Institute of Nuclear Energy Research, Atomic Energy Council, Executive Yuan, R.o.c

Institute of Nuclear Energy Research, Atomic Energy Council

Atomic Energy Council

Atomic Energy Council-institute of Nuclear Energy Research

Ning-Yih Hsu

Su-Hsine Lin

Qiao-Ya Chen

Ruey-Yi Lee

Chun-Ching Chien

Wan-Min Huang

Yi-Hsin Hu

Hung-Hsien Ku

Shean-Du Chiou

Hwa-Jou Wei

Yi-Sin Chou

Yao-Sheng Hsu

Chin-Lung Hsieh

Hwei-Liang Chang

Zone-Sure Chang

Chien-Hong Lin

Chun Chien

Tung-Jen Wen

Han-Jou Lin

Meng-han Huang

Yu-De Zhuang

Yuan-Ming Chang

Kuan-Hsiang Chen

Han-Wen Chou

Hwa-Yuan Tzeng

Wen-Song Hwang

King-Tsai Jeng

Chao-Yen Kuo

Chao Yu

Chieh Fang

Yun-Shan Tsai

Chen-To Tsai

Tai-Feng Hung

Shean-du Chiou

Hwa-Yuang Tzeng

Chen-Hao Wang

Ying Sheng Lee

Heng-Wei Chiang

A method is provided to optimize the surface of a carbon electrode for flow battery. A reaction solution is prepared as containing a requested ratio of functional group. After spraying the reaction solution on the carbon electrode, a number of related parameters of an atmospheric plasma are set for activation the carbon electrode. Thus, the functional group is covalently bonded on the surface of the carbon electrode according to requirement. Thereby, an accurate control of the type and number of the functional group bonded on the surface of the carbon electrode is achieved with the stability and performance of flow battery further enhanced.

Method of optimizing surface of carbon electrode for flow battery

A polar plate is fabricated. The polar plate is flexible and made of a plastic graphite composite. No matter a supporting member is used for calendering or not, a thin polar plate with controllable thickness is fabricated. The polar plate is excellent in blocking the through-transmission of vanadium ions and the limit of blending ratio of conductive carbon is broken through. The longitudinal through-transmission volume resistivity (proportional resistance to thickness) is greatly improved by adjusting the blending ratio of conductive carbon for meeting the demand of conductivity. In the mean time, the present invention strengthens the rigidity required for the thin polar plate while providing large-area polar plate fabrication for industrial use and convenience and provides a cooling and pressing method for patterning a composite polar plate. An integrated mold is thus obtained to replace the conventional polar plate which needs to be processed and prepared with runner.

Method for fabricating polar plate of flexible plastic graphite composite

An apparatus is provided for measuring the power of electrolytes at different positions of a flow battery by switching six-way valves without reconnecting channels. With the measurements at the positions, weighting is processed to obtain power corresponding to charging statuses for determining accurate power. The charging and discharging of voltage and current of the battery are controlled for constant operations with high efficiency. Consequently, the efficiency of power conversion is improved; energy consumption is reduced; and the battery is always run within a safe power-range for avoiding accidents or damages to the battery. In addition, the present invention is further applicable to a device monitoring the features of a battery unit. The six-way valves online monitor the power at center positions by switching. The values measured at different positions are aimed at the abnormality of the battery unit for processing adjustment or offline replacement to maintain best operation performance.

Apparatus for electricity measurement of flow battery and method thereof

A method is provided for restoring an electrolyte of vanadium (V) redox flow battery (VRFB). Electrolyte data of an original system are analyzed in advance. A reusable positive electrode is further equipped with a V electrolyte. A reductant for a stack of VRFB is used in coordination as an electrolysis device. After a long-term reaction with a VRFB having a high valence (greater than 3.5), an electrolyte at the positive electrode is directed out to a negative electrode of the electrolysis device; and, then, electrolysis is processed after accurate calculation. In the end, the internal fluid balancing method of the original system is combined. Thus, a harmless and quick valence restoration is processed for the electrolyte of the original system, which is a final resort for the restoration of V electrolyte.

Method of restoring electrolyte of vanadium redox flow battery through electrolysis

A storage module of distributed flow battery is provided. An electrochemical reaction is processed with the positive and negative electrolytes to produce and/or discharge direct current and further output the positive and negative electrolytes after the reaction. The module comprises two end plates; two frames disposed between the two end plates; two current collectors disposed between the two frames; two complex cast polar plates disposed between the two current collectors; two electrodes disposed between the two complex cast polar plates; a membrane disposed between the two electrodes; and three gaskets. Therein, two of the gaskets are set to sandwich and enclose one of the two complex cast polar plates; and the other one of the gaskets is set between the other one of the two complex cast polar plates and an adjacent one of the current collectors.

Storage module of distributed flow battery

A flow battery apparatus is provided with shunted currents repressed. The apparatus has a positive electrode device, a negative electrode device and a plurality of gas-gap devices. Gas-gap devices are separately set between branching channels and inlet and outlet manifolds of positive and negative electrodes. Each of the branching channels separately has an inserting tube to be inserted into one of the gas-gap devices. The diameter of the inserted vessel of gas-gap devices is bigger than the diameter of the inserting tube connected to a corresponding one of the branching channels. Thus, working liquids transferred to the positive and negative electrodes are segregated with coordination of the gas-gap devices. Only air spaces and discrete liquid drops are left between separated parts of the working liquids. Thus, shunted currents are repressed by preventing conductive paths from being formed between the positive and negative electrodes.

Flow battery apparatus with shunted current repressed and method thereof

A method is provided to enhance efficiency of carbon felts in a flow battery. The carbon felts are directly immersed in a mixed acid solution. The carbon felts with the solution are heated at a low temperature and processed through sonication. On surface defects of the carbon felts, &#x2014;OH and C&#x2550;O functional groups are efficiently generated. The functional groups catalyze the redox reaction of vanadium ions. More active positions are obtained on the carbon felts through the activation treatment. Both of valence exchange and redox velocity of the vanadium ions are enhanced. Thus, the present invention has simple and fast processes with easily regulated experimental parameters for good modification without high temperature treatment but low cost.

Method of enhancing efficiency of carbon felts in flow battery through sonication

A method is provided for fabricating a catalyst carrier. At first, aluminum hydroxide is used for forming an alumina powder. The alumina powder is mixed with carbon nanotubes and a complex additive to be shaped into a cake. The cake is kneaded into a noodle-like shape to be hot-dried. Then, calcination is processed in a furnace under 1200 celsius degrees (&#xb0; C.) with air passed through. The crystal structure remains without phase change. A catalyst carrier of &#x3b1;-alumina having nano-scaled pores is formed. The catalyst carrier is a powdery material made into different three-dimensional forms. The catalyst carrier thus fabricated is suitable for generating hydrogen through methane reformation. The catalyst carrier has a methane conversion greater than 99 percents. The catalyst carrier will not be crumbled under 800&#xb0; C. for 4000 hours without carbon deposit.

Method of fabricating catalyst carrier for generating hydrogen through methane reformation

A reactor using honeycomb catalyst is provided for fuel reformation with high activity and heat stability. The reactor comprises a heating tube, a methane gas inlet, a three-way steam inlet and a hydrogen-rich gas outlet. The three-way steam inlet is near to the heating tube for providing heat required for reformation and to reduce power consumption. The heating tube is made of an inconel material so that the overall reaction may be carried out at high temperature. The heating tube is set with a honeycomb carrier of cordierite. The honeycomb carrier is pasted with carbon nanotube and heat-treated to increase internal surface area. The honeycomb carrier has a Pt/CeO/&#x3b1;-AlOcatalyst; is placed in the heating tube; and has honeycomb-pores channels parallel to a main axis of the heating tube.

Reactor with honeycomb catalyst for fuel reformation

A method is provided for producing electrodes of flow cell having high power density. A plurality of seeds are distributed on a surface of a conductive carbon material. The seeds are etched into nanoparticles to form carbon nanotube (CNT) electrodes. The present invention can be applied to vanadium redox flow cell with advantages of the CNT electrodes, such as conductivity, corrosion resistance, mechanical strength and specific and electrochemical surface area. Electrons are directly passed to the material through CNTs and then to an external electronic load for improving power density of flow cell, making a cell pack more compact and reducing energy consumption on charging and discharging without using noble metal material.

Method of fabricating electrodes of high power-density flow cell

A device is provided for detecting a charging and discharging status of a flow-cell pack. During charging and discharging course of the flow-cell pack coordinated with electrolyte storage tanks and actuators, ultrasonic sensors of ultrasonic detection devices are used to sense sonic vibration generated by fluid flow in the flow-cell pack. Thus, the charging and discharging status of the flow-cell pack is detected for adjusting related parameters. The present invention has a simple structure, runs without using extra power supply, does not hinder performance of flow cell, and obtains charging and discharging status of flow cell accurately and rapidly.

Ultrasonic device detecting charging/discharging status of flow-cell pack

A gas-reforming catalyst is modified to obtain stability in high temperature. The catalyst uses &#x3b1;-AlOas a carrier and is nano-porous. Hence, reaction surface is greatly broadened; and platinum contained inside does not become bigger after times of use. The catalyst does not deposit carbon and has long life. The stability of the catalyst can be still remained even at a temperature higher than 800&#xb0; C.

Method of modifying nano-porous gas-reforming catalyst with high-temperature stability

A device for detecting steel is provided. The steel is used in a nuclear plant. The device has a detecting circuit of electrochemical corrosion potential (ECP) and alternative current (AC) impedance. An environment in a boiling water reactor (BWR) is simulated under hydrogen water chemistry (HWC). The environment is used for detecting intergranular stress corrosion cracking (IGSCC) of components coated with different precious metals. Thus, effect of coating different precious metals on steels can be evaluated for HWC.

Nuclear power plant steel detecting device

A catalyst-testing apparatus includes a heater, a U-shaped reactor, a gas flow controller, a liquid flow controller, two pressure gauges, a separator and a chromatograph. In use, under control of the gas flow controller, natural gas and air are directed to the U-shaped reactor. Under control of the liquid flow controller, pure water is directed to the U-shaped reactor. The pure water travels down the wall of the U-shaped reactor. The pure water is heated and turned into steam in a front section of the U-shaped reactor. Together with the natural gas and the air, the steam is directed to a catalyst zone in the U-shaped reactor for reaction. With the chromatograph, volumes and compositions of resultant gases are analyzed. Thus, the stability of the performance of the catalyst is tested, and the performance of the catalyst for producing hydrogen by is revealed.

Apparatus for testing catalyst

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Keelung, Taiwan

Ning-Yih Hsu