Canon Kabushiki Kaisha

Nobuhiro Nakamura

Yuka Ishiduka

Atsushi Okuda

Hiroyuki Watanabe

Atsushi Fujii

Yota Ito

Tsutomu Nishida

Hideharu Shimozawa

Michiyo Sekiya

Kenichi Kaku

Hiroyuki Tomono

Kazuhisa Shida

Kazunori Noguchi

Hideaki Matsuoka

Haruyuki Tsuji

Kunihiko Sekido

Tomohito Ishida

Yuki Yamamoto

Akihiro Maruyama

Tatsuya Yamaai

Shuntaro Watanabe

Shuhei Iwasaki

Kazuko Sakuma

Takeshi Murakami

Koichi Nakata

Daisuke Miura

Haruki Mori

Kazuhiro Yamauchi

Yuichi Kikuchi

Kazumichi Sugiyama

Takashi Anezaki

Tatsuya Ikezue

Fumiyuki Hiyama

Masatada Hirota

Koji Takahashi

Harunobu Ogaki

Masaki Nonaka

Kentaro Yamawaki

Kohei Makisumi

Satoshi Otsuji

Kazuko Araki

Takahisa Taniguchi

There is provided an electrophotographic photosensitive member comprising: a support, a photosensitive layer, and a surface layer in this order, wherein an outer surface of the electrophotographic photosensitive member exhibits a wrinkled shape by having a concavo-convex shape, the surface layer comprises a binder resin and an inorganic particle, and at least a part of the inorganic particle exposes at a concave portion of the concavo-convex shape.

Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus

In an electrophotographic photosensitive member, wrinkles have a convex portion in which a linear shape portion having a length of 50 μm or longer exists, the linear shape portion is parallel to any one of L1 to L150 and L1651 to L1800, and each of L1 to L1800 intersects with the convex portion at a plurality of places, and at least two of the places have different intersection angles; and when height information of the wrinkles is subjected to a frequency analysis, and a two-dimensional power spectrum is obtained, a one-dimensional radial distribution function has at least one local maximum value, and when an angular distribution is calculated from the spectrum at a frequency of the local maximum value, the power values have a particular relationship.

Electrophotographic photosensitive member, process cartridge and electrophotographic apparatus

Provided is an electrophotographic photosensitive member that achieves satisfactory transferability. An electrophotographic photosensitive member including a charge generating layer, a charge transporting layer, and a protection layer laminated on a support in the stated order, wherein the protection layer contains a binder resin and particles, and wherein when an average thickness of the protection layer in a site free of the particles is represented by T and a volume-average particle diameter of the particles is represented by Dm in a cross-section of the protection layer, the following formula (a) is satisfied.  Formula(a)

The electrophotographic photosensitive member includes a support and a photosensitive layer on the support, in which a surface layer of the electrophotographic photosensitive member contains a particle, the surface layer has a particle partially exposed from the surface layer among the particle contained in the surface layer, the particle has a volume average particle diameter of 50.0 nm or more and 350.0 nm or less; in a cross-section of the surface layer, the number of the particle partially exposed from the surface layer is 80% by number or more based on a total number of the particle contained in the surface layer; and a total volume of an exposed portion of the particle partially exposed from the surface layer is 30% by volume or more and 80% by volume or less based on an entire volume of the particle contained in the surface layer.

There is provided an electrophotographic photosensitive member having drum shape, the electrophotographic photosensitive member including a support and a photosensitive layer, wherein an outer surface of the electrophotographic photosensitive member has wrinkles, and when an observation region having square form with one side of 100 μm is placed at an arbitrary position on the outer surface, a line that passes through a central point of the observation region and is parallel to a circumferential direction of the electrophotographic photosensitive member is defined as a first reference line L1, and 3,599 reference lines obtained by rotating the first reference line L1 at every 0.1° around the central point are defined as L2 to L3,600, respectively, each of L1 to L3,600 intersects with convex portions of the wrinkles at a plurality of locations and has at least two different intersection angles selected from the plurality of locations.

Electrophotographic photosensitive member

A method for producing an electrophotographic photosensitive member including: forming a photosensitive layer; and forming a protective layer, wherein the step of forming the photosensitive layer forms a photosensitive layer having an amount of residual solvent of a first solvent in the photosensitive layer of 0.05% to 2.50% and an amount of residual solvent of a second solvent in the photosensitive layer of 0.50% to 2.50%, and the step of forming the protective layer includes step (A) of forming a cured film and step (B) of forming the protective layer having wrinkle shapes, wherein, in step (A), the irradiated coating film is heated at a heating temperature lower than a boiling point of the first solvent and in step (B), the cured film is heated at a heating temperature higher than a boiling point of the first solvent.

Method for producing electrophotographic photosensitive member

A process cartridge including: an electrophotographic photosensitive member having a drum shape; a developing unit for developing an electrostatic latent image on the surface of the electrophotographic photosensitive member with toner; and a cleaning blade for removing the toner on the surface of the electrophotographic photosensitive member, the cleaning blade being in contact with the electrophotographic photosensitive member, wherein the electrophotographic photosensitive member comprises wrinkles on the surface of the electrophotographic photosensitive member, and wherein the toner has a fluidity torque E of 320 mJ or more.

Process cartridge

Provided is an electrophotographic photosensitive drum that achieves both of a reduction in torque of the electrophotographic photosensitive drum at the time of its cleaning and an improvement in image transferability. The electrophotographic photosensitive drum includes: a support; and a photosensitive layer arranged on the support, the electrophotographic photosensitive drum having arranged on an outer surface thereof at least two structure groups having different appearance periods, wherein when, out of the two structure groups, a group including structures having a smaller appearance period is defined as a first structure group, and a group including structures having a larger appearance period is defined as a second structure group, a height of the first structure group is lower than a height of the second structure group.

Electrophotographic photosensitive member having outer surface with first and second structure groups, the first structure group having a smaller appearance period and a lower height than the second structure group

A process cartridge which allows any spot and stripe as image defects to be suppressed is provided. A process cartridge, in which an electroconductive layer of a charging member has a matrix including a first rubber, and domains dispersed in the matrix, the domains include a second rubber and an electron electroconductive agent, at least some of the domains are exposed on a surface of the charging member, when a volume resistivity of the matrix is 10times or more a volume resistivity of the domains, a protective layer of an electrophotographic photosensitive member includes a metal oxide particle, and when a number average primary particle size of the metal oxide particle is defined as Sm and an average value of equivalent circle diameters of the domains is defined as Sd, the Sd/Sm satisfies the following expression (1): 0.5&#x3c;Sd/Sm&#x3c;100 . . . expression (1).

Process cartridge and electrophotographic apparatus

There is provided a process cartridge detachably attachable to a main body of an electrophotographic apparatus, the process cartridge including an electrophotographic photosensitive member and a charging member, wherein an outer surface of the charging member is composed of at least a matrix and at least a part of domains, a volume resistivity of the matrix is 1.0&#xd7;10times or more of a volume resistivity of the domain, an average value Sd of circle equivalent diameters of the domains observed on the outer surface of the charging member is in a predetermined range, the electrophotographic photosensitive member contains a support, a photosensitive layer, and a protective layer in this order and when a surface roughness of the protective layer is measured, each of a protruding valley portion Rvk, a load length ratio Mr2, and Sd/Rvk is in a predetermined range.

Process cartridge and electrophotographic apparatus using the same

The present disclosure provides an electrophotographic photosensitive member that suppresses electric potential fluctuations in repeated use. The electrophotographic photosensitive member includes a support, a photosensitive layer and a protective layer, in this order, wherein the photosensitive layer includes a compound having a structure represented by formula (1), and the protective layer includes a resin having a structure represented by formula (2) and a structure represented by formula (3).

Provided are an electrophotographic apparatus and a process cartridge each capable of suppressing the occurrence of a black spot (white background contamination) in an output image under a low-temperature and low-humidity environment. The electrophotographic apparatus includes: an electrophotographic photosensitive member including a support, a photosensitive layer, and a protective layer in the stated order; an exposing device; a developing device; and a cleaning device, wherein the protective layer has a triarylamine structure and a specific structure at a ratio in a specific range, and a toner contains toner particles each containing at least a resin, and an external additive. The toner has a volume-average particle diameter of 7 &#x3bc;m or more. The external additive contains a compound containing a titanium atom. The ratio of the mass of the compound containing a titanium atom to the total mass of the toner is 0.6 mass % or more.

Electrophotographic image forming apparatus and process cartridge

An electrophotographic photosensitive member having a protective layer wherein the density unevenness among output images is reduced with abrasion resistance maintained is provided. The present invention is an electrophotographic photosensitive member having a support, a photosensitive layer and a protective layer in this order, wherein the protective layer has a triarylamine structure and a cyclic structure represented by the formula (1) or (2): and an A value expressed by expression (4), A=S1/S2, wherein, in expression (4), S1 is a peak area based on in-plane deformation vibration of terminal olefin (CH&#x2550;), and S2 is a peak area based on stretching vibration of C&#x2550;O among peak areas of a spectrum obtained by measuring a surface of the protective layer by total reflection Fourier transform infrared spectroscopy using Ge as an internal reflection element and using a measurement condition of 45&#xb0; as an incidence angle is from 0.065 to 0.100.

A method for producing an electrophotographic photosensitive member having a photosensitive layer and a protective layer above a support in this order includes: forming a coating film for a protective layer by coating a coating liquid for the protective layer for forming the protective layer on the photosensitive layer and curing the coating film for the protective layer, in which the coating liquid for the protective layer contains a solvent, a compound represented by a general formula (1), a compound represented by a general formula (2), and a compound represented by a general formula (3) at a specific ratio. In addition, in an electrophotographic photosensitive member having a photosensitive layer and a protective layer above a support in this order, the protective layer is obtained by curing a coating liquid for the protective layer.

Electrophotographic photosensitive member and method for producing electrophotographic photosensitive member

To provide an electrophotographic photosensitive member which does not cause film exfoliation in long-term use. An electrophotographic photosensitive member, having: a support; a layered photosensitive layer; and a protective layer in this order, wherein the protective layer is a single layer, the protective layer includes: at least two specific structures, the two specific structures are included in the protective layer at a mass ratio of 20% or more and 240% or less, and a peak area based on in-plane deformation vibration of terminal olefin (CH&#x2550;) of the protective layer and a peak area based on stretching vibration of C&#x2550;O of acryloyloxy groups, the peak areas being determined by total reflection Fourier transform infrared spectroscopy under conditions where an internal reflection element is Ge, and an incidence angle is 45&#xb0;, have a fixed relationship.

Electrophotographic photosensitive member and method for manufacturing the same as well as process cartridge and electrophotographic image-forming apparatus

Growing community of inventors

Numazu, Japan

Nobuhiro Nakamura