Trinseo Europe Gmbh

Styron Europe Gmbh

Nicolaas M A Hermans

Gilbert Bouquet

Norwin Van Riel

Ulrich Reifert

The teachings herein are directed to multi-layered articles, methods for making the multi-layered articles, and polymeric compositions for the multi-layered articles. The multi-layered article includes a substrate layer and an overmolded cover layer. The substrate layer preferably is a polymeric composition including about 55 weight percent or less (preferably about 50 weight percent or less) polycarbonate, a styrene containing polymer, and an impact modifier. The cover layer preferably includes a polyurethane, a polyurea, or both. The substrate preferably forms a durable bond to the cover layer that maintains adhesion even after aging (e.g., heat, thermal cycling, UV light, visible light, humidity, climate aging, or any combination thereof).

Multi-layer composite article including a cover layer and a PC/ABS layer and methods thereof

Provided is a process for preparing polystyrene having a weight average molecular weight (Mw) in the range of 120,000-160,000 g/mol, a polydispersity in the range of 4-6 and a melt flow rate of at least 40 g/10 minutes by feeding styrene into a reaction system through which the styrene passes as a component of a reaction mixture as it is polymerized, the reaction system including an initial reaction zone () and a downstream reaction zone (), comprising the steps of: polymerizing styrene in the initial reaction zone to form polystyrene having a Mw of greater than 300,000 g/mol and a polydispersity in the range 1.5-2.5, 10-30 wt. % of the styrene fed to the initial reaction zone being polymerized there, &#x2014;and polymerizing styrene remaining in the reaction mixture in the downstream reaction zone, a chain transfer agent being mixed with the reaction mixture at the commencement of this reaction zone and optionally at one or more additional locations within this reaction zone. The polystyrene may be used to manufacture expandable polystyrene beads or polystyrene foam board.

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Terneuzen, Netherlands

Nicolaas M A Hermans