Dainippon Ink and Chemicals, Incorporated

Taisei Road Construction Co., Ltd.

Noboru Okoshi

Mitsuo Kase

Masatoshi Motomura

Ichiro Muramatsu

Kazue Tsuyuzaki

Yoshitami Araki

Takenori Ikeda

Hidetoshi Konno

Kin-ichi Kudo

Kenichiro Nomura

Takehisa Kozai

Mitsuru Ohtsubo

Hidenobu Ishikawa

Shunji Arimoto

Nansei Tashiro

Osamu Maruyama

Toru Sato

Yoichi Abe

Minoru Homma

Yoichi Tanimoto

Yoichi Kawasaki

Takahiko Ito

Hiroshi Mita

Soichi Shimoyama

Shoichi Shimoyama

Niichi Toyama

Finely dispersed polyurethane polyurea crosslinked particles having an average particle diameter of not greater than 1 .mu.m and essentially comprising (A) an ion-forming polyol, (B) a polyisocyanate, and (C) a polyamine; and a process for producing the same are disclosed. The present invention provides finely dispersed polyurethane polyurea crosslinked particles and a process for producing the same; the dispersed particles being firmly crosslinked and having an average particle diameter of not greater than 1 .mu.m, and the particle dispersion having high preservation stability, preventing the core substance, if encapsulated therein, from undergoing denaturation, and exhibiting per se film-forming properties to provide a film excellent in water resistance, solvent resistance and chemical resistance.

Finely dispersed polyurethane polyurea crosslinked particles and process

A crosslinked polyurethane polyurea spherically particulate polymer having an average particle diameter of 0.1 to 500 .mu.m, wherein the polymer molecule contains an isocyanurate ring in an amount of 10 to 30% by weight is disclosed. A process for producing the crosslinked polyurethane polyurea spherically particulate polymer is also disclosed. The process comprises the steps of: reacting an isocyanurate ring-containing polyisocyanate compound with a polyhydroxy compound to form an organic phase capable of forming a three-dimensional crosslinked structure due to the reaction, wherein the amount of isocyanate groups in the polyisocyanate compound is stoichiometrically larger than that of hydroxyl groups in the polyhydroxy compound; finely dispersing the organic phase into water; and adding a polyamine to the dispersion to make interfacial polymerization between the organic phase and the polyamine and a polyurethane-forming reaction within particles, wherein the amount of the polyamine is stoichiometrically equivalent to or smaller than the stoichiometrical excess of isocyanate groups. The particulate polymer is excellent in solvent resistance and has a completely spherical shape without wrinkle on the particle surface. The particulate polymer has a good toughness and mechanical properties. Further, the particulate polymer has no reactive isocyanate group in the polymer molecule.

Isocyanurate ring-containing crosslinked polyurethane polyurea

Polyurethane polyurea particles are obtained by an interfacial polymerization reaction between a hydrophobic phase which is capable of forming a three-dimensional crosslinked structure by reaction and is a mixture comprising a polyisocyanate compound and a polyhydroxy compound with the isocyanate groups being stoichiometrically excessive, and a polyamine in an amount not more than one equivalent of the stoichiometrically excessive isocyanate groups in the hydrophobic phase, and by polyurethanization reaction inside the particles.

Polyurethane polyurea particles and process for production thereof

Disclosed is a process for preparing isocyanurate-type polyisocyanates characterized by reacting an aliphatic or alicyclic diisocyanate compound comprising hexamethylene diisocyanate as a major component in the presence of an isocyanuration catalyst represented by general formula [I], ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent a hydrocarbon group containing 1 to 20 carbon atoms, or a hydrocarbon group containing one or more hetero atoms; at least two of R.sup.1, R.sup.2 and R.sup.3 may be linked to each other; R.sup.4 indicates a hydrogen atom or a hydrocarbon group containing 1 to 20 carbon atoms; and R.sup.5, R.sup.6 and R.sup.7 independently represent a hydrocarbon group containing 1 to 20 carbon atoms. Diol-modified isocyanurate-type polyisocyanates can be prepared additionally using a hydrocarbon diol in the process.

Process for the preparation of polyisocyanate

A polyvinyl chloride resin composition is disclosed, which comprises (a) a vinyl chloride homo- or copolymer, (B) a plasticizer, (C) a blocked urethane prepolymer as essential components, the blocked urethane prepolymer (C) being a prepolymer of isocyanurate type polyisocyanate prepared from an alkylene diisocyanate which may contain in the alkylene chain thereof a substituted or unsubstituted cyclohexane or aromatic ring.

Polyvinyl chloride resin composition

Disclosed is a construction material containing bitumen comprising (A) a polyol component, the polyol component consisting essentially of (a-1) a hydroxy-polyoxyalkylene ether of bisphenol A and/or bisphenol F, and (a-2) an aliphatic polyol, (B) a polyisocyanate component, (C) a bitumen, and/or (D) an aggregate. The construction material has improved water-proof and mechanical properties.

Construction material containing bituminous substances

An urethane coating resin composition comprising as essential components (A) an isocyanurate-type polyisocyanate derived from hexamethylene diisocyanate and containing at least 65% by weight of a mononuclear compound and (B) an acrylic polyol having a number-average molecular weight of 5,000 to 25,000 and a hydroxyl value of 40 to 160.

Urethane coating resin composition

A working material for construction or repair comprising (A) a mixture of 0.5 to 30% by weight of (a-1) a hydroxide of a divalent or higher basic metal, 10 to 99% by weight of (a-2) an aggregate and 0.5 to 70% of (a-3) a bituminous substance, the total amount of these materials (a-1), (a-2) and (a-3) being 100% by weight, and covering the mixture (A), (C) oxidized rosin or a mixture of (C) oxidized rosin with (D) a compound containing more than one carboxy group per molecule on an average and/or (B) a liquid hydrocarbon or a vegetable oil.

Working material for construction or repair

A resin composition comprising (A) a polyisocyanate having an isocyanurate ring obtained by reacting at least one diisocyanate selected from alkylene diisocyanates, cycloalkylene diisocyanates and aralkylene diisocyanates with a diol having 10 to 40 carbon atoms or with a polyester polyol containing 12-hydroexystearic acid as an essential component in the presence of an isocyanuration catalyst, and (B) a nonpolar organic solvent. The composition is useful, for example, as a point, an adhesive or a molding material.

Resin composition comprising an isocyanate having an isocyanurate ring

A pigment paste comprising a pigment and as a pigment dispersing agent, a compound having a basic structure represented by the following formula ##STR1## wherein R.sub.1 represents a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, and R.sub.2 represents a residue of a diol or polyol, or a mixture of said pigment dispersing agent and an organic solvent, said pigment being dispersed in said pigment dispersing agent or in said mixture.

Pigment paste

A process for producing a polyisocyanate containing an isocyanurate ring which comprises reacting at least one diisocyanate compound selected from the group consisting of alkylene diisocyanates, cycloalkylene diisocyanates and aralkylene diisocyanates with a cycloalkylene diol in the presence of an isocyanurating catalyst; and a resin composition for use in non-yellowing fast-drying urethane paints, comprising (A) the aforesaid polyisocyanate and (B) an acrylic polyol having a number average molecular weight of 2,000 to 30,000 and a hydroxyl value of 20 to 200.

Process for producing polyisocyanate and resin composition comprising

An epoxy resin composition is provided consisting essentially of

Epoxy resin composition and construction material containing the same

A process for producing a polyisocyanate containing an isocyanurate ring, which comprises reacting at least one diisocyanate compound selected from the group consisting of alkylene diisocyanates, cycloalkylene diisocyanates and aralkylene diisocyanates with a diol having a molecular weight of 100 to 1,000 and containing at least 3 hydrocarbon substituents per molecule in the presence of an isocyanurating catalyst. A resin composition for urethane paints comprising the polyisocyanate as an essential ingredient.

Process for production of isocyanurate ring-containing polyisocyanate

A coating resin composition consisting essentially of

Coating resin composition

A process for producing a rosin-modified phenolic resin modified with an animal or vegetable oil, which has superior properties as a vehicle for offset printing inks; and a resin composition for printing inks comprising the oil-modified and rosin-modified phenolic resin obtained by the aforesaid process as an essential ingredient.

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Sodegaura, Japan

Noboru Okoshi