Storedot Ltd.

Nir Kedem

Daniel Aronov

Doron Burshtain

Eran Sella

Nir Pour

Ron Paz

Zvi Ioffe

Assaf Zehavi

Nir Baram

Dan Corfas

Hani Farran

Leora Shapiro

Yaron Ideses

Rony Schwarz

Evgenia Liel (Jeny) Kuks

Ido M Herzog

Liron Amir

Shirel Cohen

Shaked Rosenne

Daniel Hirshberg

Evgenia Llel Kuks

Dafna Meron

Yaron Idesis

Rechargeable battery cells and methods for extreme fast charging are disclosed. For example, such a rechargeable battery cell might be chargeable to at least 70% of usable capacity within 15 minutes. Such a rechargeable battery cell may include an anode having at least one surface with a reversible areal capacity, after formation, up to 8.0 mAh/cm, containing a Si—C composite within a porous structure and including a carbon-based conductive additive, wherein the Si—C composite is at least 30% Si by weight, and the material is at least 85% Si—C composite. The rechargeable battery cell may also include a cathode having at least one surface with a reversible areal capacity, after formation, up to 6 mAh/cm, wherein a ratio of areal capacity of the at least one surface of the anode to the at least one surface of the cathode is between 1.15 to 1.45.

Li-ion cells with extreme fast charging capabilities

Rechargeable battery cells and methods for extreme fast charging are disclosed. For example, such a rechargeable battery cell might be chargeable to at least 70% of usable capacity within 15 minutes. Such a rechargeable battery cell may include an anode having a conductive current collector coated with a composite containing a carbon-based material, a cathode configured as a source of Li ions, an electrolyte capable of carrying Li-ions between the anode and the cathode, and a separator between the anode and the cathode, the separator having a thickness of less than 20 microns. Methods of charging the rechargeable battery cells are also disclosed.

Rechargeable battery cell with ultra thin separator

Rechargeable battery cells and methods for extreme fast charging are disclosed. For example, such a rechargeable battery cell might be chargeable to at least 70% of usable capacity within 15 minutes. Such a rechargeable battery cell may include an anode having at least one surface with a reversible areal capacity, after formation, up to 8.0 mAh/cm, and a cathode having at least one surface with a reversible areal capacity, after formation, up to 6 mAh/cm, wherein a ratio of areal capacity of the at least one surface of the anode to the at least one surface of the cathode is between 1.15 to 1.45. Methods of charging rechargeable battery cells disclosed herein under conditions sufficient to enable charging of at least 70% of usable capacity to the rechargeable battery cell within 15 minutes, are also disclosed.

Rechargeable battery cell with increased areal capacity

Lithium ion batteries and electrolytes therefor are provided, which include electrolyte additives having dithioester functional group(s) that stabilize the SEI (solid-electrolyte interface) at the surfaces of the anode material particles, and/or stabilize the CEI (cathode electrolyte interface) at the surfaces of the cathode material particles, and/or act as oxygen scavengers to prevent cell degradation. The electrolyte additives having dithioester functional group(s) may function as polymerization controlling and/or chain transfer agents that regulate the level of polymerization of other electrolyte components, such as VC (vinyl carbonate) and improve the formation and operation of the batteries. The lithium ion batteries may have metalloid-based anodes—including mostly Si, Ge and/or Sn as anode active material particles.

Electrolytes for fast charging lithium ion batteries having four-carbon chain esters as linear components

Fast-charging lithium ion cells are provided, which have electrolytes that do not react with the cell anodes, but instead form a solid-electrolyte interphase (SEI) on the cathodes. Advantageously, such electrolytes improve the performance of the fast-charging cells, and enhance their lifetime and safety. Various electrolyte solutions and lithium ions are proposed to limit electrolyte interactions to the cathodes, or possibly even minimize or prevent these reactions by coating the cathodes. Redox couples may be used to prevent SEI formation on the anode, while promoting SEI formation on the cathode.

Fast-charging lithium ion batteries with electrolytes that do not react on the anodes

Systems and methods are provided, in which the level of metal ions in cells stacks and lithium ion batteries is regulated in situ, with the electrodes of the cell stack(s) in the respective pouches. Regulation of metal ions may be carried out electrochemically by metal ion sources in the pouches, electrically connected to the electrodes. The position and shape of the metal ion sources may be optimized to create uniform metal ion movements to the electrode surfaces and favorable SEI formation. The metal ion sources may be removable, or comprise a lithium source for lithiating the anodes or cathodes during operation of the battery according to SoH parameters. Regulation of metal ions may be carried out from metal ion sources in separate electrolyte reservoir(s), with circulation of the metal-ion-containing electrolyte through the cell stacks in the pouches prior or during the formation.

In-operation cathode lithiation according to SoH monitoring

Improved anodes and cells are provided, which enable fast charging rates with enhanced safety due to much reduced probability of metallization of lithium on the anode, preventing dendrite growth and related risks of fire or explosion. Anodes and/or electrolytes have buffering zones for partly reducing and gradually introducing lithium ions into the anode for lithiation, to prevent lithium ion accumulation at the anode electrolyte interface and consequent metallization and dendrite growth. Various anode active materials and combinations, modifications through nanoparticles and a range of coatings which implement the improved anodes are provided.

Preparing anodes for lithium ion cells from aluminum anode active material particles

Electrolytes, anodes, lithium ion cells and methods are provided for preventing lithium metallization in lithium ion batteries to enhance their safety. Electrolytes comprise up to 20% ionic liquid additives which form a mobile solid electrolyte interface during charging of the cell and prevent lithium metallization and electrolyte decomposition on the anode while maintaining the lithium ion mobility at a level which enables fast charging of the batteries. Anodes are typically metalloid-based, for example include silicon, germanium, tin and/or aluminum. A surface layer on the anode bonds, at least some of the ionic liquid additive to form an immobilized layer that provides further protection at the interface between the anode and the electrolyte, prevents metallization of lithium on the former and decomposition of the latter.

Mobile layer of ionic liquid in electrolytes

Polymer coatings and anode material pre-lithiation

Buffering zone for preventing lithium metallization on the anode of lithium ion batteries

Composite lithium borates and/or phosphates and polymer coatings for active material particles

Methods for preparing anodes from anode active material particles with lithium borates and phosphates coatings

Pre-lithiation of multiple battery pouches

Introducing a mobile layer of ionic liquid into electrolytes of lithium ion batteries

Aluminum anode active material

Growing community of inventors

Haifa, Israel

Nir Kedem