Nippon Shokubai Co., Ltd.

Nippon Shokubai Kagaku Kogyo Co., Ltd.

Noboru Sugishima

Shinyuki Masaki

Noriaki Ikeda

Motonobu Kobayashi

Atsushi Morita

Yasushi Fujii

Akira Inoue

Ryoji Kuma

Junji Okamura

Yoshiyuki Nakanishi

Ryuji Aoki

Shinji Ikuta

Yumi Hatta

Koichi Yamamoto

Yasuhiko Kizu

Jyunichiro Kugai

Katsunori Miyoshi

The present invention has an object to more enhance the efficiency of the purification of the CO-containing exhaust gases with a catalytic-component-supporting type catalyst, particularly, to enable both achievement of high purification efficiency and long-term stable maintenance of high purification efficiency without increasing the quantity of the catalytic component as supported. As a means of achieving this object, a process for purification of exhaust gases, according to the present invention, is a process for purification of exhaust gases to remove CO therefrom, and is characterized by comprising the step of bringing the exhaust gases into contact with a catalyst layer at a temperature of 250 to 600&#xb0; C., a pressure drop of not more than 100 mmHO, and a linear velocity of 0.5 to 10 m/s, wherein the catalyst layer includes a honeycomb-structural catalyst having an opening size of 1.0 to 3.0 mm, an opening ratio of 60 to 80%, and an inner wall thickness of less than 2 mm.

Process for purification of exhaust gases and catalyst used for purification of exhaust gases in this process

An object of the present invention is to provide a new method for treating an exhaust gas, which can effectively treat an exhaust gas containing a nitrogen oxide and metal mercury over a long term, and also can be applied to treatment of a large volume of an exhaust gas. As a means of achieving this object, a method according to the present invention for treating an exhaust gas comprises performing a reaction of changing metal mercury into mercury halide in the presence of a halogen compound and treatment of a nitrogen oxide, using a Ti&#x2014;V-containing catalyst, upon treatment of an exhaust gas containing a nitrogen oxide and metal mercury.

Method for treating exhaust gas

A catalyst for purification of CO-containing exhaust gases, includes a metal oxide as a support and a catalytic component A being supported thereon as a catalytic component and including a specific noble metal element; wherein the support includes a titanium-containing oxide as the metal oxide and is a monolithically molded type porous honeycomb support obtained by a process including the steps of extrusion-molding and then calcining materials of the support; and wherein the catalytic component A is distributed with a quantitatively great inclination toward surfaces of the catalyst. A process for purification of exhaust gases to remove CO therefrom, includes the step of bringing the exhaust gases into contact with the catalyst.

Catalyst for purification of exhaust gases and process for purification of exhaust gases

The present invention provides: a catalyst for purification of exhaust gases which catalyst is excellent as a denitrification catalyst which has still more excellent ability to remove nitrogen oxides and of which the ability to oxidize sulfur dioxide into sulfur trioxide is extremely suppressed and further as a catalyst which is favorable for efficiently removing organohalogen compounds, such as dioxins, from exhaust gases; a production process therefor; and a process for purification of exhaust gases. The catalyst for purification of exhaust gases comprises titanium oxide, molybdenum oxide, and vanadium oxide as catalytic components, wherein the titanium oxide and the molybdenum oxide are included in the catalyst in the form of: a binary closely mixed oxide which is beforehand prepared and includes titanium and molybdenum; and/or a trinary closely mixed oxide which is beforehand prepared and includes titanium, silicon, and molybdenum.

Catalyst for purification of exhaust gases, production process therefor, and process for purification of exhaust gases

The present invention provides: a catalyst which has more excellent removability upon organohalogen compounds and is suitable for removing the organohalogen compounds from exhaust gases; and a process for removing organohalogen compounds with this catalyst. The catalyst for removing organohalogen compounds comprises titanium oxide (TiO) and vanadium oxide as catalytic components, and has pores that includes a group of pores having a pore diameter distribution peak in the range of 0.01 to 0.05 &#x3bc;m and another group of pores having a pore diameter distribution peak in the range of 0.1 to 0.8 &#x3bc;m, and this catalyst is characterized by further comprising an oxide of at least one metal selected from the group consisting of manganese, cobalt, nickel, zinc, zirconium, niobium, molybdenum, tin, tantalum, lanthanum and cerium as another catalytic component. The process for removing organohalogen compounds involves the use of this catalyst.

Catalyst and process for removing organohalogen compounds

The present invention provides a process for the purification of exhaust gases which process enables to effectively inhibit the discharge of the dioxins by low-cost modification of already existing incineration facilities which are formed from an incinerator and an electric dust collector or cyclone. Incinerator exhaust gases a dedusted with an electric dust collector or cyclone, and then treated with a ceramic filter to sufficiently remove dust from the exhaust gases and brought into contact with a catalyst to decompose and thereby remove the dioxins which are contained in the exhaust gases.

Process for the purification of exhaust gases

The present invention provides a catalyst having excellent capability of removing organic halogen compounds such as dioxins, a method for preparing the catalyst, and a method for removing organic halogen compounds using the catalyst. A catalyst for removing organic halogen compounds comprises titanium oxide as a catalyst component and has pores including a group of pores having a pore diameter distribution peak in a range of 0.01 to 0.05 gm and another group of pores having a pore diameter distribution peak in a range of 0.1 to 0.8 .mu.m. Another catalyst for removing organic halogen compounds comprises titanium oxide and a titanium-silicon composite oxide as catalyst components and has pores including a group of pores having a pore diameter distribution peak in a range of 0.01 to 0.05 .mu.m and another group of pores having a pore diameter distribution peak in a range of 0.8 to 4 .mu.m.

Catalyst for removing organic halogen compounds, preparation method

There is provided a denitration catalyst excellent in denitration activity and durability in a high temperature region, for catalytically reducing NOx in an exhaust gas using a reducing agent such as ammonia. This denitration catalyst is (1) one containing a titanium-tungsten oxide obtained by coprecipitating a soluble titanium compound and a soluble tungsten compound from an aqueous medium under the conditions of a temperature of 60.degree. C. or less and a pH of the range of 5 to 8, and drying and calcining to coprecipitate formed; or (2) one comprising said titanium-tungsten oxide (component A), and an oxide of at least one element (component B) selected from the group consisting of cerium (Ce), lanthanum (La), praseodymium (Pr), neodymium (Nd), nickel (Ni) and tin (Sn).

Denitration catalyst

In processes for preparing a ceric ion-containing aqueous acid solution by electrolytically oxidizing cerous ions in a cerous ion-containing aqueous acid solution using a diaphragm-free electrolytic bath having no diaphragm between the anode and the cathode, a process for preparing a ceric ion-containing aqueous acid solution which comprises making at least one heterocyclic compound selected from the group consisting of five-membered heteromonocyclic compounds having substituent(s), six-membered heteromonocyclic compounds having substituent(s) and condensed heteropolycyclic compounds exist in the cerous ion-containing aqueous acid solution.

Process for preparing a ceric ion-containing aqueous acid solution

A process for preparation of a 2-substituted-1,4-naphthoquinone which comprises oxidizing a 2-substituted naphthalene to obtain reaction products comprising a 2-substituted-1,4-naphthoquinone and a 6-substituted-1,4-naphthoquinone; adding a diene compound to the reaction products and heating the mixture to form a Diels-Alder reaction adduct between the diene compound and the 6-substituted-1,4-naphthoquinone in the reaction products; and separating the 2-substituted-1,4-naphthoquinone from the adduct.

Process for preparation of 2-substituted 1,4-naphthoquinone

A process for producing 1-aminoanthraquinones represented by formula (C) ##STR1## wherein R.sup.1 and R.sup.2, independently from each other, denote one type selected from a hydrogen atom, an alkyl group having 1 to 4 carbon atoms and a halogen atom,

Process for producing 1-aminoanthraquinones

A process for producing 1-aminoanthraquinones represented by the formula (C) ##STR1## wherein R.sup.1 and R.sup.2, independently from each other, denote one type selected from a hydrogen atom, an alkyl group having 1 to 4 carbon atoms and a halogen atom, which comprises converting 5-nitro-1,4,4a,9a-tetrahydroanthraquinones respresented by formula (A) ##STR2## wherein R.sup.1 and R.sup.2 are as defined above, into 1-hydroxylaminoanthraquinones represented by formula (B) ##STR3## wherein R.sup.1 and R.sup.2 are as defined above, in the presence of a basic compound, and electrolytically reducing the resulting 1-hydroxylaminoanthraquinones in the presence of a basic compound.

A process for producing 1-aminoanthraquinone, which comprises

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Himeji, Japan

Noboru Sugishima