Mitsubishi Heavy Industries Limited

Mitsubishi Jukogyo Kabushiki Kaisha

Mitsubishi Heavy Industrials, Ltd.

Nobuhiro Hokao

Yasuhiro Yamauchi

Kan Ogata

Masakazu Tateishi

Tadatsugu Fukuzumi

Naoki Shindo

Yoshihiko Tsuchiyama

Takashi Moribe

Mitsuji Iwao

Nobuyuki Ikeda

Yasushi Mori

Akihiko Fujimoto

Tsuyoshi Sato

Tokuji Matsuo

A PCB decomposition reactor includes: an injector for injecting a mixture of water and sodium hydroxide connected to the lower part of the reaction vessel; an outlet pipe for withdrawing treated fluid connected to the sidewall of the reaction vessel and a cyclone for separating sodium carbonate from the treated fluid; a discharge pipe connected to the top of the cyclone to discharge treated fluid from which precipitated sodium carbonate has been removed; a downcomer for the separated fluid connected to the bottom of the cyclone so that precipitated sodium carbonate and fluid containing it are discharged therethrough and to an injector which is connected to a feed pipe for feeding a mixture of PCB and mineral oil; and a gas supply nozzle for injecting a gas into the reaction vessel installed at the bottom of the reaction vessel.

PCB decomposition reactor

The present invention provides a PCB decomposing apparatus capable of decomposing PCB efficiently. The PCB decomposing apparatus comprises a PCB extracting container for extracting PCB from a PCB-containing material with an organic solvent. A distilling tower provided on the downstream side of the PCB extracting container distills the organic solvent to separate the PCB. A primary reactor provided on the downstream side of the distilling tower includes a nozzle for supplying aqueous Na CO solution and a nozzle for supplying an oxidizing agent into the container. A liquid cyclone provided on the downstream side of the primary reactor can remove Na CO having a large particle size. A secondary reactor formed by a long pipe is connected to the liquid cyclone. A gas-liquid separator provided on the further downstream side of the secondary reactor can separate a gas from a solution. A film separator separates treated water into purified water and a concentrated solution, and the purified water is supplied as circulating water to the upstream side of a pressure pump.

Apparatus for decomposing PCB

This invention provides a PCB decomposition reactor which can decompose PCB efficiently. In this PCB decomposition reactor, an injector for injecting a mixture of water and sodium hydroxide into a reaction vessel is connected to the lower part of the reaction vessel. An outlet pipe for withdrawing the fluid treated within the reaction vessel is connected to the sidewall of the reaction vessel. The other end of the outlet pipe is connected to a cyclone for separating sodium carbonate from the treated fluid. A discharge pipe is connected to the top of the cyclone, so that the treated fluid from which the precipitated sodium carbonate has been removed is discharged therethrough. A downcomer for the separated fluid is connected to the bottom of the cyclone, so that the precipitated sodium carbonate and some fluid containing it are discharged therethrough. The lower end of the downcomer is connected to an injector, which has connected thereto a feed pipe for feeding a mixture of PCB and mineral oil. A gas supply nozzle for injecting a gas into the reaction vessel is installed at the bottom of the reaction vessel.

The present invention provides a PCB decomposing apparatus capable of decomposing PCB efficiently. The PCB decomposing apparatus comprises a PCB extracting container for extracting PCB from a PCB-containing material with an organic solvent. A distilling tower provided on the downstream side of the PCB extracting container distills the organic solvent to separate the PCB. A primary reactor provided on the downstream side of the distilling tower includes a nozzle for supplying aqueous Na,CO,solution and a nozzle for supplying an oxidizing agent into the container. A liquid cyclone provided on the downstream side of the primary reactor can remove Na,CO,having a large particle size. A secondary reactor formed by a long pipe is connected to the liquid cyclone. A gas-liquid separator provided on the further downstream side of the secondary reactor can separate a gas from a solution. A film separator separates treated water into purified water and a concentrated solution, and the purified water is supplied as circulating water to the upstream side of a pressure pump.

Method for decomposing PCB

A gas-liquid separating apparatus for separating gas and liquid of a gas-liquid mixture includes a drum, and a separator disposed in the drum. The gas-liquid enters the separator into a cylinder of the separator in a tangential direction, and thus flows along the inner wall surface of the cylinder so that centrifugal separation of the gas and liquid is effected. The gas is discharged into a gas-phase section of the drum. At least part of the primary isolated liquid is decelerated by a perforated plate of the separator from which the liquid flows into a liquid-phase section of the drum. Because the primary isolated liquid flowing into the liquid-phase section of the drum has a slow outflow velocity, it tends to flow upwardly in the vicinity of the cylinder due to the buoyancy of gas still entrained in the liquid. Accordingly, the gravitational separation of the entrained gas and liquid is facilitated.

Gas-liquid separating apparatus

Growing community of inventors

Nagasaki, Japan

Nobuhiro Hokao