmwhen the fatty acid cellulose ester film is observed with two polarizing plates being provided on both surfaces of the fatty acid cellulose ester film so as to shield transmission light.

Optical film and liquid crystal display using the same

An optically anisotropic film is disclosed. The film comprises a fatty acid cellulose ester film support having an acetyl group and a propionyl group, and a liquid crystal layer containing a liquid crystal compound, or a resin layer containing polyimide, polyamidoimide, polyamide, polyether imide, polyether ether ketone, polyether ketone, polyketone sulfide, polyether sulfone, polysulfone, polyphenylene sulfide, polyphenylene oxide, polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polyacetal, polycarbonate, polyallylate, acrylic resin, polyvinyl alcohol, polypropylene, cellulose based plastics, epoxy resin, or phenol resin.

An optical compensation sheet comprising at least two optically anisotropic layers each formed by orienting an optically anisotropic compound, the orientation direction in the optically anisotropic layer plane of the optically anisotropic compound in the two optically anisotropic layers intersecting each other at an angle of from 80 to 100 degrees, wherein, viewing the two layers from one side of the sheet, one of the two layers, when the compound is uniaxial, is oriented so that a first angle of optic axis of the uniaxial optically anisotropic compound to the sheet plane increases continuously or stepwise in the thickness direction of the sheet, or when the compound is biaxial, is oriented so that a second angle of a direction giving maximum refractive index of the biaxial optically anisotropic compound to the sheet plane increases continuously or stepwise in the thickness direction of the sheet, and the other layer, when the compound is uniaxial, is oriented so that the first angle decreases continuously or stepwise in the thickness direction of the sheet, or when the compound is biaxial, is oriented so that the second angle decreases continuously or stepwise in the thickness direction of the sheet.

Optical compensation sheet and liquid crystal display

A film for a liquid crystal display comprising a fatty acid cellulose ester film having an acetyl group and a propionyl group is disclosed. Sum of degree of acetyl substitution (DSac) and degree of propionyl substitution (DSpr) of the fatty acid cellulose ester film of the film is 2.8 or less, and a retardation value (Rt value) in the thickness direction define by Formula 1 is 60 to 300 nm.

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Hachioji, Japan

Nobuo Kubo