Tdk Electronics Company, Limited

Tdk Corporation

Tdk Kabushiki Kaisha

Nobuaki Kikuchi

Shinobu Fujiwara

Kiyoshi Furukawa

Hitoshi Tanaka

Osamu Iizawa

Hisayoshi Ueoka

Yasunobu Oikawa

Sho Masujima

Masahiro Yahagi

Shuichi Ono

Shuichi Itagaki

Hisao Abe

Tsunehiko Yoshioka

Yoshifumi Midori

Kenichi Umeda

Iwaya Shoichi

Masahide Shibuya

A semiconductive ceramic composition for a reduction reoxidation type semiconductive ceramic capacitor capable of increasing capacitor, dielectric strength of the capacitor and improving temperature characteristics of the capacitor. The composition includes a BaTIO.sub.3 base component and a minor component consisting of Nb and Ce. Nb and Ce are present in amounts of 0.2 to 3.0 mol % on Nb.sub.2 O.sub.5 and CeO.sub.2 bases. Addition of Co and the like increases insulation resistance and D.C. breakdown voltage of the capacitor and further improves temperature characteristics of the capacitor.

Semiconductive ceramic composition

A D-E hysteresis loop of ferroelectrics known in the art has a square shape when the ferroelectrics are a BaTiO.sub.3 single crystal. Such ferroelectrics are used as a non-linear dielectric element of, for example a pulse generating device. The non-linear dielectric element according to the present invention consists of a polycrystal, which is mainly composed of BaTiO.sub.3 and has the chemical composition expressed by the formula A.sub.y B.sub.z O.sub.3, wherein the molar ratio of y/z ranges from 0.92 to 0.99. The non-linearity is excellent and the temperature dependence of the A.sub.y B.sub.z O.sub.3 composition is considerably low.

Non-linear dielectric element

A novel ceramic composition exhibiting a solid solution structure of Pb(Fe.sub.1/2 Nb.sub.1/2)O.sub.3 -Pb(Mg.sub.1/3 Nb.sub.2/3)O.sub.3 -Pb(Mg.sub.1/2 W.sub.1/2)O.sub.3, can be sintered at a low sintering temperature; have a high insulation resistance; have a relatively high dielectric constant in the high dielectric type ceramic dielectrics, and; have a low dielectric loss. A particular amount of the additives, i.e., Pb-(Mn.sub.2/3 W.sub.1/3)O.sub.3, Pb(Mb.sub.1/2 W.sub.1/2)O.sub.3 Pb(Mn.sub.1/2 Nb.sub.2/3)O.sub.3, MnO, Pb(Mn.sub.1/3 Ta.sub.2/3)O.sub.3, Li.sub.2 O, Cr.sub.2 O.sub.3 and CeO.sub.2, is added into the composition mentioned above.

High dielectric constant type ceramic composition consisting essentially

A basic ceramic composition of high dielectric constant type ceramic composition comprises from 68.67 to 69.19% of PbO, from 3.67 to 4.09% of MgO, from 24.17 to 26.99% of Nb.sub.2 O.sub.5 and from 0.25 to 2.97% of TiO.sub.2, all percentages being by weight. Modified composition may comprise additive of Pb(Mn.sub.2/3 W.sub.1/3)O.sub.3, Pb(Mn.sub.1/3 Nb.sub.2/3)O.sub.3, Pb(Mn.sub.1/3 Ta.sub.2/3)O.sub.3, Pb(Mn.sub.1/2 W.sub.1/2)O.sub.3, MnO, and MgO. Modified composition may comprise Ba, Sr and Ca, which replace Pb of the basic ceramic composition. In a modified composition, the content of B site elements may be larger than that of A site element of an ABO.sub.3 crystal of the high dielectric constant type ceramic composition. A high dielectric constant, low dielectric loss, low temperature dependence of capacitance, high insulation resistance and a low sintering temperature are provided by the ceramic compositions of the present invention.

High dielectric constant type ceramic composition

A novel ceramic composition exhibiting a solid solution structure of Pb(Fe.sub.2/3 W.sub.1/3)O.sub.3 --Pb(ZrO.sub.3), can be sintered at a low sintering temperature; have a high insulation resistance; have a relatively high dielectric constant in the high dielectric type ceramic dielectrics; have a low dependence of dielectric constant upon temperature, and; have a low dielectric loss. A particular amount of the additives, i.e., MnO, Pb(Mn.sub.1/3 Nb.sub.2/3)O.sub.3, Pb(Mn.sub.1/2 W.sub.1/2)O.sub.3, Pb(Mn.sub.2/3 W.sub.1/3)O.sub.3, Pb(Mn.sub.1/3 Ta.sub.2/3)O.sub.3, Cr.sub.2 O.sub.3 and CeO.sub.2, is added into the composition mentioned above.

A novel ceramic composition exhibiting a solid solution structure of Pb(Fe.sub.1/2 Nb.sub.1/2)O.sub.3 --Pb(Mg.sub.1/3 Nb.sub.2/3)O.sub.3, can be sintered at a low sintering temperature; have a high insulation resistance; have a relatively high dielectric constant in the high dielectric type ceramic dielectrics, and; have a low dielectric loss. A particular amount of the additives, i.e., pb(Mn.sub.1/2 W.sub.1/2)O.sub.3, Pb(Mn.sub.1/3 Nb.sub.2/3)O.sub.3, MnO, Pb(Mn.sub.1/3 Ta.sub.2/3)O.sub.3 Li.sub.2 O, Cr.sub.2 O.sub.3 and CeO.sub.2, is added into the composition mentioned above.

A novel ceramic composition exhibiting a solid solution structure of Pb(Fe.sub.1/2 Nb.sub.178 )O.sub.3 -Pb(Mg.sub.1/3 Ta.sub.2/3)O.sub.3, can be sintered at a low sintering temperature; have a high insulation resistance; have a relatively high dielectric constant in the high dielectric type ceramic dielectrics, and; have a low dielectric loss. A particular amount of the additives, i.e., Pb(Mn.sub.1/2 W.sub.1/2)O.sub.3, Pb(Mn.sub.1/3 Nb.sub.170 )O.sub.3, MnO, Pb(Mn.sub.1/3 Ta.sub.170 )O.sub.3, Li.sub.2 O, Cr.sub.2 O.sub.3 and CeO.sub.2, is added into the composition mentioned above.

A ceramic dielectric composition which comprises 22.5-45.2 wt. % SrO, 8.3-20.6 wt. % CaO, 29.3-80.8 wt. % TiO.sub.2, and 0.07-8.3 wt. % MgO as main components.

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Akita, Japan

Nobuaki Kikuchi