Shin-Etsu Chemical Co., Ltd.

Shin-Etsu Chemical C O., Ltd.

Nobu Kato

Noriyuki Meguriya

Shigeki Shudo

Hidenori Mizushima

Shigeru Ubukata

Munenao Hirokami

Tatsuei Hara

Toshio Yamazaki

Kenichi Tsuji

Mikio Iino

Ryo Ashida

The present invention provides an addition-curable self-adhesive silicone rubber composition and a silicone rubber cured product. An addition-curable self-adhesive silicone rubber composition which contains:

Addition-curable self-adhesive silicone rubber composition and silicone rubber cured product

An addition-curable silicone rubber composition which contains: 100 parts by mass of (A) an organopolysiloxane that has at least two alkenyl groups, each of which is bonded to a silicon atom, in each molecule, and wherein an alkenyl group is bonded to a silicon atom at one end or both ends of the molecular chain; 1-80 parts by mass of (B) γ-cyclodextrin; (C) an organohydrogen polysiloxane that has at least two hydrogen atoms, each of which is bonded to a silicon atom, in each molecule in such an amount that the molar ratio of the hydrogen atoms bonded to silicon atoms (Si—H groups) to the total amount of the alkenyl groups bonded to silicon atoms in the entire composition, namely (Si—H groups)/(Si-alkenyl groups) is from 0.5 to 5.0; and a catalytic amount of (D) an addition reaction catalyst.

Addition-curable silicone rubber composition and method for producing same

An addition-curable liquid silicone rubber composition and a molded silicone-rubber object are provided. The addition-curable liquid silicone rubber composition comprises

Addition-curable liquid silicone rubber composition and molded silicone-rubber object

The purpose of the present invention is to provide an addition-curable silicone rubber composition which gives a cured product having a controlled oil-bleeding property and releasability from a mold, without increasing an amount of a bleeding oil to be added. Thus, the present invention provides an addition-curable silicone rubber composition comprising the following components (A) to (D): wherein Ris, independently of each other, an unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, Ris, independently of each other, a monovalent aromatic hydrocarbon group having 6 to 12 carbon atoms, the amount of the monovalent aromatic hydrocarbon group is at least 35 mol % and less than 50 mol %, relative to a total amount of all substituents each bonded to a silicon atom, that is, all of Rand R, m is an integer of from 0 to 3, m' is an integer of from 0 to 3, n&#x2032; is an integer of from 0 to 3, n is an integer of from 10 to 20, and m+m&#x2032;+n+n&#x2032; is in a range of from 10 to 22.

Addition-curable silicone rubber composition

Provided is an addition-curable liquid silicone rubber composition which has good curability and still provides a silicone rubber having a durometer type A hardness of 5-15 as measured after being cured and a high tear strength. The addition-curable liquid silicone rubber composition contains (A) an alkenyl group-containing organopolysiloxane having two or more silicon atom-bonded alkenyl groups per molecule, and an average polymerization degree of 1,500 or less, and is liquid at 25&#xb0; C., (B) (B-1) an organohydrogenpolysiloxane containing six or more silicon atom-bonded hydrogen atoms per molecule, and not having an aromatic group, (B-2) an organohydrogenpolysiloxane containing 3-5 silicon atom-bonded hydrogen atoms per molecule, and not having an aromatic group, (B-3) an organohydrogenpolysiloxane containing 1 or 2 silicon atom-bonded hydrogen atoms per molecule, and not having an aromatic group, (C) a fumed silica having a BET specific surface area of 130 m/g or more, and (D) an addition reaction catalyst.

Addition-curable liquid silicone rubber composition

An addition-curable silicone rubber composition which contains: 100 parts by weight of (A) an organopolysiloxane that is represented by average composition formula (1) RSiO(wherein Rrepresent monovalent hydrocarbon groups that are the same as or different from each other, and a represents a positive number of 1.5-2.8) and has at least two alkenyl groups, each of which is bonded to a silicon atom, in each molecule; 0.3-20 parts by weight of (B) an organohydrogen polysiloxane that has at least two hydrogen atoms (SiH functional groups), each of which is bonded to a silicon atom, in each molecule; 5-80 parts by weight of (C) a reinforcing silica; and (D) an addition reaction catalyst, which is configured of a platinum group metal, in an amount of 0.5-1,000 ppm relative to the total weight of the components (A) and (B). This addition-curable silicone rubber composition also contains (E) an organopolysiloxane, which has one or more Si&#x2014;OH functional groups in each molecule, while having a polymerization degree of 10 or less, in an amount of 0.005-0.3% by weight relative to the total weight of the composition.

Addition-curable silicone rubber composition and silicone rubber

This thermally-conductive silicone composition comprises: (Rrepresents an alkyl group, and a is 5-100) and of which one end is trifunctional,  (Rrepresents H or a monovalent hydrocarbon group, and Rrepresents a monovalent organic group). The composition can inhibit the decrease of the curing speed. A cured product of the composition has a small hardness increase when being aged at a high temperature, and has a small heat resistance increase after undergoing a heat cycle test.

Thermally-conductive silicone composition

Provided is an addition-curable silicone rubber composition that contains (A) an alkenyl group-containing organopolysiloxane, (B) an organohydrogenpolysiloxane, (C) a platinum catalyst and (D) a reinforcement filler material surface treated with a benzotriazole derivative represented by formula (I) (in the formula, Ris a hydrogen atom or a monovalent hydrocarbon group and Ris a monovalent organic group) and that is capable of lowering the compression set of a cured article and suppressing changes in hardness after heat degradation characteristic testing while suppressing reduced curability. Also provided are a cured article thereof and a manufacturing method for the addition-curable silicone rubber composition.

Addition-curable silicone rubber composition and cured product

Provided is an addition-curable silicone rubber composition containing 

Provided is an addition-curable liquid silicone rubber composition which is suppressed in thickening over time even in cases where a silicone raw rubber is added into a liquid silicone rubber composition, thereby having excellent storage stability, and which provides a silicone rubber that has a low hardness after being cured. An addition-curable liquid silicone rubber composition which contains: (A) an alkenyl group-containing organopolysiloxane having an average polymerization degree of 1,500 or less, which is in a liquid state at room temperature; (B) an organopolysiloxane having an average polymerization degree of 2,000 or more, which is in the form of a raw rubber at room temperature; (C) an organohydrogen polysiloxane; (D) a fumed silica having a BET specific surface area of 130 m/g or more; (E) an organosilane and/or organopolysiloxane having a silanol group; and (F) an addition reaction catalyst. This addition-curable liquid silicone rubber composition provides a low-hardness silicone rubber which has a hardness (durometer A) of 5-40 after being cured.

An addition curable self-adhesive silicone rubber composition is provided. This silicone rubber composition comprises (A) 100 parts by weight of an organopolysiloxane containing at least 2 alkenyl groups bonded to silicon atoms per molecule, (B) 0.05 to 10 parts by weight of an organosilicon compound containing 1 to 100 silicon atoms which has at least 1 phenylene skeleton per molecule, and which has at least 1 hydrogen atom bonded to a silicon atom, (C) 0 to 30 parts by weight of an organohydrogenpolysiloxane containing at least 2 hydrogen atoms bonded to silicon atoms per molecule, and containing no phenylene skeleton in the molecule, (D) 0.001 to 0.1 part by weight of a triazole compound, and (E) a catalytic amount of a platinum catalyst. This silicone rubber composition is capable of forming a cured article having good adhesion to various organic resins.

Addition curable self-adhesive silicone rubber composition

An addition curable self-adhesive silicone rubber composition comprising (A) an organopolysiloxane containing alkenyl at either end, (B) an organosilicon compound containing phenylene and SiH group, (C) an organohydrogenpolysiloxane containing two SiH groups, (D) an organohydrogenpolysiloxane containing at least three SiH groups, and (E) an addition reaction catalyst is integrally moldable with thermoplastic resins.

An addition curable self-adhesive silicone rubber composition comprising (A) an organopolysiloxane containing at least two alkenyl groups, (B) an organohydrogenpolysiloxane containing at least three SiH groups, (C) another organohydrogenpolysiloxane containing no other reactive groups than SiH groups, and (F) an addition reaction catalyst, with a SiH/alkenyl molar ratio ranging from 0.8 to 5.0, is briefly moldable and cures to various metals and organic resins.

An addition curable self-adhesive silicone rubber composition comprising (A) an organopolysiloxane containing at least two alkenyl groups, (B) an organohydrogenpolysiloxane containing at least three SiH groups, (C) an aromatic ring-free organohydrogenpolysiloxane containing at least two SiH groups, and (F) an addition reaction catalyst, with a SiH/alkenyl molar ratio ranging from 0.8 to 5.0, is briefly moldable and cures to various metals and organic resins.

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Annaka, Japan

Nobu Kato