Montedison S.p.a.

Nicola Mazzaferro

Ruggero Battisti

Gioacchino Boffa

Giovanni Bausani

Antonio Tundo

Angelo Mangini

Francesco Casagrande

Giorgio Bornengo

Luigi Cassar

Fabrizio Merlo

A new class of water-soluble monoazo cationic dyestuffs free from sulphonic or carboxylic acid groups is disclosed. A process for preparing the new dyestuffs, which are derived from 1-phenyl-3-aminopyrazoles, is also disclosed.

Water-soluble monoazo cationic dyestuffs derived from

A new class of hydrosoluble monoazoic cationic dyes free of sulphonic or carboxylic groups and derived from 1-phenyl-3-aminopyrazoles is disclosed, as are, also, processes for preparing the new dyes and use thereof in the dyeing and printing of synthetic fibers.

Monoazoic hydrosoluble cationic dyes

The present invention concerns a new class of pigments derived from cumarin and, more particularly, of bis-iminocumarinic and bis-cumarinic pigments having the following formula I described hereinlater. The present invention also includes novel processes for making the cumarinic pigments of the invention. Also, the invention relates to the use of the novel pigments of the invention for the preparation of paints, storing enamels, inks and pastes for the printing of fabrics. Also, included in this invention is the dyeing of plastic materials with the novel cumarinic pigments.

Cumarinic pigments

New yellow mono-azo dyes which are insoluble in water are disclosed. The dyes are derived from 1-phenyl-3-aminopyrazoles and are particularly effective in dyeing synthetic hydrophobic fibers to intense yellow shades.

Water-insoluble mono-azo yellow dyes derived from

1-PHENYL-3-AMINO-2-PYRAZOLINES ARE CATALYTICALLY OXIDIZED TO 1-PHENYL-3-AMINOPYRAZOLES, USING OXYGEN AND/OR AIR AS THE OXIDIZING AGENT AND IN THE PRESENCE OF COPPER SALTS, OPTIONALLY ASSOCIATED WITH METALLIC COPPER AND/OR AN AROMATIC, HETEROCYCLIC ORGANIC BASE SELECTED FROM N-dialkyl anilines, pyridines, piperidine, and ethanolamine, or equivalents thereof, in an inert reaction medium and at a temperature of from about 20.degree. C. to about 40.degree. C.

Process for preparing 1-phenyl-3-aminopyrazoles

A new class of heterocyclic compounds containing N and S in the basic skeleton and which are 5-aza-7-thiadibenzocrysene derivatives useful as dyes or as intermediates in the synthesis of dyes and pigments are disclosed, as well as a method of obtaining the same by reaction of o-aminothiophenol 2-hydroxy-1-azabenzanthrone or its derivatives.

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Novara, Italy

Nicola Mazzaferro