Nippon Paint Automotive Coatings Co., Ltd

Nobuhiro Miyamae

Tetsuya Ohara

Toshio Inbe

Takeshi Hara

Masahiko Harada

Noriyuki Nakazawa

Masayuki Kotani

Yohei Tago

Yosuke Shimodaira

Taku Kanazawa

Sari Nakashima

Makoto Andou

Hirohisa Kano

Saki Akagi

Tatsuo Ohta

An object of the present invention is to provide a preparation method for improving the edge part rust prevention property in the preparation of a cationic electrodeposition coating composition containing a bismuth compound as a curing catalyst. The present invention provides a method for preparing a cationic electrodeposition coating composition, including a step of preparing a resin emulsion (i) containing an aminated resin (A) and a blocked isocyanate curing agent (B), a step of preparing a pigment dispersion paste (ii) containing a bismuth-metal oxide mixture liquid (C) containing a bismuth compound (c1), a metal oxide (c2), a monohydroxycarboxylic acid (c3) having 3 to 5 carbon atoms in total and a solvent; a pigment dispersion resin (D); a polyvalent acid (E); and a pigment (F), and a step of mixing the resin emulsion (i) and the pigment dispersion paste (ii).

Method for preparing cationic electrodeposition coating composition

It is an object of the present invention is to provide an electrodeposition coating composition and an electrodeposition coating method that enable the formation of a cured electrodeposition coating film that develops excellent throwing power and exhibits a good appearance. An electrodeposition coating composition of the present invention comprising:

Electrodeposition coating composition and electrodeposition coating method

The present invention relates to a cationic electrodeposition coating composition containing a resin emulsion containing an aminated resin (A) and a blocked isocyanate curing agent (B), characterized in that a deposited electrodeposition coating film of the cationic electrodeposition coating composition has a coating film viscosity in a range of 5,000 to 1,000,000 mPa&#xb7;s at 110&#xb0; C., and a portion resulting from removal of a resin component from the deposited electrodeposition coating film of the cationic electrodeposition coating composition has a polarity term in a range of 2 to 30 mN/m.

Cationic electrodeposition coating material composition

The objective of the present invention is to provide a method for preparing a cationic electrodeposition coating composition that contains a bismuth compound and exhibits excellent coating material stability, curability, coating film appearance and the like. The present invention provides a method for preparing a cationic electrodeposition coating composition, which comprises a step for mixing a resin emulsion (i) and a pigment-dispersed paste, and wherein: the resin emulsion (i) contains an aminated resin (A) and a blocked isocyanate curing agent (B); the pigment-dispersed paste contains a bismuth mixture (C) that is obtained by mixing a bismuth compound (c1) and an organic acid (c2) in advance, a pigment-dispersed resin (D), an amine-modified epoxy resin emulsion (ii) that contains an amine-modified epoxy resin (E), and a pigment (F); the pigment-dispersed resin (D) has a hydroxyl number of 20-120 mgKOH/g; and the amine-modified epoxy resin (E) has a hydroxyl number of 150-650 mgKOH/g.

A method for preparing an emulsion for a cationic electrodeposition coating composition at an emulsification field, wherein the method includes synthesizing a base resin for a cationic electrodeposition coating composition, removing the base resin in a liquid state from a reaction vessel and then changing the resin into a solid state, and optionally, adjusting a size of the resin into an predetermined size, and emulsifying the resin at the emulsification field by adding water and an optional solvent, a neutralizing agent, a curing agent or additives, wherein the base resin is an aminated resin and has a softening point of 20-90&#xb0; C., and wherein the adjusted shortest size of the base resin is 40 cm or less. Furthermore, the present application relates to a method for transporting a resin for cationic electrodeposition coating composition.

Method for preparing emulsion for cationic electrodeposition coating composition in emulsification field and transporting method for aminated resin

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Hirakata, Japan

Nobuhiro Miyamae